Research outputs
2025
Ethynyl Substituents as Rheostatic Triggers in Single-Molecule Junctions
Metal ion independent conductance through bis-chelated metal complex molecular wires based on a bis(diphenylphosphino)aniline derivative
Gatto, M. F., Sangtarash, S., Jago, D., Abram, R. T., Barrett, E., Sil, A., . . . Vezzoli, A. (2025). Metal ion independent conductance through bis-chelated metal complex molecular wires based on a bis(diphenylphosphino)aniline derivative. Dalton Transactions, 54(19), 7874-7881. doi:10.1039/d5dt00292c
Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis
Morris, J. M. F., Potter, J., Bates, D., Wu, C., Robertson, C. M., Higgins, S. J., . . . Vezzoli, A. (2025). Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis. The Journal of Physical Chemistry C. doi:10.1021/acs.jpcc.4c07780
Single‐Molecule Mechanoresistivity by Intermetallic Bonding
Sil, A., Spano, C. E., Chelli, Y., Higgins, S. J., Sangtarash, S., Piccinini, G., . . . Vezzoli, A. (2025). Single‐Molecule Mechanoresistivity by Intermetallic Bonding. Angewandte Chemie International Edition, 64(6). doi:10.1002/anie.202418062
2024
Zero‐Bias Anti‐Ohmic Behaviour in Diradicaloid Molecular Wires
Sil, A., Hamilton, L., Morris, J. M. F., Daaoub, A. H. S., Burrows, J. H. H., Robertson, C. M., . . . Vezzoli, A. (2024). Zero‐Bias Anti‐Ohmic Behaviour in Diradicaloid Molecular Wires. Angewandte Chemie International Edition, 63(44). doi:10.1002/anie.202410304
A Systematic Study of Methyl Carbodithioate Esters as Effective Gold Contact Groups for Single‐Molecule Electronics
Ward, J. S., Vezzoli, A., Wells, C., Bailey, S., Jarvis, S. P., Lambert, C. J., . . . Higgins, S. J. (2024). A Systematic Study of Methyl Carbodithioate Esters as Effective Gold Contact Groups for Single‐Molecule Electronics. Angewandte Chemie International Edition, 63(31). doi:10.1002/anie.202403577
Mechanical Manipulation of Quantum Interference in Single‐Molecule Junctions
Sil, A., Alsaqer, M., Spano, C. E., Larbi, A., Higgins, S. J., Robertson, C. M., . . . Vezzoli, A. (2024). Mechanical Manipulation of Quantum Interference in Single‐Molecule Junctions. Small, 20(25). doi:10.1002/smll.202308865
Nuclear Magnetic Resonance Chemical Shift as a Probe for Single‐Molecule Charge Transport
Qiao, X., Sil, A., Sangtarash, S., Smith, S. M., Wu, C., Robertson, C. M., . . . Vezzoli, A. (2024). Nuclear Magnetic Resonance Chemical Shift as a Probe for Single‐Molecule Charge Transport. Angewandte Chemie International Edition, 63(19). doi:10.1002/anie.202402413
An Orthogonal Conductance Pathway in Spiropyrans for Well‐Defined Electrosteric Switching Single‐Molecule Junctions
Jago, D., Liu, C., Daaoub, A. H. S., Gaschk, E., Walkey, M. C., Pulbrook, T., . . . Koutsantonis, G. A. (2024). An Orthogonal Conductance Pathway in Spiropyrans for Well‐Defined Electrosteric Switching Single‐Molecule Junctions. Small, 20(8). doi:10.1002/smll.202306334
2023
Connectivity-Dependent Conductance of 2,2'-Bipyridine-Based Metal Complexes.
Chelli, Y., Ferri, N., Vezzoli, A., Davidson, R. J., Morris, J., Nichols, R. J., . . . Beeby, A. (2023). Connectivity-Dependent Conductance of 2,2'-Bipyridine-Based Metal Complexes.. ACS omega, 8(51), 48958-48965. doi:10.1021/acsomega.3c06555
Single-Molecule Conductance Behavior of Molecular Bundles.
Bara-Estaún, A., Planje, I. J., Almughathawi, R., Naghibi, S., Vezzoli, A., Milan, D. C., . . . Beeby, A. (2023). Single-Molecule Conductance Behavior of Molecular Bundles.. Inorganic chemistry, 62(51), 20940-20947. doi:10.1021/acs.inorgchem.3c01943
Evaluation of the 5-ethynyl-1,3,3-trimethyl-3H-indole ligand for molecular materials applications
Jago, D., Milan, D. C., Sobolev, A. N., Higgins, S. J., Vezzoli, A., Nichols, R. J., & Koutsantonis, G. A. (2023). Evaluation of the 5-ethynyl-1,3,3-trimethyl-3H-indole ligand for molecular materials applications. Australian Journal of Chemistry, 76(4), 209-230. doi:10.1071/ch23069
Single-Molecule Junction Formation in Deep Eutectic Solvents with Highly Effective Gate Coupling
Qiao, X., Vezzoli, A., Smith, S., Higgins, S. J., Davidson, R. J., Beeby, A., & Nichols, R. J. (2023). Single-Molecule Junction Formation in Deep Eutectic Solvents with Highly Effective Gate Coupling. The Journal of Physical Chemistry C, 127(26), 12802-12810. doi:10.1021/acs.jpcc.3c03129
Not So Innocent After All: Interfacial Chemistry Determines Charge‐Transport Efficiency in Single‐Molecule Junctions
Daaoub, A., Morris, J. M. F., Béland, V. A., Demay‐Drouhard, P., Hussein, A., Higgins, S. J., . . . Sangtarash, S. (2023). Not So Innocent After All: Interfacial Chemistry Determines Charge‐Transport Efficiency in Single‐Molecule Junctions. Angewandte Chemie, 135(24). doi:10.1002/ange.202302150
Sheathed Molecular Junctions for Unambiguous Determination of Charge‐Transport Properties
Herrer, L., Naghibi, S., Marín, I., Ward, J. S., Bonastre, J. M., Higgins, S. J., . . . Cea, P. (2023). Sheathed Molecular Junctions for Unambiguous Determination of Charge‐Transport Properties. Advanced Materials Interfaces, 10(16). doi:10.1002/admi.202300133
Not So Innocent After All: Interfacial Chemistry Determines Charge-Transport Efficiency in Single-Molecule Junctions.
Daaoub, A., Morris, J. M. F., Béland, V. A., Demay-Drouhard, P., Hussein, A., Higgins, S. J., . . . Sangtarash, S. (2023). Not So Innocent After All: Interfacial Chemistry Determines Charge-Transport Efficiency in Single-Molecule Junctions.. Angewandte Chemie (International ed. in English), e202302150. doi:10.1002/anie.202302150
Ordered arrays of gold nanoparticles crosslinked by dithioacetate linkers for molecular devices
Asaad, M., Vezzoli, A., Daaoub, A., Borowiec, J., Pyurbeeva, E., Sadeghi, H., . . . Mol, J. A. (2023). Ordered arrays of gold nanoparticles crosslinked by dithioacetate linkers for molecular devices. Journal of Materials Chemistry C, 11(16), 5431-5437. doi:10.1039/d3tc00145h
Enhanced charge transport across molecule-nanoparticle-molecule sandwiches
Zhou, P., Qiao, X., Milan, D. C., Higgins, S. J., Vezzoli, A., & Nichols, R. J. (2023). Enhanced charge transport across molecule-nanoparticle-molecule sandwiches. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 25(10), 7176-7183. doi:10.1039/d2cp05525b
Ordered Arrays of Gold Nanoparticles Crosslinked by Dithioacetate Linkers for Molecular devices
2022
Enhanced charge transport across molecule-nanoparticle-molecule sandwiches
Nichols, R., & Zhou, P. (n.d.). Enhanced charge transport across molecule-nanoparticle-molecule sandwiches. doi:10.17638/datacat.liverpool.ac.uk/1853
2,7-and 4,9-Dialkynyldihydropyrene Molecular Switches: Syntheses, Properties, and Charge Transport in Single-Molecule Junctions
Roemer, M., Gillespie, A., Jago, D., Costa-Milan, D., Alqahtani, J., Hurtado-Gallego, J., . . . Koutsantonis, G. A. (2022). 2,7-and 4,9-Dialkynyldihydropyrene Molecular Switches: Syntheses, Properties, and Charge Transport in Single-Molecule Junctions. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. doi:10.1021/jacs.2c02289
Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical**
Naghibi, S., Sangtarash, S., Kumar, V. J., Wu, J., Judd, M. M., Qiao, X., . . . Vezzoli, A. (2022). Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical**. Angewandte Chemie, 134(23). doi:10.1002/ange.202116985
Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical**
Naghibi, S., Sangtarash, S., Kumar, V. J., Wu, J., Judd, M. M., Qiao, X., . . . Vezzoli, A. (2022). Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical**. Angewandte Chemie International Edition, 61(23). doi:10.1002/anie.202116985
Electrochemical gating for single-molecule electronics with hybrid Au|graphene contacts.
Tao, S., Zhang, Q., Vezzoli, A., Zhao, C., Zhao, C., Higgins, S. J., . . . Yang, L. (2022). Electrochemical gating for single-molecule electronics with hybrid Au|graphene contacts.. Physical Chemistry Chemical Physics : PCCP. doi:10.1039/d1cp05486d
2021
A Peierls Transition in Long Polymethine Molecular Wires: Evolution of Molecular Geometry and Single-Molecule Conductance.
Xu, W., Leary, E., Sangtarash, S., Jirasek, M., González, M. T., Christensen, K. E., . . . Anderson, H. L. (2021). A Peierls Transition in Long Polymethine Molecular Wires: Evolution of Molecular Geometry and Single-Molecule Conductance.. Journal of the American Chemical Society, 143(48), 20472-20481. doi:10.1021/jacs.1c10747
Corrigendum: Unusual Length Dependence of the Conductance in Cumulene Molecular Wires
Xu, W., Leary, E., Hou, S., Sangtarash, S., González, M. T., Rubio‐Bollinger, G., . . . Anderson, H. L. (2021). Corrigendum: Unusual Length Dependence of the Conductance in Cumulene Molecular Wires. Angewandte Chemie International Edition, 60(17), 9170. doi:10.1002/anie.202102667
Molecular Structure-(Thermo)electric Property Relationships in Single-Molecule Junctions and Comparisons with Single- and Multiple-Parameter Models.
Naher, M., Milan, D. C., Al-Owaedi, O. A., Planje, I. J., Bock, S., Hurtado-Gallego, J., . . . Low, P. J. (2021). Molecular Structure-(Thermo)electric Property Relationships in Single-Molecule Junctions and Comparisons with Single- and Multiple-Parameter Models.. Journal of the American Chemical Society. doi:10.1021/jacs.0c11605
Selective Anchoring Groups for Molecular Electronic Junctions with ITO Electrodes.
Planje, I. J., Davidson, R. J., Vezzoli, A., Daaoub, A., Sangtarash, S., Sadeghi, H., . . . Nichols, R. J. (2021). Selective Anchoring Groups for Molecular Electronic Junctions with ITO Electrodes.. ACS Sensors. doi:10.1021/acssensors.0c02205
2020
Folding a Single-Molecule Junction
Wu, C., Bates, D., Sangtarash, S., Ferri, N., Thomas, A., Higgins, S. J., . . . Vezzoli, A. (2020). Folding a Single-Molecule Junction. Nano Letters, 20(11), 7980-7986. doi:10.1021/acs.nanolett.0c02815
Long-lived charged states of single porphyrin-tape junctions under ambient conditions
Leary, E., Kastlunger, G., Limburg, B., Rincon-Garcia, L., Hurtado-Gallego, J., Gonzalez, M. T., . . . Nichols, R. J. (2020). Long-lived charged states of single porphyrin-tape junctions under ambient conditions. Nanoscale Horizons, 6(1), 49-58. doi:10.1039/d0nh00415d
Determining plasmonic hot-carrier energy distributions via single-molecule transport measurements
Reddy, H., Wang, K., Kudyshev, Z., Zhu, L., Yan, S., Vezzoli, A., . . . Meyhofer, E. (2020). Determining plasmonic hot-carrier energy distributions via single-molecule transport measurements. SCIENCE, 369(6502), 423-426. doi:10.1126/science.abb3457
A Chemically Soldered Polyoxometalate Single‐Molecule Transistor
Wu, C., Qiao, X., Robertson, C. M., Higgins, S. J., Cai, C., Nichols, R. J., & Vezzoli, A. (2020). A Chemically Soldered Polyoxometalate Single‐Molecule Transistor. Angewandte Chemie International Edition, 59(29), 12029-12034. doi:10.1002/anie.202002174
In situ formation of H-bonding imidazole chains in break-junction experiments
Wu, C., Alqahtani, A., Sangtarash, S., Vezzoli, A., Sadeghi, H., Robertson, C. M., . . . Nichols, R. J. (2020). In situ formation of H-bonding imidazole chains in break-junction experiments. Nanoscale, 2020(14), 7914-7920. doi:10.1039/d0nr00630k
Conductance Behavior of Tetraphenyl-Aza-BODIPYs
Markin, A., Ismael, A. K., Davidson, R. J., Milan, D. C., Nichols, R. J., Higgins, S. J., . . . Beeby, A. (2020). Conductance Behavior of Tetraphenyl-Aza-BODIPYs. The Journal of Physical Chemistry C, 124(12), 6479-6485. doi:10.1021/acs.jpcc.9b10232
A chemically soldered polyoxometalate single-molecule transistor
Wu, C., Qiao, X., Robertson, C. M., Higgins, S. J., Cai, C., Nichols, R. J., & Vezzoli, A. (2020). A chemically soldered polyoxometalate single-molecule transistor. Angewandte Chemie. doi:10.1002/ange.202002174
2019
Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics
Ferri, N., Algethami, N., Vezzoli, A., Sangtarash, S., McLaughlin, M., Sadeghi, H., . . . Higgins, S. J. (2019). Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics. Angewandte Chemie, 131(46), 16736-16742. doi:10.1002/ange.201906400
Innenrücktitelbild: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. 46/2019)
Ferri, N., Algethami, N., Vezzoli, A., Sangtarash, S., McLaughlin, M., Sadeghi, H., . . . Higgins, S. J. (2019). Innenrücktitelbild: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. 46/2019). Angewandte Chemie, 131(46), 16851. doi:10.1002/ange.201913163
Inside Back Cover: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. Int. Ed. 46/2019)
Ferri, N., Algethami, N., Vezzoli, A., Sangtarash, S., McLaughlin, M., Sadeghi, H., . . . Higgins, S. J. (2019). Inside Back Cover: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. Int. Ed. 46/2019). Angewandte Chemie International Edition, 58(46), 16697. doi:10.1002/anie.201913163
Conductance behavior of tetraphenyl-aza-BODIPYs
Costa Milan, D., & Nichols, R. (n.d.). Conductance behavior of tetraphenyl-aza-BODIPYs. doi:10.17638/datacat.liverpool.ac.uk/973
Synthetic Control of Quantum Interference by Regulating Charge on a Single Atom in Heteroaromatic Molecular Junctions.
Naghibi, S., Ismael, A. K., Vezzoli, A., Al-Khaykanee, M. K., Zheng, X., Grace, I. M., . . . Nichols, R. J. (2019). Synthetic Control of Quantum Interference by Regulating Charge on a Single Atom in Heteroaromatic Molecular Junctions.. The journal of physical chemistry letters. doi:10.1021/acs.jpclett.9b02319
Hemilabile ligands as mechanosensitive electrode contacts for molecular electronics
Ferri, N., Algethami, N., Vezzoli, A., Sangtarash, S., McLaughlin, M., Sadeghi, H., . . . Higgins, S. (2019). Hemilabile ligands as mechanosensitive electrode contacts for molecular electronics. Angewandte Chemie (International Edition), 58(46), 16583-16589. doi:10.1002/anie.201906400
Cross-conjugation increases the conductance of <i>meta</i>-connected fluorenones
Alanazy, A., Leary, E., Kobatake, T., Sangtarash, S., González, M. T., Jiang, H. -W., . . . Lambert, C. J. (2019). Cross-conjugation increases the conductance of <i>meta</i>-connected fluorenones. Nanoscale, 11(29), 13720-13724. doi:10.1039/c9nr01235d
Unusual Length Dependence of the Conductance in Cumulene Molecular Wires.
Xu, W., Leary, E., Hou, S., Sangtarash, S., González, M. T., Rubio‐Bollinger, G., . . . Anderson, H. L. (2019). Unusual Length Dependence of the Conductance in Cumulene Molecular Wires. Angewandte Chemie International Edition, 58(25), 8378-8382. doi:10.1002/anie.201901228
Charge transfer complexation boosts molecular conductance through Fermi level pinning
Wang, K., Vezzoli, A., Grace, I. M., McLaughlin, M., Nichols, R. J., Xu, B., . . . Higgins, S. J. (2019). Charge transfer complexation boosts molecular conductance through Fermi level pinning. Chemical Science, 10(8), 2396-2403. doi:10.1039/c8sc04199g
2018
Large-Amplitude, High-Frequency Single-Molecule Switch
Ferri, N., Algethami, N., Vezzoli, A., Sangtarash, S., McLaughlin, M., Sadeghi, H., . . . Higgins, S. (2018). Large-Amplitude, High-Frequency Single-Molecule Switch. doi:10.26434/chemrxiv.7275005.v1
Bias-Driven Conductance Increase with Length in Porphyrin Tapes
Leary, E. L. (2018). Bias-Driven Conductance Increase with Length in Porphyrin Tapes. Journal of the American Chemical Society, 140(40), 12877-12883. doi:10.1021/jacs.8b06338
Charge Transfer Complexation Boosts Molecular Conductance Through Fermi Level Pinning
Wang, K., Vezzoli, A., Grace, I., McLaughlin, M., Nichols, R., Xu, B., . . . Higgins, S. (2018). Charge Transfer Complexation Boosts Molecular Conductance Through Fermi Level Pinning. doi:10.26434/chemrxiv.7110788.v1
Dual control of chemical equilibria through pH and potential in single-molecule devices
Brooke, R., Szumski, D., Vezzoli, A., Higgins, S., Nichols, R., & Schwarzacher, W. (2018). Dual control of chemical equilibria through pH and potential in single-molecule devices. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 255. Retrieved from http://gateway.webofknowledge.com/
Gating of junction conductance by charge transfer complex formation in single molecule devices
Vezzoli, A., Wang, K., Grace, I., Nichols, R., Lambert, C., Xu, B., & Higgins, S. (2018). Gating of junction conductance by charge transfer complex formation in single molecule devices. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 255. Retrieved from https://www.webofscience.com/
Structural design of single-molecule junctions with electromechanical switching properties
Vezzoli, A., Wang, K., Ismael, A. K., Grace, I., Lambert, C., Xu, B., . . . Nichols, R. (2018). Structural design of single-molecule junctions with electromechanical switching properties. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 255. Retrieved from https://www.webofscience.com/
Dual Control of Molecular Conductance through pH and Potential in Single-Molecule Devices
Brooke, R. J., Szumski, D. S., Vezzoli, A., Higgins, S. J., Nichols, R. J., & Schwarzacher, W. (2018). Dual Control of Molecular Conductance through pH and Potential in Single-Molecule Devices. Nano Letters, 18(2), 1317-1322. doi:10.1021/acs.nanolett.7b04995
Gateway state-mediated, long-range tunnelling in molecular wires
Sangtarash, S., Vezzoli, A., Sadeghi, H., Ferrib, N., OBrien, H. M., Gracea, I., . . . Lambert, C. J. (2018). Gateway state-mediated, long-range tunnelling in molecular wires. Nanoscale, 10(6), 3060-3067. doi:10.1039/C7NR07243K
Metal/molecule/metal junction studies of organometallic and coordination complexes; What can transition metals do for molecular electronics?
Higgins, S. J., & Nichols, R. J. (2018). Metal/molecule/metal junction studies of organometallic and coordination complexes; What can transition metals do for molecular electronics?. Polyhedron, 140, 25-34. doi:10.1016/j.poly.2017.10.022
Detecting Mechanochemical Atropisomerization within an STM Break Junction
Leary, E., Roche, C., Jiang, H. -W., Grace, I., González, M. T., Rubio-Bollinger, G., . . . Nichols, R. J. (2018). Detecting Mechanochemical Atropisomerization within an STM Break Junction. Journal of the American Chemical Society, 140(2), 710-718. doi:10.1021/jacs.7b10542
Charge Transfer in Single Molecules at Electrochemical Interfaces
Nichols, R. J., & Higgins, S. J. (2018). Charge Transfer in Single Molecules at Electrochemical Interfaces. In Encyclopedia of Interfacial Chemistry (pp. 15-23). Elsevier. doi:10.1016/b978-0-12-409547-2.13616-9
Charge Transport at a Molecular GaAs Nanoscale Junction
Vezzoli, A., Brooke, R., Ferri, N., Brooke, C., Higgins, S., Schwarzacher, W., & Nichols, R. (2018). Charge Transport at a Molecular GaAs Nanoscale Junction. Faraday Discussions. doi:10.1039/C8FD00016F
Conductance of ‘bare-bones’ tripodal molecular wires
Davidson, R. J., Milan, D. C., Al-Owaedi, O. A., Ismael, A. K., Nichols, R. J., Higgins, S. J., . . . Beeby, A. (2018). Conductance of ‘bare-bones’ tripodal molecular wires. RSC Advances, 8(42), 23585-23590. doi:10.1039/c8ra01257a
2017
Influence of surface coverage on the formation of 4,4 '- bipyridinium (viologen) single molecular junctions
Osorio, H. M., Martin, S., Milan, D. C., Gonzalez-Orive, A., Gluyas, J. B. G., Higgins, S. J., . . . Cea, P. (2017). Influence of surface coverage on the formation of 4,4 '- bipyridinium (viologen) single molecular junctions. JOURNAL OF MATERIALS CHEMISTRY C, 5(45), 11717-11723. doi:10.1039/c7tc03624h
Side Group-Mediated Mechanical Conductance Switching in Molecular Junctions
Ismael, A. K., Wang, K., Vezzoli, A., Al-Khaykanee, M., Gallagher, H., Grace, I., . . . Higgins, S. (2017). Side Group-Mediated Mechanical Conductance Switching in Molecular Junctions. Angewandte Chemie (International Edition), 56(48), 15378-15382. doi:10.1002/anie.201709419
Side‐Group‐Mediated Mechanical Conductance Switching in Molecular Junctions
Ismael, A. K., Wang, K., Vezzoli, A., Al‐Khaykanee, M. K., Gallagher, H. E., Grace, I. M., . . . Higgins, S. J. (2017). Side‐Group‐Mediated Mechanical Conductance Switching in Molecular Junctions. Angewandte Chemie, 129(48), 15580-15584. doi:10.1002/ange.201709419
Single-Molecule Photocurrent at a Metal–Molecule–Semiconductor Junction
Vezzoli, A., Brooke, R. J., Higgins, S. J., Schwarzacher, W., & Nichols, R. J. (2017). Single-Molecule Photocurrent at a Metal–Molecule–Semiconductor Junction. Nano Letters, 17(11), 6702-6707. doi:10.1021/acs.nanolett.7b02762
Side Group-Mediated Mechanical Conductance Switching in Molecular Junctions
Vezzoli, A., Higgins, S., & Nichols, R. (n.d.). Side Group-Mediated Mechanical Conductance Switching in Molecular Junctions. doi:10.17638/datacat.liverpool.ac.uk/405
Detecting mechanochemical atropisomerization within an STM breakjunction
Leary, E. (n.d.). Detecting mechanochemical atropisomerization within an STM breakjunction. doi:10.17638/datacat.liverpool.ac.uk/398
Single molecule electrochemistry in nanoscale junctions
Nichols, R. J., & Higgins, S. J. (2017). Single molecule electrochemistry in nanoscale junctions. Current Opinion in Electrochemistry, 4(1), 98-104. doi:10.1016/j.coelec.2017.09.009
Insulated molecular wires: inhibiting orthogonal contacts in metal complex based molecular junctions
Al-Owaedi, O. A., Bock, S., Milan, D. C., Oerthel, M. -C., Inkpen, M. S., Yufit, D. S., . . . Low, P. J. (2017). Insulated molecular wires: inhibiting orthogonal contacts in metal complex based molecular junctions. Nanoscale, 9(28), 9902-9912. doi:10.1039/c7nr01829k
Soft versus hard junction formation for α-terthiophene molecular wires and their charge transfer complexes
Vezzoli, A., Grace, I. M., Brooke, C., Nichols, R. J., Lambert, C. J., & Higgins, S. J. (2017). Soft versus hard junction formation for α-terthiophene molecular wires and their charge transfer complexes. The Journal of Chemical Physics, 146(9). doi:10.1063/1.4969077
Single‐Molecule Conductance Studies of Organometallic Complexes Bearing 3‐Thienyl Contacting Groups
Bock, S., Al‐Owaedi, O. A., Eaves, S. G., Milan, D. C., Lemmer, M., Skelton, B. W., . . . Low, P. J. (2017). Single‐Molecule Conductance Studies of Organometallic Complexes Bearing 3‐Thienyl Contacting Groups. Chemistry – A European Journal, 23(9), 2133-2143. doi:10.1002/chem.201604565
Single-Molecule Transport at a Rectifying GaAs Contact
Vezzoli, A., Brooke, R. J., Ferri, N., Higgins, S. J., Schwarzacher, W., & Nichols, R. J. (2017). Single-Molecule Transport at a Rectifying GaAs Contact. Nano Letters, 17(2), 1109-1115. doi:10.1021/acs.nanolett.6b04663
The single-molecule electrical conductance of a rotaxane-hexayne supramolecular assembly
Milan, D. C., Krempe, M., Ismael, A. K., Movsisyan, L. D., Franz, M., Grace, I., . . . Nichols, R. J. (2017). The single-molecule electrical conductance of a rotaxane-hexayne supramolecular assembly. Nanoscale, 9(1), 355-361. doi:10.1039/c6nr06355a
Synthesis and characterization of [MCl2(PAr3)2]–ethylenedioxythiophene copolymers (M = Pd, Pt), made by electropolymerisation of diphenyl(2,2′,3,3′-tetrahydro-[5,5′-bithieno[3,4-b][1,4]dioxin]-7-yl)phosphane (Ph2P[bis-EDOT]) complexes
Velauthamurty, K., Rajapakse, R. M. G., & Higgins, S. J. (2017). Synthesis and characterization of [MCl2(PAr3)2]–ethylenedioxythiophene copolymers (M = Pd, Pt), made by electropolymerisation of diphenyl(2,2′,3,3′-tetrahydro-[5,5′-bithieno[3,4-b][1,4]dioxin]-7-yl)phosphane (Ph2P[bis-EDOT]) complexes. Inorganica Chimica Acta, 464, 59-64. doi:10.1016/j.ica.2017.04.035
2016
Electrochemically grafted single molecule junctions exploiting a chemical protection strategy
Liang, J., Smith, R. E. G., Vezzoli, A., Xie, L., Milan, D. C., Davidson, R., . . . Nichols, R. J. (2016). Electrochemically grafted single molecule junctions exploiting a chemical protection strategy. Electrochimica Acta, 220, 436-443. doi:10.1016/j.electacta.2016.10.095
Single Molecule Nanoelectrochemistry in Electrical Junctions
Nichols, R. J., & Higgins, S. J. (2016). Single Molecule Nanoelectrochemistry in Electrical Junctions. Accounts of Chemical Research, 49(11), 2640-2648. doi:10.1021/acs.accounts.6b00373
Insulated molecular wires: Inhibiting orthogonal contacts in metal complex based molecular junctions.
Costa Milan, D., & Nichols, R. (n.d.). Insulated molecular wires: Inhibiting orthogonal contacts in metal complex based molecular junctions.. doi:10.17638/datacat.liverpool.ac.uk/212
Soft vs Hard contact junction formation study on terthiophene molecular wires and their charge transfer complexes
Vezzoli, A., Higgins, S., & Nichols, R. (n.d.). Soft vs Hard contact junction formation study on terthiophene molecular wires and their charge transfer complexes. doi:10.17638/datacat.liverpool.ac.uk/203
Experimental and Computational Studies of the Single-Molecule Conductance of Ru(II) and Pt(II) <i>trans</i>-Bis(acetylide) Complexes
Al-Owaedi, O. A., Milan, D. C., Oerthel, M. -C., Bock, S., Yufit, D. S., Howard, J. A. K., . . . Low, P. J. (2016). Experimental and Computational Studies of the Single-Molecule Conductance of Ru(II) and Pt(II) <i>trans</i>-Bis(acetylide) Complexes. Organometallics, 35(17), 2944-2954. doi:10.1021/acs.organomet.6b00472
Electrochemically grafted single molecule junctions exploiting a chemical protection strategy
Liang, J. -H. (n.d.). Electrochemically grafted single molecule junctions exploiting a chemical protection strategy. doi:10.17638/datacat.liverpool.ac.uk/191
Low variability of single-molecule conductance assisted by bulky metal–molecule contacts
Costa Milan, D. (n.d.). Low variability of single-molecule conductance assisted by bulky metal–molecule contacts. doi:10.17638/datacat.liverpool.ac.uk/180
Single Molecule Conductance Studies of Organometallic Complexes Bearing 3-Thienyl Contacting Groups
Costa Milan, D., & Nichols, R. (n.d.). Single Molecule Conductance Studies of Organometallic Complexes Bearing 3-Thienyl Contacting Groups. doi:10.17638/datacat.liverpool.ac.uk/172
Experimental and computational studies of the single molecule conductance of Ru(II) and Pt(II) trans-bis(acetylide) complexes
Costa Milan, D., & Nichols, R. (n.d.). Experimental and computational studies of the single molecule conductance of Ru(II) and Pt(II) trans-bis(acetylide) complexes. doi:10.17638/datacat.liverpool.ac.uk/139
The Single-Molecule Electrical Conductance of a Rotaxane-Hexayne Supramolecular Assembly
Costa Milan, D., & Nichols, R. (n.d.). The Single-Molecule Electrical Conductance of a Rotaxane-Hexayne Supramolecular Assembly. doi:10.17638/datacat.liverpool.ac.uk/170
Solvent Dependence of the Single Molecule Conductance of Oligoyne-Based Molecular Wires
Milan, D. C., Al-Owaedi, O. A., Oerthel, M. -C., Marqués-González, S., Brooke, R. J., Bryce, M. R., . . . García-Suárez, V. M. (2016). Solvent Dependence of the Single Molecule Conductance of Oligoyne-Based Molecular Wires. The Journal of Physical Chemistry C, 120(29), 15666-15674. doi:10.1021/acs.jpcc.5b08877
Single-Molecule Conductance of Viologen-Cucurbit[8]uril Host-Guest Complexes
Zhang, W., Gan, S., Vezzoli, A., Davidson, R. J., Milan, D. C., Luzyanin, K. V., . . . Niu, L. (2016). Single-Molecule Conductance of Viologen-Cucurbit[8]uril Host-Guest Complexes. ACS Nano, 10(5), 5212-5220. doi:10.1021/acsnano.6b00786
Effects of Electrode–Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes
Davidson, R., Al-Owaedi, O. A., Milan, D. C., Zeng, Q., Tory, J., Hartl, F., . . . Low, P. J. (2016). Effects of Electrode–Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes. Inorganic Chemistry, 55(6), 2691-2700. doi:10.1021/acs.inorgchem.5b02094
Evidence for a hopping mechanism in metal|single molecule|metal junctions involving conjugated metal–terpyridyl complexes; potential-dependent conductances of complexes [M(pyterpy)<sub>2</sub>]<sup>2+</sup> (M = Co and Fe; pyterpy = 4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine) in ionic liquid
Chappell, S., Brooke, C., Nichols, R. J., Kershaw Cook, L. J., Halcrow, M., Ulstrup, J., & Higgins, S. J. (2016). Evidence for a hopping mechanism in metal|single molecule|metal junctions involving conjugated metal–terpyridyl complexes; potential-dependent conductances of complexes [M(pyterpy)<sub>2</sub>]<sup>2+</sup> (M = Co and Fe; pyterpy = 4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine) in ionic liquid. Faraday Discussions, 193, 113-131. doi:10.1039/c6fd00080k
From single cells to single molecules: general discussion
Gooding, J., Magnussen, O., Fermin, D., Crooks, R., Kanoufi, F., Schuhmann, W., . . . Lemay, S. (2016). From single cells to single molecules: general discussion. Faraday Discussions, 193, 141-170. doi:10.1039/c6fd90066f
Low variability of single-molecule conductance assisted by bulky metal–molecule contacts
Ferradás, R. R., Marqués-González, S., Osorio, H. M., Ferrer, J., Cea, P., Milan, D. C., . . . Martín, S. (2016). Low variability of single-molecule conductance assisted by bulky metal–molecule contacts. RSC Advances, 6(79), 75111-75121. doi:10.1039/c6ra15477h
Reactions at the nanoscale: general discussion
Hersbach, T., MacPherson, J., Magnussen, O., Crooks, R., Higgins, S., Fermin, D., . . . Krischer, K. (2016). Reactions at the nanoscale: general discussion. Faraday Discussions, 193, 265-292. doi:10.1039/c6fd90067d
2015
Gating of single molecule junction conductance by charge transfer complex formation
Vezzoli, A., Grace, I., Brooke, C., Wang, K., Lambert, C. J., Xu, B., . . . Higgins, S. J. (2015). Gating of single molecule junction conductance by charge transfer complex formation. Nanoscale, 7(45), 18949-18955. doi:10.1039/c5nr04420k
Electrochemical Single-Molecule Transistors with Optimized Gate Coupling
Osorio Calvopina, H., Catarelli, S., Cea, P., Gluyas, J. B. G., Hartl, F., Higgins, S., . . . Zeng, Q. (2015). Electrochemical Single-Molecule Transistors with Optimized Gate Coupling. Journal of the American Chemical Society, 137(45), 14319-14328. doi:10.1021/jacs.5b08431
Effects of asymmetric contacts on single molecule conductances of HS(CH2)nCOOH in nano-electrical junctions
Martin, S., Manrique, D., Garcia-Suarez, V. M., Haiss, W., Higgins, S. J., Lambert, C. J., & Nichols, R. J. (2015). Effects of asymmetric contacts on single molecule conductances of HS(CH2)nCOOH in nano-electrical junctions. Retrieved from https://arxiv.org/abs/1509.00875v1
Single-Molecule Electronics: Chemical and Analytical Perspectives
Nichols, R. J., & Higgins, S. J. (2015). Single-Molecule Electronics: Chemical and Analytical Perspectives. Annual Review of Analytical Chemistry, 8(1), 389-417. doi:10.1146/annurev-anchem-071114-040118
Synthesis, Electrochemistry, and Single-Molecule Conductance of Bimetallic 2,3,5,6-Tetra(pyridine-2-yl)pyrazine-Based Complexes
Davidson, R., Liang, J. -H., Costa Milan, D., Mao, B. -W., Nichols, R. J., Higgins, S. J., . . . Low, P. J. (2015). Synthesis, Electrochemistry, and Single-Molecule Conductance of Bimetallic 2,3,5,6-Tetra(pyridine-2-yl)pyrazine-Based Complexes. Inorganic Chemistry, 54(11), 5487-5494. doi:10.1021/acs.inorgchem.5b00507
Resonant transport and electrostatic effects in single-molecule electrical junctions
Brooke, C., Vezzoli, A., Higgins, S. J., Zotti, L. A., Palacios, J. J., & Nichols, R. J. (2015). Resonant transport and electrostatic effects in single-molecule electrical junctions. Physical Review B, 91(19). doi:10.1103/physrevb.91.195438
Single-molecule contacts exposed
Nichols, R. J., & Higgins, S. J. (2015). Single-molecule contacts exposed. Nature Materials, 14(5), 465-466. doi:10.1038/nmat4225
Electrical characterization of single molecule and Langmuir–Blodgett monomolecular films of a pyridine-terminated oligo(phenylene-ethynylene) derivative
Osorio, H. M., Martín, S., López, M. C., Marqués-González, S., Higgins, S. J., Nichols, R. J., . . . Cea, P. (2015). Electrical characterization of single molecule and Langmuir–Blodgett monomolecular films of a pyridine-terminated oligo(phenylene-ethynylene) derivative. Beilstein Journal of Nanotechnology, 6, 1145-1157. doi:10.3762/bjnano.6.116
Single Gold Atom Containing Oligo(phenylene)ethynylene: Assembly into LB Films and Electrical Characterization
Ballesteros, L. M., Martín, S., Marqués-González, S., López, M. C., Higgins, S. J., Nichols, R. J., . . . Cea, P. (2015). Single Gold Atom Containing Oligo(phenylene)ethynylene: Assembly into LB Films and Electrical Characterization. The Journal of Physical Chemistry C, 119(1), 784-793. doi:10.1021/jp510078w
2014
Ionic Liquid Based Approach for Single-Molecule Electronics with Cobalt Contacts
Catarelli, S. R., Higgins, S. J., Schwarzacher, W., Mao, B. -W., Yan, J. -W., & Nichols, R. J. (2014). Ionic Liquid Based Approach for Single-Molecule Electronics with Cobalt Contacts. Langmuir, 30(47), 14329-14336. doi:10.1021/la503077c
Molecular electronics: general discussion
Hodgkiss, J., Zysman-Colman, E., Higgins, S., Solomon, G., Bâldea, I., Samuel, I., . . . Bradley, D. (2014). Molecular electronics: general discussion. Faraday Discuss., 174, 125-151. doi:10.1039/c4fd90049a
Organic bioelectronics: general discussion
Higgins, S., Hodgkiss, J., Plank, N., Torsi, L., Cowper, P., Malliaras, G., . . . Melzer, K. (2014). Organic bioelectronics: general discussion. Faraday Discuss., 174, 413-428. doi:10.1039/c4fd90048k
Organic photovoltaics and energy: general discussion
Hodgkiss, J., Conboy, G., Hutchings, G., Higgins, S., Galbraith, I., Findlay, N., . . . Kim, J. -S. (2014). Organic photovoltaics and energy: general discussion. Faraday Discuss., 174, 341-355. doi:10.1039/c4fd90050b
Photonics: general discussion
Higgins, S., Torsi, L., Whitworth, G., Laurand, N., Zhang, S., Samuel, I., . . . Fraboni, B. (2014). Photonics: general discussion. Faraday Discuss., 174, 235-253. doi:10.1039/c4fd90047b
Single Molecular Electrochemistry within an STM
Nichols, R. J., & Higgins, S. J. (2013). Single Molecular Electrochemistry within an STM. In Unknown Book (pp. 99-136). Wiley. doi:10.1002/9783527680436.ch3
2013
Controlling the Structural and Electrical Properties of Diacid Oligo(Phenylene Ethynylene) Langmuir–Blodgett Films
Ballesteros, L. M., Martín, S., Cortés, J., Marqués‐González, S., Higgins, S. J., Nichols, R. J., . . . Cea, P. (2013). Controlling the Structural and Electrical Properties of Diacid Oligo(Phenylene Ethynylene) Langmuir–Blodgett Films. Chemistry – A European Journal, 19(17), 5352-5363. doi:10.1002/chem.201203261
Simplifying the conductance profiles of molecular junctions: the use of the trimethylsilylethynyl moiety as a molecule–gold contact
Marqués-González, S., Yufit, D. S., Howard, J. A. K., Martín, S., Osorio, H. M., García-Suárez, V. M., . . . Low, P. J. (2013). Simplifying the conductance profiles of molecular junctions: the use of the trimethylsilylethynyl moiety as a molecule–gold contact. Dalton Trans., 42(2), 338-341. doi:10.1039/c2dt31825c
Fundamentals of Picoscience
Sattler, K. D. (Ed.) (2013). Fundamentals of Picoscience. In . CRC Press. doi:10.1201/b15523
Single Molecular Electrochemistry within an STM
Nichols, R. J., & Higgins, S. J. (2013). Single Molecular Electrochemistry within an STM. In Advances in Electrochemical Science and Engineering Electrocatalysis Volume 14 (pp. 99-136). doi:10.1002/9783527680436.ch3
2012
Single-Molecule Electrochemical Gating in Ionic Liquids
Kay, N. J., Higgins, S. J., Jeppesen, J. O., Leary, E., Lycoops, J., Ulstrup, J., & Nichols, R. J. (2012). Single-Molecule Electrochemical Gating in Ionic Liquids. Journal of the American Chemical Society, 134(40), 16817-16826. doi:10.1021/ja307407e
Quantized Electron‐Transfer Pathways at Nanoparticle–Redox Centre Hybrids
Cabo‐Fernández, L., Bradley, D. F., Romani, S., Higgins, S. J., & Schiffrin, D. J. (2012). Quantized Electron‐Transfer Pathways at Nanoparticle–Redox Centre Hybrids. ChemPhysChem, 13(12), 2997-3007. doi:10.1002/cphc.201200142
Single-molecule conductance determinations on HS(CH<sub>2</sub>)<sub>4</sub>O(CH<sub>2</sub>)<sub>4</sub>SH and HS(CH<sub>2</sub>)<sub>2</sub>O(CH<sub>2</sub>)<sub>2</sub>O(CH<sub>2</sub>)<sub>2</sub>SH, and comparison with alkanedithiols of the same length
Scullion, L. E., Leary, E., Higgins, S. J., & Nichols, R. J. (2012). Single-molecule conductance determinations on HS(CH<sub>2</sub>)<sub>4</sub>O(CH<sub>2</sub>)<sub>4</sub>SH and HS(CH<sub>2</sub>)<sub>2</sub>O(CH<sub>2</sub>)<sub>2</sub>O(CH<sub>2</sub>)<sub>2</sub>SH, and comparison with alkanedithiols of the same length. Journal of Physics: Condensed Matter, 24(16), 164211. doi:10.1088/0953-8984/24/16/164211
Comparison of the Conductance of Three Types of Porphyrin‐Based Molecular Wires: <i>β,meso,β‐</i>Fused Tapes, <i>meso</i>‐Butadiyne‐Linked and Twisted <i>meso‐meso</i> Linked Oligomers
Sedghi, G., Esdaile, L. J., Anderson, H. L., Martin, S., Bethell, D., Higgins, S. J., & Nichols, R. J. (2012). Comparison of the Conductance of Three Types of Porphyrin‐Based Molecular Wires: <i>β,meso,β‐</i>Fused Tapes, <i>meso</i>‐Butadiyne‐Linked and Twisted <i>meso‐meso</i> Linked Oligomers. Advanced Materials, 24(5), 653-657. doi:10.1002/adma.201103109
Electrochemical investigations of dissolved and surface immobilised 2-amino-1,4-naphthoquinones in aqueous solutions
Bouffier, L., Lister, K. E., Higgins, S. J., Nichols, R. J., & Doneux, T. (2012). Electrochemical investigations of dissolved and surface immobilised 2-amino-1,4-naphthoquinones in aqueous solutions. Journal of Electroanalytical Chemistry, 664, 80-87. doi:10.1016/j.jelechem.2011.10.017
Interference comes into view
Nichols, R. J., & Higgins, S. J. (2012). Interference comes into view. Nature Nanotechnology, 7(5), 281-282. doi:10.1038/nnano.2012.46
MOLECULAR JUNCTIONS Interference comes into view
Nichols, R. J., & Higgins, S. J. (2012). MOLECULAR JUNCTIONS Interference comes into view. Nature Nanotechnology, 7(5), 281-282.
2011
Ionic Liquids As a Medium for STM-Based Single Molecule Conductance Determination: An Exploration Employing Alkanedithiols
Kay, N. J., Nichols, R. J., Higgins, S. J., Haiss, W., Sedghi, G., Schwarzacher, W., & Mao, B. -W. (2011). Ionic Liquids As a Medium for STM-Based Single Molecule Conductance Determination: An Exploration Employing Alkanedithiols. The Journal of Physical Chemistry C, 115(43), 21402-21408. doi:10.1021/jp206241d
Large Conductance Changes in Peptide Single Molecule Junctions Controlled by pH
Scullion, L., Doneux, T., Bouffier, L., Fernig, D. G., Higgins, S. J., Bethell, D., & Nichols, R. J. (2011). Large Conductance Changes in Peptide Single Molecule Junctions Controlled by pH. The Journal of Physical Chemistry C, 115(16), 8361-8368. doi:10.1021/jp201222b
Metal–Organic Conjugated Microporous Polymers
Jiang, J., Wang, C., Laybourn, A., Hasell, T., Clowes, R., Khimyak, Y. Z., . . . Cooper, A. I. (2011). Metal–Organic Conjugated Microporous Polymers. Angewandte Chemie International Edition, 50(5), 1072-1075. doi:10.1002/anie.201005864
Looking Ahead: Challenges and Opportunities in Organometallic Chemistry
Higgins, S. J., Nichols, R. J., Martin, S., Cea, P., van der Zant, H. S. J., Richter, M. M., & Low, P. J. (2011). Looking Ahead: Challenges and Opportunities in Organometallic Chemistry. Organometallics, 30(1), 7-12. doi:10.1021/om100919r
Long-range electron tunnelling in oligo-porphyrin molecular wires
Sedghi, G., García-Suárez, V. M., Esdaile, L. J., Anderson, H. L., Lambert, C. J., Martín, S., . . . Nichols, R. J. (2011). Long-range electron tunnelling in oligo-porphyrin molecular wires. Nature Nanotechnology, 6(8), 517-523. doi:10.1038/nnano.2011.111
Metal-Organic Conjugated Microporous Polymers
Jiang, J. -X., Wang, C., Laybourn, A., Hasell, T., Clowes, R., Khimyak, Y. Z., . . . Cooper, A. I. (2011). Metal-Organic Conjugated Microporous Polymers. Angewandte Chemie-International Edition, 50(5), 1072-1075. doi:10.1002/ange.201005864
Nanocomposites of poly(3,4-ethylenedioxythiophene) and montmorillonite clay: synthesis and characterization
Rajapakse, R. M. G., Higgins, S., Velauthamurty, K., Bandara, H. M. N., Wijeratne, S., & Rajapakse, R. M. M. Y. (2011). Nanocomposites of poly(3,4-ethylenedioxythiophene) and montmorillonite clay: synthesis and characterization. Journal of Composite Materials, 45(5), 597-608. doi:10.1177/0021998310377935
2010
Regarding ruthenium
Higgins, S. (2010). Regarding ruthenium. Nature Chemistry, 2(12), 1100. doi:10.1038/nchem.917
Synthesis and characterization of monomeric and polymeric Cu(II) complexes of 3,4-ethylenedioxythiophene-functionalized with cyclam ligand
Velauthamurty, K., Higgins, S. J., Rajapakse, R. M. G., Bandara, H. M. N., & Shimomura, M. (2010). Synthesis and characterization of monomeric and polymeric Cu(II) complexes of 3,4-ethylenedioxythiophene-functionalized with cyclam ligand. Electrochimica Acta, 56(1), 326-332. doi:10.1016/j.electacta.2010.08.075
High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene
Jiang, J. -X., Laybourn, A., Clowes, R., Khimyak, Y. Z., Bacsa, J., Higgins, S. J., . . . Cooper, A. I. (2010). High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene. Macromolecules, 43(18), 7577-7582. doi:10.1021/ma101468r
High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene
Jiang, J. -X., Laybourn, A., Clowes, R., Khimyak, Y. Z., Bacsa, J., Higgins, S. J., . . . Cooper, A. I. (2010). High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene. Macromolecules, 43(18), 7577-7582. doi:10.1021/ma101468r
Identifying Diversity in Nanoscale Electrical Break Junctions
Martín, S., Grace, I., Bryce, M. R., Wang, C., Jitchati, R., Batsanov, A. S., . . . Nichols, R. J. (2010). Identifying Diversity in Nanoscale Electrical Break Junctions. Journal of the American Chemical Society, 132(26), 9157-9164. doi:10.1021/ja103327f
The Impact of <i>E</i>−<i>Z</i> Photo-Isomerization on Single Molecular Conductance
Martin, S., Haiss, W., Higgins, S. J., & Nichols, R. J. (2010). The Impact of <i>E</i>−<i>Z</i> Photo-Isomerization on Single Molecular Conductance. Nano Letters, 10(6), 2019-2023. doi:10.1021/nl9042455
The experimental determination of the conductance of single molecules
Nichols, R. J., Haiss, W., Higgins, S. J., Leary, E., Martin, S., & Bethell, D. (2010). The experimental determination of the conductance of single molecules. Physical Chemistry Chemical Physics, 12(12), 2801. doi:10.1039/b922000c
Single‐Molecule Organic Electronics: Toward Functional Structures
Higgins, S. J., & Nichols, R. J. (2011). Single‐Molecule Organic Electronics: Toward Functional Structures. In Unknown Book (pp. 527-550). Wiley. doi:10.1002/9783527689897.ch16
2009
A dramatic effect of water on single molecule conductance
Leary, E., Höbenreich, H., Higgins, S. J., Van Zalinge, H., Haiss, W., Nichols, R. J., . . . Lambert, C. J. (2009). A dramatic effect of water on single molecule conductance. In Materials Research Society Symposium Proceedings Vol. 1154 (pp. 3-8).
Anomalous length and voltage dependence of single molecule conductance
Haiss, W., Martin, S., Scullion, L. E., Bouffier, L., Higgins, S. J., & Nichols, R. J. (2009). Anomalous length and voltage dependence of single molecule conductance. Physical Chemistry Chemical Physics, 11(46), 10831. doi:10.1039/b910194b
Influence of Conformational Flexibility on Single-Molecule Conductance in Nano-Electrical Junctions
Martín, S., Giustiniano, F., Haiss, W., Higgins, S. J., Whitby, R. J., & Nichols, R. J. (2009). Influence of Conformational Flexibility on Single-Molecule Conductance in Nano-Electrical Junctions. The Journal of Physical Chemistry C, 113(43), 18884-18890. doi:10.1021/jp906763p
Oligoyne Single Molecule Wires
Wang, C., Batsanov, A. S., Bryce, M. R., Martín, S., Nichols, R. J., Higgins, S. J., . . . Lambert, C. J. (2009). Oligoyne Single Molecule Wires. Journal of the American Chemical Society, 131(43), 15647-15654. doi:10.1021/ja9061129
A molecular wire incorporating a robust hexanuclear platinum cluster
Leary, E., Van Zalinge, H., Higgins, S. J., Nichols, R. J., Fabrizi de Biani, F., Leoni, P., . . . Zanello, P. (2009). A molecular wire incorporating a robust hexanuclear platinum cluster. Physical Chemistry Chemical Physics, 11(25), 5198. doi:10.1039/b817424e
Adverse effects of asymmetric contacts on single molecule conductances of HS(CH<sub>2</sub>)<sub><i>n</i></sub>COOH in nanoelectrical junctions
Martín, S., Manrique, D. Z., García-Suárez, V. M., Haiss, W., Higgins, S. J., Lambert, C. J., & Nichols, R. J. (2009). Adverse effects of asymmetric contacts on single molecule conductances of HS(CH<sub>2</sub>)<sub><i>n</i></sub>COOH in nanoelectrical junctions. Nanotechnology, 20(12), 125203. doi:10.1088/0957-4484/20/12/125203
Molecular Dynamics and Electrochemical Investigations of a pH-Responsive Peptide Monolayer
Doneux, T., Bouffier, L., Mello, L. V., Rigden, D. J., Kejnovská, I., Fernig, D. G., . . . Nichols, R. J. (2009). Molecular Dynamics and Electrochemical Investigations of a pH-Responsive Peptide Monolayer. The Journal of Physical Chemistry C, 113(16), 6792-6799. doi:10.1021/jp810859k
Impact of Junction Formation Method and Surface Roughness on Single Molecule Conductance
Haiss, W., Martín, S., Leary, E., Zalinge, H. V., Higgins, S. J., Bouffier, L., & Nichols, R. J. (2009). Impact of Junction Formation Method and Surface Roughness on Single Molecule Conductance. The Journal of Physical Chemistry C, 113(14), 5823-5833. doi:10.1021/jp811142d
Synthesis and characterization of monomeric and polymeric Pd(II) and Pt(II) complexes of 3,4-ethylenedioxythiophene-functionalized phosphine ligands
Velauthamurty, K., Higgins, S. J., Rajapakse, R. M. G., Bacsa, J., van Zalinge, H., Nichols, R. J., & Haiss, W. (2009). Synthesis and characterization of monomeric and polymeric Pd(II) and Pt(II) complexes of 3,4-ethylenedioxythiophene-functionalized phosphine ligands. Journal of Materials Chemistry, 19(13), 1850. doi:10.1039/b817210b
Single-Molecule Solvation-Shell Sensing
Leary, E., Höbenreich, H., Higgins, S. J., van Zalinge, H., Haiss, W., Nichols, R. J., . . . Smerdon, J. (2009). Single-Molecule Solvation-Shell Sensing. Physical Review Letters, 102(8). doi:10.1103/physrevlett.102.086801
2008
Structure−Property Relationships in Redox-Gated Single Molecule Junctions − A Comparison of Pyrrolo-Tetrathiafulvalene and Viologen Redox Groups
Leary, E., Higgins, S. J., van Zalinge, H., Haiss, W., Nichols, R. J., Nygaard, S., . . . Ulstrup, J. (2008). Structure−Property Relationships in Redox-Gated Single Molecule Junctions − A Comparison of Pyrrolo-Tetrathiafulvalene and Viologen Redox Groups. Journal of the American Chemical Society, 130(37), 12204-12205. doi:10.1021/ja8014605
Variable contact gap single-molecule conductance determination for a series of conjugated molecular bridges
Haiss, W., Wang, C., Jitchati, R., Grace, I., Martín, S., Batsanov, A. S., . . . Nichols, R. J. (2008). Variable contact gap single-molecule conductance determination for a series of conjugated molecular bridges. Journal of Physics: Condensed Matter, 20(37), 374119. doi:10.1088/0953-8984/20/37/374119
Single Molecule Conductance of Porphyrin Wires with Ultralow Attenuation
Sedghi, G., Sawada, K., Esdaile, L. J., Hoffmann, M., Anderson, H. L., Bethell, D., . . . Nichols, R. J. (2008). Single Molecule Conductance of Porphyrin Wires with Ultralow Attenuation. Journal of the American Chemical Society, 130(27), 8582-8583. doi:10.1021/ja802281c
A Comprehensive Study of the Single Molecule Conductance of α,ω-Dicarboxylic Acid-Terminated Alkanes
Martín, S., Haiss, W., Higgins, S., Cea, P., López, M. C., & Nichols, R. J. (2008). A Comprehensive Study of the Single Molecule Conductance of α,ω-Dicarboxylic Acid-Terminated Alkanes. The Journal of Physical Chemistry C, 112(10), 3941-3948. doi:10.1021/jp709745z
2007
Single-Molecule Conductance of Redox Molecules in Electrochemical Scanning Tunneling Microscopy
Haiss, W., Albrecht, T., van Zalinge, H., Higgins, S. J., Bethell, D., Höbenreich, H., . . . Ulstrup, J. (2007). Single-Molecule Conductance of Redox Molecules in Electrochemical Scanning Tunneling Microscopy. The Journal of Physical Chemistry B, 111(24), 6703-6712. doi:10.1021/jp068692m
An electrogenerated polyterthiophene for binding and sensing polyadenosine-functionalised oligonucleotides
Higgins, S. J., Mouffouk, F., Brown, S. J., Williams, D. R., & Cossins, A. R. (2007). An electrogenerated polyterthiophene for binding and sensing polyadenosine-functionalised oligonucleotides. Sensors and Actuators B: Chemical, 122(1), 253-258. doi:10.1016/j.snb.2006.05.031
Catalysts under the microscope
Higgins, S. J., & Nichols, R. J. (2007). Catalysts under the microscope. Nature Nanotechnology, 2(5), 270-271. doi:10.1038/nnano.2007.117
Chemical control of double barrier tunnelling in α,ω-dithiaalkane molecular wires
Leary, E., Higgins, S. J., van Zalinge, H., Haiss, W., & Nichols, R. J. (2007). Chemical control of double barrier tunnelling in α,ω-dithiaalkane molecular wires. Chemical Communications, (38), 3939. doi:10.1039/b709576g
Regioregular poly(3-hexyl)selenophene: a low band gap organic hole transporting polymer
Heeney, M., Zhang, W., Crouch, D. J., Chabinyc, M. L., Gordeyev, S., Hamilton, R., . . . Tierney, S. (2007). Regioregular poly(3-hexyl)selenophene: a low band gap organic hole transporting polymer. Chemical Communications, (47), 5061. doi:10.1039/b712398a
Reliable Suzuki Chemistry For Functionalised Polythiophene Synthesis
Higgins, S., Liversedge, I., Badriya, S., Heeney, M., Giles, M., & McCulloch, I. (2007). Reliable Suzuki Chemistry For Functionalised Polythiophene Synthesis. In MRS Proceedings Vol. 1003. Springer Science and Business Media LLC. doi:10.1557/proc-1003-o01-06
Single-molecule conductance of redox molecules in electrochemical scanning tunneling microscopy
Haiss, W., Albrecht, T., van Zalinge, H., Higgins, S. J., Bethell, D., Hobenreich, H., . . . Ulstrup, J. (2007). Single-molecule conductance of redox molecules in electrochemical scanning tunneling microscopy. Journal of Physical Chemistry B, 111(24), 6703-6712. doi:10.1021/jp068692m|ISSN
2006
Precision control of single-molecule electrical junctions
Haiss, W., Wang, C., Grace, I., Batsanov, A. S., Schiffrin, D. J., Higgins, S. J., . . . Nichols, R. J. (2006). Precision control of single-molecule electrical junctions. Nature Materials, 5(12), 995-1002. doi:10.1038/nmat1781
Noise for Health: Phage-Based Rapid Bacterial Identification Method
King, M. D., Seo, S., Kim, J., Cheng, M., Higgins, S., Young, R., . . . Kish, L. B. (n.d.). Noise for Health: Phage-Based Rapid Bacterial Identification Method. Unknown Journal, 171-179. doi:10.1007/3-540-33878-0_14
A [Ni(cyclam)]2+-functionalised poly(3,4-ethylenedioxythiophene): Synthesis, electropolymerisation and characterisation of the polymer by cyclic voltammetry and in situ reflectance FTIR spectroscopy
Mouffouk, F., Demetriou, A., Higgins, S. J., & Nichols, R. J. (2006). A [Ni(cyclam)]2+-functionalised poly(3,4-ethylenedioxythiophene): Synthesis, electropolymerisation and characterisation of the polymer by cyclic voltammetry and in situ reflectance FTIR spectroscopy. Inorganica Chimica Acta, 359(11), 3491-3496. doi:10.1016/j.ica.2005.12.001
Suzuki route to regioregular polyalkylthiophenes using Ir-catalysed borylation to make the monomer, and Pd complexes of bulky phosphanes as coupling catalysts for polymerisation
Liversedge, I. A., Higgins, S. J., Giles, M., Heeney, M., & McCulloch, I. (2006). Suzuki route to regioregular polyalkylthiophenes using Ir-catalysed borylation to make the monomer, and Pd complexes of bulky phosphanes as coupling catalysts for polymerisation. Tetrahedron Letters, 47(29), 5143-5146. doi:10.1016/j.tetlet.2006.05.063
Experimental observation of the density of localized trapping levels in organic semiconductors
Sedghi, N., Donaghy, D., Raja, M., Badriya, S., Higgins, S. J., & Eccleston, W. (2006). Experimental observation of the density of localized trapping levels in organic semiconductors. Journal of Non-Crystalline Solids, 352(9-20), 1641-1643. doi:10.1016/j.jnoncrysol.2005.10.049
Oligonucleotide–functionalised poly(3,4-ethylenedioxythiophene)-coated microelectrodes which show selective electrochemical response to hybridisation
Mouffouk, F., & Higgins, S. J. (2006). Oligonucleotide–functionalised poly(3,4-ethylenedioxythiophene)-coated microelectrodes which show selective electrochemical response to hybridisation. Electrochemistry Communications, 8(2), 317-322. doi:10.1016/j.elecom.2005.11.027
A biotin-functionalised poly(3,4-ethylenedioxythiophene)-coated microelectrode which responds electrochemically to avidin binding
Mouffouk, F., & Higgins, S. J. (2006). A biotin-functionalised poly(3,4-ethylenedioxythiophene)-coated microelectrode which responds electrochemically to avidin binding. Electrochemistry Communications, 8(1), 15-20. doi:10.1016/j.elecom.2005.10.009
Mater. Res. Soc. Symp. Proc.
Ohta, H., Ow-Yang, C. W., Paine, D. C., Perkins, J. D., & Tate, J. (Eds.) (2006). Mater. Res. Soc. Symp. Proc.. In MRS Fall Meeting Vol. 905E. Boston: MRS. Retrieved from http://www.mrs.org/
2005
Functionalized Regioregular Polyalkylthiophenes for Biosensing Applications
Higgins, S. J., Mouffouk, F., Brown, S. J., Sedghi, N., Eccleston, B., & Reeman, S. (2005). Functionalized Regioregular Polyalkylthiophenes for Biosensing Applications. In MRS Proceedings Vol. 871. Springer Science and Business Media LLC. doi:10.1557/proc-871-i1.3
Modelling of polymer schottky diodes for real device applications
Raja, M., Sedghi, N., Badriya, S., Higgins, S. J., Lloyd, G. C. R., & Eccleston, W. (n.d.). Modelling of polymer schottky diodes for real device applications. In Proceedings of 35th European Solid-State Device Research Conference, 2005. ESSDERC 2005. (pp. 253-256). IEEE. doi:10.1109/essder.2005.1546633
Electrosynthesis and characterization of biotin-functionalized poly(terthiophene) copolymers, and their response to avidin
Mouffouk, F., Brown, S. J., Demetriou, A. M., Higgins, S. J., Nichols, R. J., RajapakseOn leave from Department o, R. M. G., & Reeman, S. (2005). Electrosynthesis and characterization of biotin-functionalized poly(terthiophene) copolymers, and their response to avidin. Journal of Materials Chemistry, 15(11), 1186. doi:10.1039/b413974g
Electrochemical characterization of the Pt/PEDOT electrode in DMFC*
Shen, M., Roy, S., Scoth, K., Higgins, S., & Rajapaksez, G. (2005). Electrochemical characterization of the Pt/PEDOT electrode in DMFC*. Progress in Natural Science, 15(1), 89-97. doi:10.1080/10020070512330013
Functionalised regioregular polyalkylthiophenes for biosensing applications
Higgins, S. J., Mouffouk, F., Brown, S. J., Sedghi, N., Eccleston, W., & Reeman, S. (2005). Functionalised regioregular polyalkylthiophenes for biosensing applications. Mater. Res. Soc. Symp. Proc., 871E, I13.
Variable Temperature Capacitance-Voltage Measurements to Investigate the Density of Localized Trapping Levels in Organic Semiconductors
Sedghi, N., Donaghy, D., Raja, M., Badriya, S., Higgins, S. J., & Eccleston, B. (2005). Variable Temperature Capacitance-Voltage Measurements to Investigate the Density of Localized Trapping Levels in Organic Semiconductors. MRS Proceedings, 905. doi:10.1557/proc-0905-dd06-02
2004
Practicability of the development of design tools for polymer TFT circuit development
Raja, M., Sedghi, N., Donaghy, D., Lloyd, G., Badriya, S., Higgins, S. J., & Eccleston, B. (2004). Practicability of the development of design tools for polymer TFT circuit development. SPIE Proceedings, 5464, 382. doi:10.1117/12.547722
Versatile coordination behaviour of Ph2AsCH2AsPh2 with Ru(II)
Barton, V. E., Bickley, J. F., Cain, L. A., Leary, E., Ledger, J., Higgins, S. J., & Mouffouk, F. (2004). Versatile coordination behaviour of Ph2AsCH2AsPh2 with Ru(II). Inorganica Chimica Acta, 357(15), 4488-4495. doi:10.1016/j.ica.2004.07.002
A regioregular polyalkylthiophene bearing covalently-linked biotin, and its interaction with avidin in solution and in thin films
Mouffouk, F., Higgins, S. J., Brown, S. J., Sedghi, N., Eccleston, B., & Reeman, S. (2004). A regioregular polyalkylthiophene bearing covalently-linked biotin, and its interaction with avidin in solution and in thin films. Chemical Communications, (20), 2314. doi:10.1039/b408935a
Measurement of single molecule conductivity using the spontaneous formation of molecular wires
Haiss, W., Nichols, R. J., van Zalinge, H., Higgins, S. J., Bethell, D., & Schiffrin, D. J. (2004). Measurement of single molecule conductivity using the spontaneous formation of molecular wires. Physical Chemistry Chemical Physics, 6(17), 4330. doi:10.1039/b404929b
Molecular Wire Formation from Viologen Assemblies
Haiss, W., van Zalinge, H., Höbenreich, H., Bethell, D., Schiffrin, D. J., Higgins, S. J., & Nichols, R. J. (2004). Molecular Wire Formation from Viologen Assemblies. Langmuir, 20(18), 7694-7702. doi:10.1021/la049183j
Wiring nanoparticles with redox molecules
Haiss, W., Nichols, R. J., Higgins, S. J., Bethell, D., Höbenreich, H., & Schiffrin, D. J. (2004). Wiring nanoparticles with redox molecules. Faraday Discuss., 125, 179-194. doi:10.1039/b303214k
2003
Syntheses, characterisation and some ligand substitution chemistry of Ru(<scp>ii</scp>)–diphosphine triflate complexes
Bickley, J. F., La Pensée, A. A., Higgins, S. J., & Stuart, C. A. (2003). Syntheses, characterisation and some ligand substitution chemistry of Ru(<scp>ii</scp>)–diphosphine triflate complexes. Dalton Trans., (24), 4663-4668. doi:10.1039/b306552a
Redox State Dependence of Single Molecule Conductivity
Haiss, W., van Zalinge, H., Higgins, S. J., Bethell, D., Höbenreich, H., Schiffrin, D. J., & Nichols, R. J. (2003). Redox State Dependence of Single Molecule Conductivity. Journal of the American Chemical Society, 125(50), 15294-15295. doi:10.1021/ja038214e
Grafting and electrochemical characterisation of poly-(3,4-ethylenedioxythiophene) films, on Nafion and on radiation-grafted polystyrenesulfonate–polyvinylidene fluoride composite surfaces
Higgins, S. J., Lovell, K. V., Gamini Rajapakse, R. M., & Walsby, N. M. (2003). Grafting and electrochemical characterisation of poly-(3,4-ethylenedioxythiophene) films, on Nafion and on radiation-grafted polystyrenesulfonate–polyvinylidene fluoride composite surfaces. J. Mater. Chem., 13(10), 2485-2489. doi:10.1039/b303424k
Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes
Bickley, J., Higgins, S. J., & La Pensée, A. A. (2003). Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes. Collection of Czechoslovak Chemical Communications, 68(8), 1461-1466. doi:10.1135/cccc20031461
A TFT strategy for polymer circuits
Sedghi, N., Raja, M., Lloyd, G. C. R., Liversedge, I., Higgins, S. J., & Eccleston, B. (2003). A TFT strategy for polymer circuits. In POLYMER/METAL INTERFACES AND DEFECT MEDIATED PHENOMENA IN ORDERED POLYMERS Vol. 734 (pp. 365-370). Retrieved from https://www.webofscience.com/
The benefits of high-<i>K</i> dielectrics for polymer TFTs
Raja, M., Sedghi, N., Higgins, S. J., & Eccleston, W. (2003). The benefits of high-<i>K</i> dielectrics for polymer TFTs. In POLYMER/METAL INTERFACES AND DEFECT MEDIATED PHENOMENA IN ORDERED POLYMERS Vol. 734 (pp. 213-218). Retrieved from https://www.webofscience.com/
2002
Conduction processes in conjugated, highly regio-regular, high molecular mass, poly(3-hexylthiophene) thin-film transistors
Raja, M., Lloyd, G. C. R., Sedghi, N., Eccleston, W., Di Lucrezia, R., & Higgins, S. J. (2002). Conduction processes in conjugated, highly regio-regular, high molecular mass, poly(3-hexylthiophene) thin-film transistors. Journal of Applied Physics, 92(3), 1441-1445. doi:10.1063/1.1490622
Critical Considerations in Polymer Thin-Film Transistor (TFT) Dielectrics
Raja, M., Lloyd, G., Sedghi, N., Higgins, S. J., & Eccleston, W. (2002). Critical Considerations in Polymer Thin-Film Transistor (TFT) Dielectrics. In MRS Proceedings Vol. 725. Springer Science and Business Media LLC. doi:10.1557/proc-725-p6.5
Homoleptic iron(<scp>ii</scp>)–diphosphine and –diarsine complexes: syntheses, characterization and redox properties
La Pensée, A. A., Bickley, J., & Higgins, S. J. (2002). Homoleptic iron(<scp>ii</scp>)–diphosphine and –diarsine complexes: syntheses, characterization and redox properties. J. Chem. Soc., Dalton Trans., (16), 3241-3244. doi:10.1039/b204533h
Improved Thin Film Transistor (TFT) performance using fractionated Poly-3-hexylthiophene (P3HT)
Raja, M., Lloyd, G., Sedghi, N., di Lucrezia, R., Higgins, S. J., & Eccleston, W. (2002). Improved Thin Film Transistor (TFT) performance using fractionated Poly-3-hexylthiophene (P3HT). ORGANIC OPTOELECTRONIC MATERIALS, PROCESSING AND DEVICES, 708, 423-428. Retrieved from https://www.webofscience.com/
Increasing the carrier mobility in P3HT by doping for use in Schottky barrier TFTs
Lloyd, G. C. R., Sedghi, N., Raja, M., Di Lucrezia, R., Higgins, S., & Eccleston, W. (2002). Increasing the carrier mobility in P3HT by doping for use in Schottky barrier TFTs. In ORGANIC OPTOELECTRONIC MATERIALS, PROCESSING AND DEVICES Vol. 708 (pp. 429-434). Retrieved from https://www.webofscience.com/
Some in situ reflectance Fourier transform infrared studies of electrochemically prepared polybenzo[c]thiophene and poly-5-fluorobenzo[c]thiophene filmsElectronic supplementary information (ESI) available: schematic representation of the energy levels of polybenzothiophenes, CVs and FTIR spectra. See http://www.rsc.org/suppdata/jm/b1/b108054g/
Jones, C. L., Higgins, S. J., & Christensen, P. A. (2002). Some in situ reflectance Fourier transform infrared studies of electrochemically prepared polybenzo[c]thiophene and poly-5-fluorobenzo[c]thiophene filmsElectronic supplementary information (ESI) available: schematic representation of the energy levels of polybenzothiophenes, CVs and FTIR spectra. See http://www.rsc.org/suppdata/jm/b1/b108054g/. Journal of Materials Chemistry, 12(3), 758-764. doi:10.1039/b108054g
Syntheses, characterization and redox properties of homoleptic ruthenium(<scp>ii</scp>)–diphosphine and diarsine complexes: deviations from ligand additivity
La Pensée, A. A., Bickley, J., Higgins, S. J., Marcaccio, M., Paolucci, F., Roffia, S., & Charnock, J. M. (2002). Syntheses, characterization and redox properties of homoleptic ruthenium(<scp>ii</scp>)–diphosphine and diarsine complexes: deviations from ligand additivity. J. Chem. Soc., Dalton Trans., (22), 4095-4104. doi:10.1039/b206234h
2001
Ionising radiation detector
Smith, N. A., Higgins, S., Eccleston, W., & Casse, G. (2001). Ionising radiation detector.
Silver(I)-mediated isomerisation of trans-[RuCl2(P–P)2] (P–P = four-membered ring chelate diphosphine ligand) to cis-[{Ru(P–P)2(μ-Cl)2}nAg]+ species, and applications in stereoselective syntheses of cis- and trans-[RuCl(L)(P–P)2]+ (L = neutral ligand) †
Higgins, S. J., La Pensée, A., Stuart, C. A., & Charnock, J. M. (2001). Silver(I)-mediated isomerisation of trans-[RuCl2(P–P)2] (P–P = four-membered ring chelate diphosphine ligand) to cis-[{Ru(P–P)2(μ-Cl)2}nAg]+ species, and applications in stereoselective syntheses of cis- and trans-[RuCl(L)(P–P)2]+ (L = neutral ligand) †. Journal of the Chemical Society, Dalton Transactions, (6), 902-910. doi:10.1039/b009645h
The properties of MOS structures using conjugated polymers as the semiconductor
Lloyd, G., Raja, M., Sellers, I., Sedghi, N., Di Lucrezia, R., Higgins, S., & Eccleston, B. (2001). The properties of MOS structures using conjugated polymers as the semiconductor. Microelectronic Engineering, 59(1-4), 323-328. doi:10.1016/s0167-9317(01)00617-7
Syntheses and electro(co)polymerization of novel thiophene- and 2,2′:5′,2″-terthiophene-functionalized metal–tetraazamacrocycle complexes, and electrochemical and spectroelectrochemical characterization of the resulting polythiophenes
Higgins, S. J., Pounds, T. J., & Christensen, P. A. (2001). Syntheses and electro(co)polymerization of novel thiophene- and 2,2′:5′,2″-terthiophene-functionalized metal–tetraazamacrocycle complexes, and electrochemical and spectroelectrochemical characterization of the resulting polythiophenes. Journal of Materials Chemistry, 11(9), 2253-2261. doi:10.1039/b103284b
Ruthenium(II)-dppm Coordination Chemistry. An Advanced Inorganic Miniproject
Higgins, S. J. (2001). Ruthenium(II)-dppm Coordination Chemistry. An Advanced Inorganic Miniproject. Journal of Chemical Education, 78(5), 663. doi:10.1021/ed078p663
Silver( I )-mediated isomerisation of trans -[RuCl 2 (P–P) 2 ] (P–P = four-membered ring chelate diphosphine ligand ) to cis -[{Ru(P–P) 2 (μ-Cl) 2 } n Ag] + species, and applications in stereoselective syntheses of cis - and trans -[RuCl(L)(P–P) 2 ] + (L = neutral ligand )
Higgins, S. J., La Pensée, A., Stuart, C. A., & Charnock, J. M. (2001). Silver( I )-mediated isomerisation of trans -[RuCl 2 (P–P) 2 ] (P–P = four-membered ring chelate diphosphine ligand ) to cis -[{Ru(P–P) 2 (μ-Cl) 2 } n Ag] + species, and applications in stereoselective syntheses of cis - and trans -[RuCl(L)(P–P) 2 ] + (L = neutral ligand ). Dalton Transactions, 0(6), 902-910. doi:10.1039/b009645h
The properties of MOS structures using conjugated polymers as the semiconductor
Lloyd, G., Raja, M., Sellers, I., Sedghi, N., Di Lucrezia, R., Higgins, S., & Eccleston, B. (2001). The properties of MOS structures using conjugated polymers as the semiconductor. Microelectronic Engineering, 59(1-4), 323-328.
2000
Silver(I)-mediated isomerisation of trans-[RuCl2(P-P)2] (P-P=4-membered ring chelate diphosphine ligand) and its application in the syntheses of [RuCl(L)(P-P)2]+ (L=neutral ligand)
Higgins, S. J., Stuart, C. A., & Mills, A. (2000). Silver(I)-mediated isomerisation of trans-[RuCl2(P-P)2] (P-P=4-membered ring chelate diphosphine ligand) and its application in the syntheses of [RuCl(L)(P-P)2]+ (L=neutral ligand). Inorganic Chemistry Communications, 3(5), 208-210. doi:10.1016/s1387-7003(00)00055-1
Syntheses, characterisation and ligand substitution reactions of the useful synthons [Ru(OTf)2(P-P)2] (P-P=4-membered ring chelate diphosphine ligand)
Bickley, J. F., Higgins, S. J., Stuart, C. A., & Steiner, A. (2000). Syntheses, characterisation and ligand substitution reactions of the useful synthons [Ru(OTf)2(P-P)2] (P-P=4-membered ring chelate diphosphine ligand). Inorganic Chemistry Communications, 3(5), 211-213. doi:10.1016/s1387-7003(00)00054-x
Benzo[c]thiophenes
Gilchrist, T. L., & Higgins, S. J. (2000). Benzo[c]thiophenes. In E. J. Thomas (Ed.), Houben¿Weyl Science of Synthesis (pp. 185-210). Stuttgart: Thieme.
1999
Homoleptic complexes [Ru(L-L)3]2+ (L-L=diphosphine, diarsine)
La Pensée, A. A., Higgins, S. J., Stuart, C. A., & Bickley, J. F. (1999). Homoleptic complexes [Ru(L-L)3]2+ (L-L=diphosphine, diarsine). Inorganic Chemistry Communications, 2(11), 524-526. doi:10.1016/s1387-7003(99)00147-1
Homoleptic complexes [Ru(L-L)3]2+ (L-L=diphosphine, diarsine)
La Pensée, A. A., Higgins, S. J., Stuart, C. A., & Bickley, J. F. (1999). Homoleptic complexes [Ru(L-L)3]2+ (L-L=diphosphine, diarsine). Inorganic Chemistry Communications, 2(11), 524-526. doi:10.1016/S1387-7003(99)00147-1
Symmetrical alkyl-substituted oligothiophenes as ligands: complexation of the [(η-C5H5)Ru]+ moiety by hexyl-substituted ter-, quater- and quinque-thiophenes
Jones, C. L., & Higgins, S. J. (1999). Symmetrical alkyl-substituted oligothiophenes as ligands: complexation of the [(η-C5H5)Ru]+ moiety by hexyl-substituted ter-, quater- and quinque-thiophenes. Journal of Materials Chemistry, 9(4), 865-874. doi:10.1039/a809623f
Synthesis and electropolymerisation of 1,1′-bis(5-oligothienyl)ferrocenes: poly(oligothiophene–ferrocene)-modified electrodes
Higgins, S. J., L. Jones, C., & Francis, S. M. (1999). Synthesis and electropolymerisation of 1,1′-bis(5-oligothienyl)ferrocenes: poly(oligothiophene–ferrocene)-modified electrodes. Synthetic Metals, 98(3), 211-214. doi:10.1016/s0379-6779(98)00189-1
1998
Complexes of 2,3-bis(diphenylphosphino)propene with PtII, PdII and RuII: synthesis, characterisation and rearrangements to complexes of cis-1,2-bis(diphenylphosphino)propene
Barkley, J., Higgins, S. J., & McCart, M. K. (1998). Complexes of 2,3-bis(diphenylphosphino)propene with PtII, PdII and RuII: synthesis, characterisation and rearrangements to complexes of cis-1,2-bis(diphenylphosphino)propene. Journal of the Chemical Society, Dalton Transactions, (11), 1787-1792. doi:10.1039/a801351i
Further analysis of space-charge-limited currents in polybenzo[c]thiophene films
Musa, I., Eccleston, W., & Higgins, S. J. (1998). Further analysis of space-charge-limited currents in polybenzo[c]thiophene films. Journal of Applied Physics, 83(10), 5558-5560. doi:10.1063/1.367497
Unusually Stable Four-Membered Chelate Rings in Nickel(II), Palladium(II), and Platinum(II) Complexes with the Ligand 2,2-Bis(diphenylphosphino)propane (2,2-dppp). Crystal and Molecular Structure of [PdI<sub>2</sub>(2,2-dppp)]·0.8CH<sub>2</sub>Cl<sub>2</sub>
Barkley, J., Ellis, M., Higgins, S. J., & McCart, M. K. (1998). Unusually Stable Four-Membered Chelate Rings in Nickel(II), Palladium(II), and Platinum(II) Complexes with the Ligand 2,2-Bis(diphenylphosphino)propane (2,2-dppp). Crystal and Molecular Structure of [PdI<sub>2</sub>(2,2-dppp)]·0.8CH<sub>2</sub>Cl<sub>2</sub>. Organometallics, 17(9), 1725-1731. doi:10.1021/om970941t
1997
Space-charge limited conduction processes in polybenzo[c]thiophene films
Musa, I., Higgins, S. J., & Eccleston, W. (1997). Space-charge limited conduction processes in polybenzo[c]thiophene films. Journal of Applied Physics, 81(5), 2288-2290. doi:10.1063/1.364280
Addition of alcohols and pyrroles to trans- RuCl2{(Ph2P)(2)C=CH2}(2) . A polypyrrole bearing a covalently bound metal-diphosphine complex
Higgins, S. J., Jones, H. L., McCart, M. K., & Pounds, T. J. (1997). Addition of alcohols and pyrroles to trans- RuCl2{(Ph2P)(2)C=CH2}(2) . A polypyrrole bearing a covalently bound metal-diphosphine complex. Chemical Communications, (19), 1907-1908.
Addition of alcohols and pyrroles to trans-[RuCl2{(Ph2P)2C=CH2} 2]. A polypyrrole bearing a covalently bound metal-diphosphine complex
Higgins, S. J., Jones, H. L., McCart, M. K., & Pounds, T. J. (1997). Addition of alcohols and pyrroles to trans-[RuCl2{(Ph2P)2C=CH2} 2]. A polypyrrole bearing a covalently bound metal-diphosphine complex. Chemical Communications, (19), 1907-1908.
Conjugated polymers incorporating pendant functional groups—synthesis and characterisation
Higgins, S. J. (1997). Conjugated polymers incorporating pendant functional groups—synthesis and characterisation. Chem. Soc. Rev., 26(4), 247-257. doi:10.1039/cs9972600247
Nickel 1995
Higgins, S. J. (1997). Nickel 1995. Coordination Chemistry Reviews, 164, 503-573. doi:10.1016/s0010-8545(97)00037-4
Nucleophilic Addition to Complexes of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>as a Route to Functionalized, Redox-Active Ruthenium(II)−Diphosphine Complexes
Barkley, J. V., Higgins, S. J., McCart, M. K., & Pounds, T. J. (1997). Nucleophilic Addition to Complexes of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>as a Route to Functionalized, Redox-Active Ruthenium(II)−Diphosphine Complexes. Inorganic Chemistry, 36(27), 6188-6196. doi:10.1021/ic970799o
1996
Improved preparation of polybenzo[c]thiophene-modified electrodes employing p-toluenesulfonate as dopant anion
Higgins, S. J., Jones, C., King, G., Slack, K. H. D., & Pétidy, S. (1996). Improved preparation of polybenzo[c]thiophene-modified electrodes employing p-toluenesulfonate as dopant anion. Synthetic Metals, 78(2), 155-159. doi:10.1016/0379-6779(96)80117-2
In situ FTIR study of charge conduction in a poly(3-methylthiophene)–poly({1-[2-(3-thienyl)ethyl]-1,4,8,11-tetraazacyclotetradecane}nickel(<scp>II</scp>) perchlorate) copolymer film
Christensen, P. A., Hamnett, A., & Higgins, S. J. (1996). In situ FTIR study of charge conduction in a poly(3-methylthiophene)–poly({1-[2-(3-thienyl)ethyl]-1,4,8,11-tetraazacyclotetradecane}nickel(<scp>II</scp>) perchlorate) copolymer film. J. Chem. Soc., Faraday Trans., 92(5), 773-781. doi:10.1039/ft9969200773
6. Nickel 1994
Higgins, S. J. (1996). 6. Nickel 1994. Coordination Chemistry Reviews, 152, 175-249. doi:10.1016/0010-8545(96)01273-8
In Situ Ellipsometry and FTIR Spectroscopy Applied to Electroactive Polymer-Modified Electrodes
Higgins, S. J., Christensen, P. A., & Hamnett, A. (1996). In Situ Ellipsometry and FTIR Spectroscopy Applied to Electroactive Polymer-Modified Electrodes. In Electroactive Polymer Electrochemistry (pp. 133-172). Springer US. doi:10.1007/978-1-4899-1715-7_3
1995
A novel method for oxide surface modification using functionalised diphosphine complexes
Higgins, S. J., McCart, M. K., McElhinney, M., Nugent, D. C., & Pounds, T. J. (1995). A novel method for oxide surface modification using functionalised diphosphine complexes. Journal of the Chemical Society, Chemical Communications, (20), 2129. doi:10.1039/c39950002129
Four-membered chelate rings in complexes with 2,2-bis(diphenylphosphino)propane. Crystal and molecular structures of trans-[RuCl<sub>2</sub>{Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}<sub>2</sub>], [RuCl{Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}(η-C<sub>5</sub>H<sub>5</sub>)] and [(η-C<sub>5</sub>H<sub>5</sub>)Ru(µ-CO)<sub>2</sub>-{µ-Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}RhCl<sub>2</sub>](Rh–Ru)
Barkley, J. V., Grimshaw, J. C., Higgins, S. J., Hoare, P. B., McCart, M. K., & Smith, A. K. (1995). Four-membered chelate rings in complexes with 2,2-bis(diphenylphosphino)propane. Crystal and molecular structures of trans-[RuCl<sub>2</sub>{Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}<sub>2</sub>], [RuCl{Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}(η-C<sub>5</sub>H<sub>5</sub>)] and [(η-C<sub>5</sub>H<sub>5</sub>)Ru(µ-CO)<sub>2</sub>-{µ-Me<sub>2</sub>C(PPh<sub>2</sub>)<sub>2</sub>}RhCl<sub>2</sub>](Rh–Ru). J. Chem. Soc., Dalton Trans., (17), 2901-2908. doi:10.1039/dt9950002901
An in-situ Fourier transform infrared study of CO2 electroreduction catalysed by Ni(0)—4,4′-dimethyl 2,2′-bipyridine and Ni(0)—1,10-phenanthroline complexes
Christensen, P. A., Hamnett, A., Higgins, S. J., & Timney, J. A. (1995). An in-situ Fourier transform infrared study of CO2 electroreduction catalysed by Ni(0)—4,4′-dimethyl 2,2′-bipyridine and Ni(0)—1,10-phenanthroline complexes. Journal of Electroanalytical Chemistry, 395(1-2), 195-209. doi:10.1016/0022-0728(95)04133-9
The electrochemical reduction of CO2 to oxalate at a Pt electrode immersed in acetonitrile and coated with
Christensen, P. A., & Higgins, S. J. (1995). The electrochemical reduction of CO2 to oxalate at a Pt electrode immersed in acetonitrile and coated with. Journal of Electroanalytical Chemistry, 387(1-2), 127-132. doi:10.1016/0022-0728(95)03949-h
4-Membered Chelate Rings in Complexes with 2.2- Bis(Diphenylphosphino)Propane - Crystal and Molecular- Structures of Trans- Rucl2(Me(2)C(Pph(2))(2))(2) , Rucl(Me(2)C(Pph(2))(2))(Eta-C5h5) and (Eta-C5h5)Ru(Mu- Co)(2)(Mu-Me(2)C(Pph(2))(2))Rhcl2 (Rh-Ru)
Barkley, J. V., Grimshaw, J. C., Higgins, S. J., Hoare, P. B., McCart, M. K., & Smith, A. K. (1995). 4-Membered Chelate Rings in Complexes with 2.2- Bis(Diphenylphosphino)Propane - Crystal and Molecular- Structures of Trans- Rucl2(Me(2)C(Pph(2))(2))(2) , Rucl(Me(2)C(Pph(2))(2))(Eta-C5h5) and (Eta-C5h5)Ru(Mu- Co)(2)(Mu-Me(2)C(Pph(2))(2))Rhcl2 (Rh-Ru). Journal of the Chemical Society-Dalton Transactions, (17), 2901-2908.
6. Nickel 1993
Higgins, S. J. (1995). 6. Nickel 1993. Coordination Chemistry Reviews, 146, 115-201. doi:10.1016/0010-8545(96)83892-6
Nickel 1993
Higgins, S. J. (1995). Nickel 1993. Coordination Chemistry Reviews, 146, 115-201.
Synthesis and characterisation of novel substituted benzo[c]thiophenes and polybenzo[c]thiophenes: tuning the potentials for n- and p-doping in transparent conducting polymers
King, G., & Higgins, S. J. (1995). Synthesis and characterisation of novel substituted benzo[c]thiophenes and polybenzo[c]thiophenes: tuning the potentials for n- and p-doping in transparent conducting polymers. Journal of Materials Chemistry, 5(3), 447. doi:10.1039/jm9950500447
1994
Analysis of electrogenerated films by ellipsometry and infrared spectrometry
Hamnett, A., Christensen, P. A., & Higgins, S. J. (1994). Analysis of electrogenerated films by ellipsometry and infrared spectrometry. The Analyst, 119(5), 735. doi:10.1039/an9941900735
Growth and electrochemical behaviour of a poly [tricarbonyl(vinylbipyridyl)rhenium chloride] film. Heterogeneous reduction of CO2
Christensen, P., Hamnett, A., Muir, A. V. G., Timney, J. A., & Higgins, S. (1994). Growth and electrochemical behaviour of a poly [tricarbonyl(vinylbipyridyl)rhenium chloride] film. Heterogeneous reduction of CO2. Journal of the Chemical Society, Faraday Transactions, 90(3), 459. doi:10.1039/ft9949000459
Novel substituted poly(benzo[c]thiophenes); controlling the n- and p-doping potentials
King, G., & Higgins, S. J. (1994). Novel substituted poly(benzo[c]thiophenes); controlling the n- and p-doping potentials. Journal of the Chemical Society, Chemical Communications, (7), 825. doi:10.1039/c39940000825
New substituted polybenzo[c]thiophenes: controlling the n- and p-doping potentials
King, G., Higgins, S. J., Garner, S. E., & Robert Hillman, A. (1994). New substituted polybenzo[c]thiophenes: controlling the n- and p-doping potentials. Synthetic Metals, 67(1-3), 241-244. doi:10.1016/0379-6779(94)90049-3
Nickel 1990
Higgins, S. J. (1994). Nickel 1990. Coordination Chemistry Reviews, 134, A1-A73.
1993
An in situ Fourier-transform infrared study of the electroreduction of polybithiophene
Christensen, P. A., Hamnett, A., Hillman, A. R., Swann, M. J., & Higgins, S. J. (1993). An in situ Fourier-transform infrared study of the electroreduction of polybithiophene. Journal of the Chemical Society, Faraday Transactions, 89(6), 921. doi:10.1039/ft9938900921
Metal-containing conducting polymers
Higgins, S., & Crayston, J. A. (1993). Metal-containing conducting polymers. Synthetic Metals, 55(2-3), 879-883. doi:10.1016/0379-6779(93)90168-V
Metal-containing conducting polymers
Higgins, S., & Crayston, J. A. (1993). Metal-containing conducting polymers. Synthetic Metals, 55(2-3), 879-883. doi:10.1016/0379-6779(93)90168-v
An Insitu Fourier-Transform Infrared Study of the Electroreduction of Polybithiophene
Christensen, P. A., Hamnett, A., Hillman, A. R., Swann, M. J., & Higgins, S. J. (1993). An Insitu Fourier-Transform Infrared Study of the Electroreduction of Polybithiophene. Journal of the Chemical Society-Faraday Transactions, 89(6), 921-926.
1992
Charge conduction in polybithiophene : an in situ Fourier-transform infrared study
Christensen, P. A., Hamnett, A., Hillman, A. R., Swann, M. J., & Higgins, S. J. (1992). Charge conduction in polybithiophene : an in situ Fourier-transform infrared study. Journal of the Chemical Society, Faraday Transactions, 88(4), 595. doi:10.1039/ft9928800595
Use of Michael additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>complexes to prepare thiophene- and pyrrole-functionalised metal–phosphine complexes
King, G., Higgins, S. J., & Hopton, A. (1992). Use of Michael additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>complexes to prepare thiophene- and pyrrole-functionalised metal–phosphine complexes. J. Chem. Soc., Dalton Trans., (24), 3403-3409. doi:10.1039/dt9920003403
Insitu Spectroscopic Studies of N-Doped Polybithiophene
Glidle, A., Hillman, A. R., Swann, M. J., Christensen, P. A., Hamnett, A., & Higgins, S. J. (1992). Insitu Spectroscopic Studies of N-Doped Polybithiophene. Abstracts of Papers of the American Chemical Society, 2, 153-COLL.
Novel conducting polymers incorporating covalently bound metal–tetraazamacrocycle complexes
King, G., Higgins, S. J., & Price, N. (1992). Novel conducting polymers incorporating covalently bound metal–tetraazamacrocycle complexes. The Analyst, 117(8), 1243-1246. doi:10.1039/an9921701243
1991
In situ ellipsometric study of the growth and electrochemical cycling of polypyrrole films on platinum
Higgins, S. J., & Hamnett, A. (1991). In situ ellipsometric study of the growth and electrochemical cycling of polypyrrole films on platinum. Electrochimica Acta, 36(14), 2123-2134. doi:10.1016/0013-4686(91)85220-2
1990
A study of electrochemically grown prussian blue films using Fourier-transform infra-red spectroscopy
Christensen, P. A., Hamnett, A., & Higgins, S. J. (1990). A study of electrochemically grown prussian blue films using Fourier-transform infra-red spectroscopy. Journal of the Chemical Society, Dalton Transactions, (7), 2233. doi:10.1039/dt9900002233
1989
General discussion
Owen, J. R., Peter, L. M., Epstein, A. J., Heeger, A. J., Hamnett, A., Lyons, M. E. G., . . . Girault, H. H. (1989). General discussion. Faraday Discussions of the Chemical Society, 88, 291. doi:10.1039/dc9898800291
General discussion
Zambonin, P. G., Doblhofer, K., Peter, L. M., MacDiarmid, A. G., Wegner, G., Lyons, M. E. G., . . . Ratner, M. A. (1989). General discussion. Faraday Discussions of the Chemical Society, 88, 351. doi:10.1039/dc9898800351
General discussion
Vincent, C. A., Latham, R. J., Murray, R. W., Cameron, G. G., Cheradame, M., Bruce, P. G., . . . Peter, L. M. (1989). General discussion. Faraday Discussions of the Chemical Society, 88, 133. doi:10.1039/dc9898800133
An ellipsometric study of polypyrrole films on platinum
Hamnett, A., Higgins, S. J., Fisk, P. R., & Albery, W. J. (1989). An ellipsometric study of polypyrrole films on platinum. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 270(1-2), 479-488. doi:10.1016/0022-0728(89)85063-6
Ellipsometric studies of ferrocene-containing copolymer films
Robert Hillman, A., Taylor, D. A., Hamnett, A., & Higgins, S. J. (1989). Ellipsometric studies of ferrocene-containing copolymer films. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 266(2), 423-435. doi:10.1016/0022-0728(89)85086-7
A combined ellipsometric and in situ infrared (SNIFTIRS) study of poly(benzo-[c]-thiophene) films
Christensen, P. A., Kerr, J. C. H., Higgins, S. J., & Hamnett, A. (1989). A combined ellipsometric and in situ infrared (SNIFTIRS) study of poly(benzo-[c]-thiophene) films. Faraday Discussions of the Chemical Society, 88, 261. doi:10.1039/dc9898800261
Charge transport in electroactive polymer films
Hillman, A. R., Loveday, D. C., Swann, M. J., Eales, R. M., Hamnett, A., Higgins, S. J., . . . Wilde, C. P. (1989). Charge transport in electroactive polymer films. Faraday Discussions of the Chemical Society, 88, 151. doi:10.1039/dc9898800151
Nucleophilic (Michael) additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>when chelated to platinum(<scp>II</scp>) dichloride or di-iodide
Higgins, S. J., & Shaw, B. L. (1989). Nucleophilic (Michael) additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>when chelated to platinum(<scp>II</scp>) dichloride or di-iodide. J. Chem. Soc., Dalton Trans., (8), 1527-1530. doi:10.1039/dt9890001527
1988
Syntheses of vinylidene-bridged A-frame palladium complexes containing Ph2PCH2PPh2 or Ph2PCHMePPh2: protonation to give carbyne-bridged complexes
Fontaine, X. L. R., Higgins, S. J., & Shaw, B. L. (1988). Syntheses of vinylidene-bridged A-frame palladium complexes containing Ph2PCH2PPh2 or Ph2PCHMePPh2: protonation to give carbyne-bridged complexes. Journal of the Chemical Society, Dalton Transactions, (5), 1179. doi:10.1039/dt9880001179
A study of the electrodeposition and subsequent potential cycling of Prussian Blue films using ellipsometry
Hamnett, A., Higgins, S., Mortimer, R. S., & Rosseinsky, D. R. (1988). A study of the electrodeposition and subsequent potential cycling of Prussian Blue films using ellipsometry. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 255(1-2), 315-324. doi:10.1016/0022-0728(88)80024-x
Acid-catalysed additions of acetylenes to [XPd(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>PdX](X = Cl, Br, or I) to give dimetallated olefin complexes of type [XPd(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>(µ-HCCR)PdX](R = H, Ph, or C<sub>6</sub>H<sub>4</sub>Me-p)
Higgins, S. J., & Shaw, B. L. (1988). Acid-catalysed additions of acetylenes to [XPd(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>PdX](X = Cl, Br, or I) to give dimetallated olefin complexes of type [XPd(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>(µ-HCCR)PdX](R = H, Ph, or C<sub>6</sub>H<sub>4</sub>Me-p). J. Chem. Soc., Dalton Trans., (2), 457-460. doi:10.1039/dt9880000457
Nucleophilic (Michael) additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>when chelated to dimethylplatinum(<scp>II</scp>), di(o-tolyl)platinum(<scp>II</scp>), or iodo(trimethyl)platinum(<scp>IV</scp>). Crystal structure of [PtMe<sub>3</sub>I{(PPh<sub>2</sub>)CH(PPh<sub>2</sub>)CH<sub>2</sub>NHCH<sub>2</sub>Ph}]
Hassan, F. S. M., Higgins, S. J., Jacobsen, G. B., Shaw, B. L., & Thornton-Pett, M. (1988). Nucleophilic (Michael) additions to (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>when chelated to dimethylplatinum(<scp>II</scp>), di(o-tolyl)platinum(<scp>II</scp>), or iodo(trimethyl)platinum(<scp>IV</scp>). Crystal structure of [PtMe<sub>3</sub>I{(PPh<sub>2</sub>)CH(PPh<sub>2</sub>)CH<sub>2</sub>NHCH<sub>2</sub>Ph}]. J. Chem. Soc., Dalton Trans., (12), 3011-3016. doi:10.1039/dt9880003011
Syntheses of vinylidene-bridged A-frame palladium complexes containing Ph 2 PCH 2 PPh 2 or Ph 2 PCHMePPh 2 : protonation to give carbyne-bridged complexes
Fontaine, X. L. R., Higgins, S. J., & Shaw, B. L. (1988). Syntheses of vinylidene-bridged A-frame palladium complexes containing Ph 2 PCH 2 PPh 2 or Ph 2 PCHMePPh 2 : protonation to give carbyne-bridged complexes. Dalton Transactions, 0(5), 1179-1184. doi:10.1039/dt9880001179
1987
Coordination chemistry of higher oxidation states. Part 24. Palladium(IV) and nickel(III) complexes of hybrid thio- and seleno-ether ligands
Harbron, S. K., Higgins, S. J., Hope, E. G., Kemmitt, T., & Levason, W. (1987). Coordination chemistry of higher oxidation states. Part 24. Palladium(IV) and nickel(III) complexes of hybrid thio- and seleno-ether ligands. Inorganica Chimica Acta, 130(1), 43-47. doi:10.1016/s0020-1693(00)85927-7
Complexes of platinum(II) and palladium(II) with hybrid phosphine-phosphine oxide ligands of type Ph2P(CH2) P()Ph2 (n = 1, 2, 3, or 4)
Higgins, S. J., Taylor, R., & Shaw, B. L. (1987). Complexes of platinum(II) and palladium(II) with hybrid phosphine-phosphine oxide ligands of type Ph2P(CH2) P()Ph2 (n = 1, 2, 3, or 4). Journal of Organometallic Chemistry, 325(1-2), 285-292. doi:10.1016/0022-328x(87)80408-4
Complexes of platinum(II) and palladium(II) with hybrid phosphine-phosphine oxide ligands of type Ph2P(CH2)nP()Ph2 (n = 1, 2, 3, or 4)
Higgins, S. J., Taylor, R., & Shaw, B. L. (1987). Complexes of platinum(II) and palladium(II) with hybrid phosphine-phosphine oxide ligands of type Ph2P(CH2)nP()Ph2 (n = 1, 2, 3, or 4). Journal of Organometallic Chemistry, 325(1-2), 285-292. doi:10.1016/0022-328x(87)80408-4
Bimetallic systems. Part 18. Nickel( II )-mercury( II ) acetylide complexes containing bridging Ph 2 PCH 2 PPh 2 ligands
Fontaine, X. L. R., Higgins, S. J., Langrick, C. R., & Shaw, B. L. (1987). Bimetallic systems. Part 18. Nickel( II )-mercury( II ) acetylide complexes containing bridging Ph 2 PCH 2 PPh 2 ligands. Dalton Transactions, 0(4), 777-779. doi:10.1039/dt9870000777
Bimetallic systems. Part 18. Nickel(II)-mercury(II) acetylide complexes containing bridging Ph2PCH2PPh2 ligands
Fontaine, X. L. R., Higgins, S. J., Langrick, C. R., & Shaw, B. L. (1987). Bimetallic systems. Part 18. Nickel(II)-mercury(II) acetylide complexes containing bridging Ph2PCH2PPh2 ligands. Journal of the Chemical Society, Dalton Transactions, (4), 777. doi:10.1039/dt9870000777
Bimetallic systems. Part 21. Synthesis of vinylidene- and phenylene-bridged complexes of dinickel(<scp>II</scp>), nickel(<scp>II</scp>)–palladium(<scp>II</scp>), and nickel(<scp>II</scp>)-platinum(<scp>II</scp>) containing Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>(dppm): crystal structures of [(SCN)Ni(µ-dppm)<sub>2</sub>(µ-CCH<sub>2</sub>)Ni(NCS)] and [ClPd(µ-dppm)<sub>2</sub>(µ-CCCl<sub>2</sub>)NiCl]
Fontaine, X. L. R., Higgins, S. J., Shaw, B. L., Thornton-Pett, M., & Yichang, W. (1987). Bimetallic systems. Part 21. Synthesis of vinylidene- and phenylene-bridged complexes of dinickel(<scp>II</scp>), nickel(<scp>II</scp>)–palladium(<scp>II</scp>), and nickel(<scp>II</scp>)-platinum(<scp>II</scp>) containing Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>(dppm): crystal structures of [(SCN)Ni(µ-dppm)<sub>2</sub>(µ-CCH<sub>2</sub>)Ni(NCS)] and [ClPd(µ-dppm)<sub>2</sub>(µ-CCCl<sub>2</sub>)NiCl]. J. Chem. Soc., Dalton Trans., (6), 1501-1507. doi:10.1039/dt9870001501
1986
Coordination chemistry of higher oxidation states. 19. Synthesis and properties of diphosphine and diarsine complexes of iron(IV), and iron K-edge EXAFS data on [Fe(o-C6H4(PMe2)2)2Cl2]n+[BF4]n (n = 0-2)
Harbron, S. K., Higgins, S. J., Levason, W., Feiters, M. C., & Steel, A. T. (1986). Coordination chemistry of higher oxidation states. 19. Synthesis and properties of diphosphine and diarsine complexes of iron(IV), and iron K-edge EXAFS data on [Fe(o-C6H4(PMe2)2)2Cl2]n+[BF4]n (n = 0-2). Inorganic Chemistry, 25(11), 1789-1794. doi:10.1021/ic00231a015
Nickel(II) fluoride complexes of diamines and diimines
Higgins, S. J., & Levason, W. (1986). Nickel(II) fluoride complexes of diamines and diimines. Inorganica Chimica Acta, 113(1), 47-50. doi:10.1016/s0020-1693(00)86856-5
Co-ordination chemistry of higher oxidation states. Part 17. Synthesis and properties of nickel( IV ) complexes with neutral ligands, and structures of [Ni{ o -C 6 H 4 (EMe 2 ) 2 } 2 Cl 2 ][ClO 4 ] n (E = P or As; n = 1 or 2) by nickel K -edge extended X -ray absorption fine structure
Higgins, S. J., Levason, W., Feiters, M. C., & Steel, A. T. (1986). Co-ordination chemistry of higher oxidation states. Part 17. Synthesis and properties of nickel( IV ) complexes with neutral ligands, and structures of [Ni{ o -C 6 H 4 (EMe 2 ) 2 } 2 Cl 2 ][ClO 4 ] n (E = P or As; n = 1 or 2) by nickel K -edge extended X -ray absorption fine structure. Dalton Transactions, 0(2), 317-322. doi:10.1039/dt9860000317
Co-ordination chemistry of higher oxidation states. Part 17. Synthesis and properties of nickel(IV) complexes with neutral ligands, and structures of [Ni{o-C6H4(EMe2)2}2Cl2][ClO4] n (E = P or As; n= 1 or 2) by nickel K-edge extended X-ray absorption fine structure
Higgins, S. J., Levason, W., Feiters, M. C., & Steel, A. T. (1986). Co-ordination chemistry of higher oxidation states. Part 17. Synthesis and properties of nickel(IV) complexes with neutral ligands, and structures of [Ni{o-C6H4(EMe2)2}2Cl2][ClO4] n (E = P or As; n= 1 or 2) by nickel K-edge extended X-ray absorption fine structure. Journal of the Chemical Society, Dalton Transactions, (2), 317. doi:10.1039/dt9860000317
Iron K-edge EXAFS data on [Fe(o-C6H4(PMe2)2)2Cl2][BF4]n (n = 0-2). The structure of an iron(IV) complex of o-phenylenebis(dimethylphosphine)
Harbron, S. K., Higgins, S. J., Levason, W., Garner, C. D., Steel, A. T., Feiters, M. C., & Hasnain, S. S. (1986). Iron K-edge EXAFS data on [Fe(o-C6H4(PMe2)2)2Cl2][BF4]n (n = 0-2). The structure of an iron(IV) complex of o-phenylenebis(dimethylphosphine). Journal of the American Chemical Society, 108(3), 526-528. doi:10.1021/ja00263a039
The extremely rapid acid-catalysed additions of acetylenes to [Pd<sub>2</sub>Cl<sub>2</sub>(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>] and the synthesis of [Pd<sub>2</sub>Cl<sub>2</sub>(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>(µ-CCH<sub>2</sub>)]
Higgins, S. J., & Shaw, B. L. (1986). The extremely rapid acid-catalysed additions of acetylenes to [Pd<sub>2</sub>Cl<sub>2</sub>(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>] and the synthesis of [Pd<sub>2</sub>Cl<sub>2</sub>(µ-Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>(µ-CCH<sub>2</sub>)]. J. Chem. Soc., Chem. Commun., (22), 1629-1630. doi:10.1039/c39860001629
The high activation of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>by palladium acetate or palladium chloride towards additions
Herring, A. M., Higgins, S. J., Jacobsen, G. B., & Shaw, B. L. (1986). The high activation of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>by palladium acetate or palladium chloride towards additions. J. Chem. Soc., Chem. Commun., (11), 882-883. doi:10.1039/c39860000882
1985
Structure of trans-dichlorobis[3,4,5,6-tetrafluoro-o-phenylenebis(dimethylphosphine)]iron(III) tetrafluoroborate, [FeCl2(C10H12F4P2)2]BF4
Higgins, S. J., Jewiss, H. C., Levason, W., & Webster, M. (1985). Structure of trans-dichlorobis[3,4,5,6-tetrafluoro-o-phenylenebis(dimethylphosphine)]iron(III) tetrafluoroborate, [FeCl2(C10H12F4P2)2]BF4. Acta Crystallographica Section C Crystal Structure Communications, 41(5), 695-697. doi:10.1107/s0108270185005157
Combination of EXAFS and electronic spectroscopy to determine the structure of nickel(IV) complexes
Steel, A. T., Feiters, M. C., Garner, C. D., Hasnain, S. S., Levason, W., & Higgins, S. J. (1985). Combination of EXAFS and electronic spectroscopy to determine the structure of nickel(IV) complexes. Journal of the Chemical Society, Chemical Communications, (8), 484. doi:10.1039/c39850000484
Coordination chemistry of higher oxidation states. 12. Synthesis and complexes of the bis(phosphine) 1,2-bis(dimethylphosphino)-3,4,5,6-tetrafluorobenzene o-C6F4(PMe2)2
Higgins, S. J., & Levason, W. (1985). Coordination chemistry of higher oxidation states. 12. Synthesis and complexes of the bis(phosphine) 1,2-bis(dimethylphosphino)-3,4,5,6-tetrafluorobenzene o-C6F4(PMe2)2. Inorganic Chemistry, 24(7), 1105-1107. doi:10.1021/ic00201a030
The very high activity of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>to Michael additions when complexed to platinum(<scp>II</scp>) or platinum(<scp>IV</scp>)
Fonmtaine, X. L. R., Hassan, F. S. M., Higgins, S. J., Jacobsen, G. B., Shaw, B. L., & Thornton-Pett, M. (1985). The very high activity of (Ph<sub>2</sub>P)<sub>2</sub>CCH<sub>2</sub>to Michael additions when complexed to platinum(<scp>II</scp>) or platinum(<scp>IV</scp>). J. Chem. Soc., Chem. Commun., (22), 1635-1636. doi:10.1039/c39850001635
1984
Co-ordination chemistry of higher oxidation states. Part 11. The reaction of nickel(<scp>II</scp>) iodo-complexes with molecular iodine; crystal and molecular structure of [Ni{o-C<sub>6</sub>H<sub>4</sub>(PMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>][I<sub>3</sub>]<sub>2</sub>·2I<sub>2</sub>
Gray, L. R., Higgins, S. J., Levason, W., & Webster, M. (1984). Co-ordination chemistry of higher oxidation states. Part 11. The reaction of nickel(<scp>II</scp>) iodo-complexes with molecular iodine; crystal and molecular structure of [Ni{o-C<sub>6</sub>H<sub>4</sub>(PMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>][I<sub>3</sub>]<sub>2</sub>·2I<sub>2</sub>. J. Chem. Soc., Dalton Trans., (7), 1433-1439. doi:10.1039/dt9840001433
Coordination chemistry of higher oxidation states Part 9 [1]. Nickel(III) complexes of monodentate phosphines and related ligands
Higgins, S. J., Levason, W., & Wilkes, D. J. (1984). Coordination chemistry of higher oxidation states Part 9 [1]. Nickel(III) complexes of monodentate phosphines and related ligands. Inorganica Chimica Acta, 84(1), 1-6. doi:10.1016/s0020-1693(00)87660-4
Osmium(III) and Osmium(IV) complexes of bi- and polydentate thioethers
Ali, R., Higgins, S. J., & Levason, W. (1984). Osmium(III) and Osmium(IV) complexes of bi- and polydentate thioethers. Inorganica Chimica Acta, 84(1), 65-69. doi:10.1016/s0020-1693(00)87670-7
Co-ordination chemistry of higher oxidation states. Part 8. Nickel( III ) complexes of bi- and multi-dentate phosphorus and arsenic ligands; crystal and molecular structure of [Ni(Ph 2 PCH 2 CH 2 PPh 2 )Br 3 ]·C 6 H 5 Me
Gray, L. R., Higgins, S. J., Levason, W., & Webster, M. (1984). Co-ordination chemistry of higher oxidation states. Part 8. Nickel( III ) complexes of bi- and multi-dentate phosphorus and arsenic ligands; crystal and molecular structure of [Ni(Ph 2 PCH 2 CH 2 PPh 2 )Br 3 ]·C 6 H 5 Me. Dalton Transactions, 0(3), 459-467. doi:10.1039/dt9840000459
Co-ordination chemistry of higher oxidation states. Part 8. Nickel(<scp>III</scp>) complexes of bi- and multi-dentate phosphorus and arsenic ligands; crystal and molecular structure of [Ni(Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)Br<sub>3</sub>]·C<sub>6</sub>H<sub>5</sub>Me
Gray, L. R., Higgins, S. J., Levason, W., & Webster, M. (1984). Co-ordination chemistry of higher oxidation states. Part 8. Nickel(<scp>III</scp>) complexes of bi- and multi-dentate phosphorus and arsenic ligands; crystal and molecular structure of [Ni(Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)Br<sub>3</sub>]·C<sub>6</sub>H<sub>5</sub>Me. J. Chem. Soc., Dalton Trans., (3), 459-467. doi:10.1039/dt9840000459
1983
Co-ordination chemistry of higher oxidation states. Part 7. Nickel(<scp>III</scp>) and nickel(<scp>II</scp>)–nickel(<scp>IV</scp>) complexes of ethylenediamine and related ligands. A clarification
Cooper, D. A., Higgins, S. J., & Levason, W. (1983). Co-ordination chemistry of higher oxidation states. Part 7. Nickel(<scp>III</scp>) and nickel(<scp>II</scp>)–nickel(<scp>IV</scp>) complexes of ethylenediamine and related ligands. A clarification. J. Chem. Soc., Dalton Trans., (9), 2131-2133. doi:10.1039/dt9830002131
Platinum metal complexes of the methoxyphenylstibines Ph3-nSb(o-MeOC6H4)n (n = 1, 2, 3,)o-Me2SbC6H4OMe and of Me2Sb(CH2)2O(CH2)2O(CH2)2SbMe2
Higgins, S. J., Levason, W., McCullough, F. P., & Sheikh, B. (1983). Platinum metal complexes of the methoxyphenylstibines Ph3-nSb(o-MeOC6H4)n (n = 1, 2, 3,)o-Me2SbC6H4OMe and of Me2Sb(CH2)2O(CH2)2O(CH2)2SbMe2. Inorganica Chimica Acta, 71, 87-94. doi:10.1016/s0020-1693(00)83643-9