Hardwick Group
Publications
2024
Concluding remarks: A summary of the Faraday Discussion on Rechargeable non-aqueous metal–oxygen batteries
L.J. Hardwick
Faraday Discussions, 248 (2024) 412 DOI
Simultaneous Surface-Enhanced Raman Scattering with a Kerr Gate for Fluorescence Suppression
G. Cabello, I.V. Sazanovich, I. Siachos, M. Bilton, B.L. Mehdi, A.R. Neale, L.J. Hardwick.
J. Phys. Chem. Lett. (2024) DOI
Effect of alkali-metal cation on oxygen adsorption at Pt single-crystal electrodes in non-aqueous electrolytes
J. Fernández-Vidal, L.J. Hardwick, G. Cabello, G.A. Attard.
Faraday Discussions (2024) DOI
2023
Shell-isolated nanoparticle-enhanced Raman spectroscopy
Y.J. Zhang, H. Ze, P.P. Fang, Y.F. Huang, A. Kudelski, J. Fernández-Vidal, L.J.Hardwick, J. Lipkowski, S.Q.Tian, J.F. Li.
Nature Reviews Methods Primers 3 (2023) 36 DOI
Electrodeposition of Manganese Dioxide Coatings onto Graphene Foam Substrates for Electrochemical Capacitors F. Braga, G. Casano, L.M. Daniels, M. Caffio, L.J. Hardwick.
Electrochimica Acta (2023) 142433 DOI
Fluorine-Rich Oxyfluoride Spinel-like Li1.25Ni0.625Mn1.125O3F Utilizing Redox-Active Ni and Mn for High Capacity and Improved Cyclability
H. Cai, R. Chen, M. Bahri, C.J. Hawkins, M. Sonni, L.M. Daniels, J. Lim, J.A. Evans, M. Zanella, L.A.H. Jones. T.D. Manning, T.D. Veal, L.J.Hardwick, M.S.Dyer, N.D. Browning, J.B. Claridge, M.J.Rosseinsky.
ACS Materials Letters 5 (2023) 527-535 DOI
Towards commercialization of fluorinated cation-disordered rock-salt Li-ion cathodes
G.H. Lee, J. Lim, J. Shin, L.J. Hardwick, W. Yang
Frontiers in Chemistry 11 (2023) DOI
Raman analysis of inverse vulcanised polymers
L.J. Dodd, C. Lima, D. Costa-Milan, A.R. Neale, B. Saunders, B. Zhang, S.A. Bowen, A. Sarua, R. Goodacre, L.J. Hardwick, M. Kuball, T. Hassell.
Polymer Chemistry 14 (2023) 1369-1386 DOI
Effect of alkali-metal cation on oxygen adsorption at Pt single-crystal electrodes in non-aqueous electrolytes
J. Fernández-Vidal, L.J. Hardwick, G. Cabello, & G.A. Attard (2023).
Faraday Discussions DOI
Localised degradation within sulfide-based all-solid-state electrodes visualised by Raman mapping
J. Lim, Y. Zhou, R.H. Powell, T. Ates, S. Passerini, , & L.J. Hardwick (2023).
Chemical Communications 59(51) 7982-7985 DOI
Nanophase-photocatalysis: loading, storing, and release of H2O2 using graphitic carbon nitride
A. Karunakaran, K.J. Francis, C.R. Bowen, R.J. Ball, Y. Zhao, L, Wang, . . . F. Marken, (2023).
Chemical Communications 59(48), 7423-7426. DOI
2022
Oxygen heteroatom enhanced sulfur-rich polymers synthesized by inverse vulcanization for high-performance lithium-sulfur batteries
H. Wang, B Zhang, R. Dop, P. Yan, A.R. Neale, L.J. Hardwick, T. Hasell.
J. Power Sources 545 (2022) 231921 DOI
Corrosion suppression of aluminium current collectors within Li-ion cells using 3-methoxypropionitrile-based electrolytes
C.H. Yen, A.R. Neale, J. Lim, D. Bresser, C.-C. Hu, L.J. Hardwick.
Electrochim. Acta (2022) 141105 DOI
Lithium Insertion into Graphitic Carbon Observed via Operando Kerr-Gated Raman Spectroscopy Enables High State of Charge Diagnostics
A.R. Neale, D. Costa-Milan, F. Braga, I.V. Sazanovich, L.J. Hardwick.
ACS Energy Letts. 7 (2022) 2611 DOI
Long-Life and pH-Stable SnO2-Coated Au Nanoparticles for SHINERS
J. Fernández-Vidal, A. Gomez, L.A.H. Jones, C.H. Yen, T.D. Veal, V.R. Dhanak, C.-C. Hu, L.J. Hardwick.
J. Phys. Chem. C 126 (2022) 12074 DOI
Dynamics of Solid‐Electrolyte Interphase Formation on Silicon Electrodes Revealed by Combinatorial Electrochemical Screening
D. Martín-Yerga, D.Costa. Milan, X. Xu, J. Fernández-Vidal, L. Whalley, A.J. Cowan, L.J. Hardwick, P. Unwin.
Angew. Chemie. Int. Ed. (2022) e202207184 DOI
A Pyrene-4, 5, 9, 10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode
H. Gao, A.R. Neale, Q. Zhu, M. Bahri, X. Wang, H. Yang, Y. Xu, R. Clowes, N.D. Browning, M.A. Little, L.J. Hardwick, A.I. Cooper.
J. Amer. Chem. Soc. 144 (2022) 9436 DOI
Investigating the presence of adsorbed species on Pt steps at low potentials
R. Rizo, J. Fernández-Vidal, L.J. Hardwick, G.A. Attard, F.J. Vidal-Iglesias, V. Climent, E. Herrero, J.M. Feliu.
Nature Commun. 13 (2022) 255 DOI
2021
Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li4CuSbO5.5, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure
A.J. Perez, A. Vasylenko, T.W. Surta, H. Niu, L.M. Daniels, L.J. Hardwick, M.S. Dyer, J.B. Claridge, M.J. Rosseinsky.
Inorg. Chem. 60 (2021) 19022 DOI
Design Parameters for Ionic Liquid–Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li–O2 Batteries
A.R. Neale, R. Sharpe, S. Yeandel, C.H. Yen, K.V. Luzyanin, P. Goddard, E. Petrucco, L.J. Hardwick
Adv. Funct Mater. 31 (2021) 2170193 DOI
Integrated Covalent Organic Framework/Carbon Nanotube Composite as Li‐Ion Positive Electrode with Ultra‐High Rate Performance
H. Gao, Q. Zhu, A.R. Neale, M. Bahri, X. Wang, H. Yang, L. Liu, R. Clowes, N.D. Browning, R.S. Sprick, M.A. Little, L.J. Hardwick, A.I. Cooper
Adv. Ener. Mater. 11 (2021) 210880 DOI
Trapped interfacial redox introduces reversibility in the oxygen reduction reaction in a non-aqueous Ca2+ electrolyte
Y.-T. Lu, A.R. Neale, C.-C. Hu, L.J. Hardwick
Chem. Sci., 1 (2021) 8909 DOI
Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability
G. Han, A. Vasylenko, A.R. Neale, B. Duff, R. Chen, M.S. Dyer, Y. Dang, L. Daniels, M. Zanella, C. Robertson, L. Kershaw Cook, A.-L. Hansen, M. Knapp, L.J. Hardwick, F. Blanc, J.B. Claridge, M.J. Rosseinsky
J. Amer. Chem Soc. (2021) DOI
Element selection for crystalline inorganic solid discovery guided by unsupervised machine learning of experimentally explored chemistry
A. Vasylenko, J. Gamon, B. Duff, V.V. Guse, L.M. Daniels, M. Zanella, J.F Shin, P.M. Sharp, A. Morscher, R. Chen, A.R. Neale, L.J. Hardwick, J.B. Claridge, F. Blanc, M.W. Gaultois, M.S. Dyer, M.J. Rosseinsky
Nature Commun. 12 143 (2021) 18216 DOI
Data Management Plans: The Importance of Data Management in the BIG-MAP Project
I.E. Castelli, D.J. A. Arrieta, A. Bhowmik, I. Cekic-Laskovic, S. Clark, R. Dominko, E. Flores, J. Flowers, K.U. Frederiksen, J. Friis, A. Grimaud, K.V. Hansen, L.J. Hardwick, K. Hermansson, L. Königer, H. Lauritzen, F. Le Cras, H. Li, S. Lyonnard, H. Lorrmann, N. Marzari, L. Niedzicki, G. Pizzi, F. Rahmanian, H. Stein, M.U., W. Wenzel, M. Winter, C. Wölke, T. Vegge
Batteries&SuperCap. (2021) DOI
Porous polyimide separator promotes uniform lithium plating for lithium-free cells
J.-Y. Pai, H.-Y. Ku, C.-C. Lin, L.J. Hardwick, C.-C. Hu
Electrochem. Sci. Adv. (2021) DOI
The Effect of Degrees of Inversion on the Electronic Structure of Spinel NiCo2O4: A Density Functional Theory Study
T.-C. Chang, Y.-T. Lu, C.-H. Lee, J.K. Gupta, L.J. Hardwick, C.-C. Hu, H.-Y.T. Chen
ACS Omega 6 (2021) 9692 DOI
Divalent Nonaqueous Metal-Air Batteries
Y.-T. Lu, A.R. Neale, C.-C. Hu, L.J. Hardwick
Frontiers in Energy Research, 8 (2021) 602918 DOI
Engineering of electrospun polyimide separators for electrical double-layer capacitors and lithium-ion cells
J.Y. Pai, C.T. Hsieh, C.H. Lee, J.A. Wang, H.Y. Ku, C.L. Huang, L.J. Hardwick, C.-C. Hu
Journal of Power Sources 482 (2021) 229054 DOI
2020
An electrochemical investigation of oxygen adsorption on Pt single crystal electrodes in a non-aqueous Li+ electrolyte
T.A. Galloway, G. Attard, L.J. Hardwick
Electrochemistry Communications 119 (2020) 106814 DOI
Crosslinked Polyimide and Reduced Graphene Oxide Composites as Long Cycle Life Positive Electrode for Lithium‐Ion Cells
H. Gao, B. Tian, H. Yang, A.R. Neale, M.A. Little, R.S. Sprick, L.J. Hardwick, A.I. Cooper
ChemSusChem 13 (2020) 5571 DOI
2020 roadmap on solid-state batteries
M Pasta, D Armstrong, ZL Brown, J Bu, MR Castell, P Chen, A Cocks, S.A. Corr, E.J. Cussen, E. Darnbrough, V. Deshpande, C .Doerrer, M.S. Dyer, H. El-Shinawi, N. Fleck, P. Grant, G.L. Gregory, C. Grovenor, L.J. Hardwick, J.T.S. Irvine, H.J. Lee, G. Li, E. Liberti, I. McClelland, C. Monroe, P.D. Nellist, P.R. Shearing, E. Shoko, W. Song, D.S. Jolly, C.I. Thomas, S.J. Turrell, M. Vestli, C.K. Williams, Y. Zhou, P.G. Bruce
Journal of Physics: Energy 2 (2020) 032008 DOI
Na2Fe2OS2, a new earth abundant oxysulphide cathode material for Na-ion batteries
J .Gamon, A.J. Perez, L.A.H. Jones, M. Zanella, L.M. Daniels, R.E. Morris, C.C. Tang, T.D. Veal, L.J. Hardwick, M.S. Dyer, J.B. Claridge, M.J. Rosseinsky
Journal of Materials Chemistry A, 8 (2020) 20553 DOI
Sn 5s2 lone pairs and the electronic structure of tin sulphides: A photoreflectance, high-energy photoemission, and theoretical investigation
L.A.H. Jones, W.M. Linhart, N. Fleck, J.E.N. Swallow, P.A.E. Murgatroyd, H. Shiel, T.J. Featherstone, M.J. Smiles, P.K. Thakur, T.-L. Lee, L.J. Hardwick, J. Alaria, F. Jäckel, R. Kudrawiec, L.A. Burton, A. Walsh, J.M. Skelton, T.D. Veal, V.R. Dhanak
Physical Review Materials 4 (2020) 074602 DOI
Quantitative Resolution of Complex Stoichiometric Changes During Electrochemical Cycling by Density Functional Theory Assisted, Electrochemical Quartz Crystal Microbalance
T.-H. Wu, I. Scivetti, J.-C. Chen, J.-A. Wang, G. Teobaldi, C.-C. Hu L.J. Hardwick
ACS Applied Energy Materials 3 (2020) 3347 DOI
Observation of Interfacial Degradation of Li6PS5Cl against Lithium Metal and LiCoO2 via In Situ Electrochemical Raman Microscopy
Y. Zhou, C. Doerrer, J. Kasemchainan, P.G. Bruce, M. Pasta, L.J. Hardwick
Batteries & Supercaps 3 (2020) 647 DOI
Water oxidation intermediates on iridium oxide electrodes probed by in situ electrochemical SHINERS
K.H. Saeed, M. Forster, J.F. Li, L.J. Hardwick, A.J. Cowan
Chemical Communications 56 (2020) 1129 DOI
Intercalation behaviour of Li and Na into 3-layer and multilayer MoS2 flakes
J. Zou, F. Li, M.A. Bissett, F. Kim, L.J. Hardwick
Electrochimica Acta 331 (2020) 135284 DOI
2019
Enhanced oxygen evolution performance of spinel Fe0.1Ni0.9Co2O4/ Activated carbon composites
Y.-T. Lu, J. Wu, Z.-X. Lin, T.-H. You, S.-C. Lin, H.-Y. T. Chen, L. J. Hardwick and C.-C. Hu
Electrochimica Acta., (2019), 326, 134986 DOI
Kerr gated Raman spectroscopy of LiPF6 salt and LiPF6-based organic carbonate electrolyte for Li-ion batteries
L. Cabo-Fernandez, A. R. Neale, F. Braga, I. V. Sazanovich, R. Kostecki and L. J. Hardwick
Phys. Chem. Chem. Phys., (2019), Advance Article DOI
The Facile Fabrication of a Light-weight Dual-functional Modified Separator towards High Performance Li-S Batteries
R. Yi, X. Lin, Y. Zhao, C. Liu, Y. Li, L.J. Hardwick, L. Yang, C. Zhao, X. Geng and Q. Zhang
ChemElectroChem., 6 (2019), 3648 DOI
Stabilization of O-O bonds by d0 cations in Li4+xNi1-xWO6 (0≤ x≤ 0.25) rocksalt oxides as the origin of large voltage hysteresis
Z.N. Taylor, A.J. Perez, J.A. Coca-Clemente, F. Braga, N.E. Drewett, M.J. Pitcher, W.J. Thomas, M.S. Dyer, C. Collins, M. Zanella, T. Johnson, S. Day, C. Tang, V.R. Dhanak, J.B. Claridge, L.J. Hardwick and M.J. Rosseinsky
J. Am. Chem. Soc., 141 18 (2019), 7333- 7346 DOI
Advanced spectroelectrochemical techniques to study electrode interfaces within lithium-ion and lithium-oxygen batteries
A. J. Cowan and L. J. Hardwick
Annu. Rev. Anal. Chem., 12 (2019), 23.1- 23.24 DOI
Adsorption, surface relaxation and electrolyte structure at Pt(111) electrodes in non-aqueous and aqueous acetonitrile electrolytes
G. S. Harlow, I. M. Aldous, P. Thompson, Y. Grunder, L. J. Hardwick and C. A. Lucas
Phys. Chem. Chem. Phys., 21 (2019), 8654-8662 DOI
Evaluating chemical bonding in dioxides for the development of metal-oxygen batteries: vibrational spectroscopic trends of dioxygenyls, dioxygen, superoxides and peroxides
P. M. Radjenovic and L. J. Hardwick
Phys. Chem. Chem. Phys., 21 (2019), 1552-1563 DOI
A light-weight free-standing graphene foam-based interlayer towards improved Li-S cells
R. Yi, C. Liu, Y. Zhao, L. J. Hardwick, Y. Li, X. Geng, Q. Zhang, L. Yang, C. Zhao
Electrochimica Acta, 299 (2019), 479-488 DOI
Oxygen reactions on Pt{hkl} in a non-aqueous Na+ electrolyte: Site selective stabilization of a sodium peroxy species
T. A. Galloway, J. Dong, J.F. Li, G. Attard and L. J. Hardwick
Chem. Sci, 10 (2019), 2956-2964 DOI
In situ electrochemical SHINERS investigation of SEI composition on carbon-coated Zn0.9Fe0.1O anode for lithium-ion batteries
L. Cabo-Fernandez, D. Bresser, F. Braga, S. Passerini, and L. J. Hardwick
Batteries & Supercaps., 2 (2019), 168-177 DOI
Enhanced oxygen evolution performance of spinel Fe0.1Ni0.9Co2O4/ Activated carbon composites
Y.-T. Lu, J. Wu, Z.-X. Lin, T.-H. You, S.-C. Lin, H.-Y. T. Chen, L. J. Hardwick and C.-C. Hu
Electrochimica Acta. 326 (2019), 134986 DOI
Kerr gated Raman spectroscopy of LiPF6 salt and LiPF6-based organic carbonate electrolyte for Li-ion batteries
L. Cabo-Fernandez, A. R. Neale, F. Braga, I. V. Sazanovich, R. Kostecki and L. J. Hardwick
Phys. Chem. Chem. Phys., 21 (2019), 23833 DOI
2018
Metal-Air Batteries: Fundamentals and Applications; Chapter 9 Metal-Air Battery: In Situ Spectro-electrochemical Techniques
I. M. Aldous, L. J. Hardwick, R. J. Nichols, and J. Padmanabhan Vivek
Ed. Xin-bo Zhang, Wiley 2018, Book
Lithium transport in Li4.4M0.4M’0.6S4 (M= Al3+, Ga3+ and M’= Ge4+, Sn4+): Combined crystallographic, conductivity, solid state NMR and computational studies
B, T. Leube, K, K. Inglis, E. Carrington, P. M. Sharp, J. F. Shin, A. R. Neale, T. D. Manning, M. J. Pitcher, L. J. Hardwick, M. S. Dyer, F. Blanc, J. B. Claridge, and M. J. Rosseinsky
Chem. Matter., 30 (2018), 7183-7200 DOI
Growth and Dissolution of NaO2 in an Ether-based Electrolyte as the Discharge Product in the Na-O2 Cell
I. Aldous, L. J. Hardwick
Chem. Commun., 54 (2018), 3444- 3447 DOI
Rechargeable Multi-Valent Metal-Air Batteries: A Review of Research and Current Challenges in Secondary Multivalent Metal-Oxygen Batteries
L. J. Hardwick, C. Ponce de Leon
Johnson Matthey Technol. Rev., 2 (2018), 62, 134–149 DOI
Time-resolved SERS study of the Oxygen Reduction Reaction in Ionic Liquid Electrolytes for Non-Aqueous Lithium-Oxygen Cells
P. Radjenovic, L.J. Hardwick
Faraday Discuss., 206 (2018) 379-392 DOI
Structure and Dynamics of Ionic Liquids: A General Discussion
M. Addicoat, R. Atkin, J. N. C. Lopes, M. C. Gomes, M. Firestone, R. Gardas, S. Halstead, C. Hardacre, L. J. Hardwick, J. Holbrey, P. Hunt, V. Ivaništšev, J. Jacquemin, R. Jones, B. Kirchner, R. Lynden-Bell, D. MacFarlane, G. Marlair, H. Medhi, M. Mezger, A. Pádua, I. Pantenburg, S. Perkin, J. E. S. J. Reid, M. Rutland, S. Saha, K. Shimizu, J. M. Slattery, M. Swadźba-Kwaśny, S. Tiwari, S. Tsuzuki, B. Uralcan, A. van den Bruinhorst, M. Watanabe and J. Wishart
Faraday Discuss., 206 (2018), 291- 337 DOI
Electrochemistry: General Discussion
A. Abbott, L. Aldous, N. Borisenko, S. Coles, O. Fontaine, J. D. G. Garcia, R. Gardas, O. Hammond, L. J. Hardwick, P. Haumesser, F. Hausen, C. Horwood, J. Jacquemin, R. Jones, E. Jónsson, A. Lahiri, D. MacFarlane, G. Marlair, B. May, H. Medhi, V. H. Paschoal, J. E. S. J. Reid, T. Schoetz, K. Tamura, M. L. Thomas, S. Tiwari, B. Uralcan, A. van den Bruinhorst, M. Watanabe and J. Wishart
Faraday Discuss., 206 (2018), 405- 426 DOI
2017
Analytical SERS: General Dicussion
H. Aitchison, J. Aizpurua, H. Arnolds, J. Baumberg, S. Bell, A. Bonifacio, R. Chikkaraddy, P. Dawson, B. de Nijs, V. Deckert, I. Delfino, G. Di Martino, O. Eremina, K. Faulds, A. Fountain, S. Gawinkowski, M. Gomez Castano, R. Goodacre, J. Gracie, D. Graham, J. Guicheteau, L. Hardwick, M. Hardy, C. Heck, L. Jamieson, M. Kamp, A. Keeler, C. Kuttner, J. Langer, S. Mahajan, N. M. Sabanés, K. Murakoshi, M. Porter, G. Schatz, S. Schlücker, Z. Tian, A. Tripathi, R. Van Duyne and P. Vikesland
Faraday Discuss., 205 (2017), 561- 600 DOI
Template-free Synthesis of Nitrogen doped Carbon Materials from an Organic Ionic Dye (Murexide) For Supercapacitor Application
M. Serwar, U. Ali Rana, H. M. Siddiqi, S. Ud-Din Khan, F. A. Ahmed Ali, A. Al-Fatesh, A. Adomkevicius, J. A. Coca-Clemente, L. Cabo-Fernandez, F. Braga and L. J. Hardwick
RSC Adv., 7 (2017), 54626- 54637 DOI
In Situ Surface-Enhanced Infrared Spectroscopy to Identify Oxygen Reduction Products in Nonaqueous Metal–Oxygen Batteries
J. Padmanabhan Vivek, N.G. Berry, J. Zou, R. J. Nichols, L. J. Hardwick
J. Phys.Chem. C, 121 (2017) 19657-19667 DOI
In Situ Raman Spectroscopic Analysis of the Lithiation and Sodiation of Antimony Microparticles
N.E. Drewett, I.M. Aldous, J. Zou, L.J. Hardwick
Electrochim. Acta., (2017) 247 (2017) 296-305, DOI
Shell Isolated Nanoparticles for Enhanced Raman Spectroscopy Studies in Lithium-Oxygen Cells
T.A. Galloway, L. Cabo-Fernandez, I.M. Aldous, F. Braga, L.J. Hardwick
Faraday Discuss., 205 (2017) 469-490 DOI
Na0.35MnO2 as an Ionic Conductor with Randomly Distributed Nano-sized Layers
A. Adomkevicius, L. Cabo-Fernandez, T.-H. Wu, T.-M. Ou, M.-G. Chen, Y. Andreev, C.-C. Hu and L.J. Hardwick
J. Mater. Chem. A., 5 (2017) 10021-10026 DOI
2016
In Situ Study of Li Intercalation into Highly Crystalline Graphitic Flakes of Varying Thicknesses
J. Zou, C. Sole, N.E. Drewett, M. Velický, L.J. Hardwick
J. Phys. Chem. Lett.,7 (2016) 4291–4296 DOI
Three-dimensional Protonic Conductivity in Porous Organic Cage Solids
Ming Liu, Linjiang Chen, Scott Lewis, Samantha Y. Chong, Marc A. Little, Tom Hasell, Iain M. Aldous, Craig M. Brown, Martin W.Smith, Carole A. Morrison, Laurence J. Hardwick and Andrew I. Cooper
Nature Commun., 7 (2016) 12750 DOI
Batteries: Avoiding oxygen
Laurence J Hardwick
Nature Energy., 1 (2016) 16115 DOI
Solvent-Mediated Control of the Electrochemical Discharge Products of Non-Aqueous Sodium-Oxygen Electrochemistry
I.M. Aldous, L.J. Hardwick
Angew. Chem. Int. Ed., 55 (2016) 8254-8257 DOI
Utilizing In Situ Electrochemical SHINERS for Oxygen Reduction Reaction Studies in Aprotic Electrolytes
T. Galloway, L.J. Hardwick
J. Phys. Chem. Lett., 7 (2016) 2119-2124 DOI
Mechanistic Insight into the Superoxide Induced Ring Opening in Propylene Carbonate Based Electrolytes using In Situ Surface-Enhanced Infrared Spectroscopy
Padmanabhan Vivek, N.G. Berry, G. Papageorgiou, R. J. Nichols, L. J. Hardwick
J. Amer. Chem. Soc., 138 (2016) 3745-3751 DOI
In Situ Raman Spectroscopy of Carbon-Coated ZnFe2O4 Anode Material in Li-ion Batteries - Investigation of SEI Growth
Laura Cabo-Fernandez, Franziska Mueller, Stefano Passerini, and Laurence J. Hardwick
Chem. Commun., 52 (2016) 3970-3973 DOI
A Highly Active Nickel Electrocatalyst shows Excellent Selectivity for CO2 Reduction in Acidic Media
Gaia Neri, Iain M. Aldous, James J. Walsh, Laurence J. Hardwick and Alexander J. Cowan
Chem. Sci., 7 (2016) 1521-1526 DOI
2015
Scaling up “Nano” Li4Ti5O12 for High-Power Lithium-Ion Anodes Using Large Scale Flame Spray Pyrolysis
A.Birrozzi, M. Copley, J. von Zamory, M.Pasqualini, S. Calcaterra, F. Nobili, A. Di Cicco, H. Rajanti, M. Briceno, E. Bilbé, L. Cabo-Fernandez, L.J. Hardwick, D Bresser, S. Passerini
J. Electrochem. Soc., 162 (2015) A2331-A2338.DOI
The Role of Re-Aggregation on the Performance of Electrochemically Exfoliated Many-Layer Graphene for Li-Ion Batteries
C. Sole, N. Drewett, F. Liu, A. Abdelkader, I. Kinloch, L.J. Hardwick
J. Electroanal. Chem., 53 (2015) 35-41 DOI PDF
Charge Storage Mechanism of Activated Manganese Oxide Composites for Pseudocapacitors
T.-H. Wu, D. Hesp, V. Dhanak, C. Collins, F. Braga, L.J. Hardwick, C.-C. Hu
J. Mater. Chem. A, 3 (2015) 12786-12795 DOI PDF
2014
Influence of Tetraalkylammonium Cation Chain Length on Gold and Glassy Carbon Electrode Interfaces for Alkali Metal–Oxygen Batteries
I.M. Aldous, L.J. Hardwick
J. Phys. Chem. Lett., 5 (2014) 3924–3930 DOI PDF ACS LiveSlidesTM
In Situ Raman Study of Lithium-Ion Intercalation into Microcrystalline Graphite
C. Sole, N. Drewett, L.J. Hardwick
Faraday Discuss., 172 (2014) 223-237 DOI PDF
Characterization of Aluminum Doped Lithium-Manganese Rich Composites for Higher Rate Lithium-Ion Cathodes
M. Iftekhar, N.E. Drewett, A.R. Armstrong, D. Hesp, F. Braga, S. Ahmed, L.J. Hardwick
J. Electrochem. Soc., 161 (2014) A2109-A2116 DOI PDF
Electrochemical Performance of Laser Microstructured Nickel Oxyhydroxide Cathodes
A.R. Neale, Y. Jin, J. Ouyang, S. Hughes, D. Hesp, V. Dhanak, G. Dearden, S. Edwardson, L.J. Hardwick
J. Power Sources, 271 (2014) 42-47 DOI PDF
2013
Important Parameters Affecting the Cell Voltage of Aqueous Electrical Double-Layer Capacitors
T.-H. Wu, Y.-H. Chu, C.-C. Hu, L.J. Hardwick
J. Power Sources, 242 (2013) 289-298 DOI PDF
Criteria Appointing the Highest Acceptable Cell Voltage of Asymmetric Supercapacitors
T.-H. Wu, Y.-H. Chu, C.-C. Hu, L.J. Hardwick
Electrochem. Commun., 27 (2013) 81-84 DOI PDF
2012
Direct Detection of Discharge Products in Lithium-Oxygen Batteries by Solid-State NMR Spectroscopy
M. Leskes, N. Drewett, L.J. Hardwick, P.G. Bruce, G.R. Goward, C.P. Grey
Angew. Chem. Int. Ed., 51 (2012) 8560-8563 DOI PDF
Lithium Insertion into Anatase Nanotubes
V. Gentili, S. Brutti, L.J. Hardwick, A.R. Armstrong, S. Panero, B. Scrosati, P.G. Bruce
Chem. Mater, 24 (2012) 4468-4476 DOI PDF
The Pursuit of Rechargeable Non-Aqueous Lithium-Oxygen Battery Cathodes
L.J. Hardwick, P.G. Bruce
Curr. Opin Solid St. M., 16 (2012) 178-185 DOI PDF
Li-O2 and Li-S Batteries with High Energy Storage
P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.-M. Tarascon
Nature Mater., 11 (2012) 19-29 DOI PDF
2011
The Lithium-Oxygen Battery with Ether-Based Electrolytes
S. Freunberger, Y. Chen, N. Drewett, L.J. Hardwick, F. Bardé, P.G. Bruce
Angew. Chem. Int. Ed., 50 (2011) 8609-8613 DOI PDF
Oxygen Reactions in a Non-Aqueous Li+ Electrolyte
Z. Peng, S. Freunberger, L.J. Hardwick, Y. Chen, V. Giordani, F. Bardé, P. Novák, J.-M. Tarascon, D. Graham, P.G. Bruce
Angew. Chem. Int. Ed., 50 (2011) 6351-6355 DOI PDF
Lithium-Air and Lithium-Sulfur Batteries
P.G. Bruce, L.J. Hardwick, K.M. Abraham
MRS Bull., 36 (2011) 506-512 DOI PDF
Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes
S. Freunberger, Y. Chen, Z. Peng, J. Griffin, L.J. Hardwick, F. Bardé, P. Novák, P.G. Bruce
J. Amer. Chem. Soc., 133 (2011) 8040-8047 DOI PDF
Activated Lithium-Metal-Oxides as Catalytic Electrodes for Li-O2 Cells
L. Trahey, C.S. Johnson, J.T. Vaughey, S.-H. Kang, L.J. Hardwick, S.A. Freunberger, P.G. Bruce, M.M. Thackeray
Electrochem. Solid-State Letts., 14 (2011) A64-A66 DOI
2010
Lithium Diffusion in Graphitic Carbon
K. Persson, V.A. Sethuraman, L.J. Hardwick, Y. Hinuma, Y. Meng, A. Van Der Ven, V. Srinivasan, R. Kostecki, G. Ceder
J. Phys. Chem. Lett., 1 (2010) 1176-1180 DOI PDF
Lithium Intercalation into Mesoporous Anatase with an Ordered 3D Pore Structure
Y. Ren, L.J. Hardwick, P.G. Bruce
Angew. Chem. Int. Ed., 49 (2010) 2570-2574 DOI PDF
Surface Structural Disordering in Graphite upon Lithium Intercalation/Deintercalation
V.A. Sethuraman, L.J. Hardwick, V. Srinivasan, R. Kostecki
J. Power Sources, 195 (2010) 3655-3660 DOI PDF
Microwave Plasma Chemical Vapor Deposition of Graphitic Carbon Thin Films
M. Marcinek, L.J. Hardwick, G.Z. Zukowska, R. Kostecki
Carbon, 48 (2010) 1552-1557 DOI PDF
2009
Electrochemical Doping of Single Walled Carbon Nanotubes in Double Layer Capacitors Studied by In Situ Raman Spectroscopy
P.W. Ruch, L.J. Hardwick, M. Hahn, A. Foelske, R. Kötz, A. Wokaun
Carbon, 47 (2009) 38-52 DOI PDF
FTIR and Raman Study of the LixTiyMn1-yO2 (y=0, 0.11) Cathodes in Methylpropyl Pyrrolidinium Bis(fluoro-sulfonyl)imide, LiTFSI Electrolyte
L.J. Hardwick, J. Saint, I.T. Lucas, M. Doeff, R. Kostecki
J. Electrochem. Soc., 156 (2009) A120-A127 DOI
2008
An Investigation of the Effect of Graphite Degradation on Irreversible Capacity in Lithium-Ion Cells
L.J. Hardwick, M. Marcinek, L. Beer, J. Kerr, R. Kostecki
J. Electrochem. Soc., 155 (2008) A442-A447 DOI
In Situ Raman Spectroscopy of Insertion Electrodes for Lithium-Ion Batteries and Supercapacitors: First Cycle Effects
L.J. Hardwick, P. Ruch, M. Hahn, W. Scheifele, R. Kötz, P. Novák
J. Phys. Chem. Solids., 69 (2008) 1232-1237 DOI PDF
2007
Electrochemical Lithium Insertion into TiO2 Anatase Materials: An In Situ Raman Microscopy Investigation
L.J. Hardwick, M. Holzapfel, P. Novák, L. Dupont, E. Baudrin
Electrochim. Acta, 52 (2007) 5357-5367 DOI PDF
Microwave Plasma Chemical Vapor Deposition of Nano-Structured Sn/C Composite Thin-Film Anodes for Li-Ion Batteries
M. Marcinek, L.J. Hardwick, T.J. Richardson, X. Song, R. Kostecki
J. Power Sources, 173 (2007) 965-971 DOI PDF
Behaviour of Highly Crystalline Graphitic Materials in Lithium-Ion Cells with Propylene Carbonate containing Electrolytes: An In Situ Raman and SEM Study
L.J. Hardwick, H. Buqa, M. Holzapfel, W. Scheifele, F. Krumeich, P. Novák
Electrochim. Acta, 52 (2007) 4884-4891 DOI PDF
Raman Study of Lithium Coordination in EMI-TFSI Additive Systems as Lithium-Ion Battery Ionic Liquid Electrolytes
L.J. Hardwick, M. Holzapfel, A. Wokaun, P. Novák
J. Raman Spectrosc., 38 (2007) 110-112 DOI PDF
2006
Nano Silicon for Lithium-Ion Batteries
M. Holzapfel, H. Buqa, L.J. Hardwick, M. Hahn, F. Krumeich, A. Würsig, W. Scheifele, P. Novák, R. Kötz, C. Veit, F. Petrat
Electrochim. Acta, 52 (2006) 973-978 DOI PDF
Graphite Surface Disorder Detection using In Situ Raman Microscopy
L.J. Hardwick, H. Buqa, P. Novák
Solid State Ion., 177 (2006) 2801-2806 DOI PDF
An In Situ Raman Study of the Intercalation of Supercapacitor-Type Electrolyte into Microcrystalline Graphite
L.J. Hardwick, M. Hahn, P. Ruch, M. Holzapfel, W. Scheifele, H. Buqa, F. Krumeich, P. Novák, R. Kötz
Electrochim. Acta, 52 (2006) 675-680 DOI PDF
Surface Reactivity of Graphite Materials and their Surface Passivation during the First Electrochemical Lithium Insertion
M.E. Spahr, H. Buqa, A. Würsig, D. Goers, L.J. Hardwick, P. Novák, F. Krumeich, J. Dentzer, C. Vix-Guterl
J. Power Sources, 153 (2006) 300-311 DOI PDF
2005
Behaviour of Highly Crystalline Graphites in Lithium-Ion Cells with Propylene Carbonate containing Electrolytes
H. Buqa, A. Würsig, D. Goers, L.J. Hardwick, M. Holzapfel, P. Novák, F. Krumeich, M.E. Spahr
J. Power Sources, 146 (2005) 134-141 DOI PDF
Advanced In Situ Characterization Methods Applied to Carbonaceous Materials
P. Novák, D. Goers, L. Hardwick, M. Holzapfel, W. Scheifele, J. Ufheil, A. Würsig
J. Power Sources, 146 (2005) 15-20 DOI PDF
2003
Raman Spectroscopic and Structural Studies of Heat-Treated Graphites for Lithium-Ion Batteries
D. Goers, H. Buqa, L. Hardwick, A. Würsig, P. Novák
Ionics, 9 (2003) 258-265 DOI PDF