Overview
This project uses robotics to accelerate the discovery of multicomponent metal-organic frameworks (MOFs) for carbon capture and clean catalysis. It combines automated synthesis, advanced characterisation, and data analysis to identify promising porous materials, preparing researchers for future industrial and academic roles in sustainable materials science.
About this opportunity
New porous materials are important for advances in key technologies such as carbon dioxide sequestration and storage or catalysts for clean manufacturing. The assembly of multiple metal and organic linkers in the well-defined and complex crystal structures of multicomponent metal organic frameworks (MOFs) will deliver materials with enhanced properties. However, at present we do not have the experimental tools with the scale and speed to efficiently explore the vast chemical space available. This project will harness recent advances in robotics to efficiently explore the discovery of new multicomponent MOFs. The student will design and execute experiments on state-of-the-art robotic synthesis platforms, develop the required measurement approaches to extract and analyse data from the arrays of materials.
Training in robotics, chemistry and structural characterisation will be given. The project will develop protocols to identify materials with potential application gas separation (focusing on capturing carbon dioxide from flue gas and challenging separations of hydrocarbons) and catalysis (transformation of biomass for next-generation clean manufacturing) applications that will focus the large numbers of new materials identified for further detailed exploration. The project is driven by a vision of a future where research scientists will make routine, broad use of robotics as part of the discovery of advanced materials, and thus the project will prepare the student for a wide range of industrial and academic career opportunities. Experimental work will be enabled by instrumentation and methods that are already established and available in the research group of Prof Rosseinsky, together with world-class characterization and synthetic facilities available within the Materials Innovation Factory.
Further reading
[1] G. S. G. Farmer, D. J. Cheney, K-N Truong, N. Gedikoglu, B. P. Mali, D. Markad, D. Antypov, F.Blanc, A. P. Katsoulidis, M. J. Rosseinsky, Ordering Bent and Straight Dicarboxylate Linkers in an fcu Zirconium Metal–Organic Framework, J. Am. Chem. Soc. 2025, 147, 31, 27586–27598
[2] A. M. Tollitt, R. Vismara, L. M. Daniels, D. Antypov, M. W. Gaultois, A. P. Katsoulidis, M. J.Rosseinsky, High-Throughput Discovery of Rhombohedral Twelve Connected Zirconium Metal-Organic Framework with Ordered Terephthalate and Fumarate Linkers, Angewandte Chemie International Edition, 60 (2021) 26939-26946.