2022
Camara, M., Green, W., MacPhee, C. E., Rakowska, P. D., Raval, R., Richardson, M. C., . . . Webb, J. S. (2022). Economic significance of biofilms: a multidisciplinary and cross-sectoral challenge. NPJ BIOFILMS AND MICROBIOMES, 8(1). doi:10.1038/s41522-022-00306-yDOI: 10.1038/s41522-022-00306-y
Sorzabal-Bellido, I., Barbieri, L., Beckett, A. J., Prior, I. A., Susarrey-Arce, A., Tiggelaar, R. M., . . . Fernandez, Y. A. D. (2022). Effect of Local Topography on Cell Division of <i>Staphylococcus</i> spp.. NANOMATERIALS, 12(4). doi:10.3390/nano12040683DOI: 10.3390/nano12040683
2021
Barbieri, L., Sorzabal Bellido, I., Beckett, A. J., Prior, I. A., Fothergill, J., Diaz Fernandez, Y. A., & Raval, R. (2021). One-step preparation of antimicrobial silicone materials based on PDMS and salicylic acid: insights from spatially and temporally resolved techniques. NPJ BIOFILMS AND MICROBIOMES, 7(1). doi:10.1038/s41522-021-00223-6DOI: 10.1038/s41522-021-00223-6
Morris, G., Sorzabal-Bellido, I., Bilton, M., Dawson, K., McBride, F., Raval, R., . . . Diaz Fernandez, Y. A. (n.d.). A Novel Self-Assembly Strategy for the Fabrication of Nano-Hybrid Satellite Materials with Plasmonically Enhanced Catalytic Activity. Nanomaterials, 11(6), 1580. doi:10.3390/nano11061580DOI: 10.3390/nano11061580
Kunstmann-Olsen, C., Belic, D., Bradley, D. F., Danks, S. P., Diaz Fernandez, Y. A., Grzelczak, M. P., . . . Brust, M. (2021). Ion shuttling between emulsion droplets by crown ether modified gold nanoparticles. Nanoscale Advances. doi:10.1039/d1na00009hDOI: 10.1039/d1na00009h
2020
Wang, X., Fu, Z., Zheng, L., Zhao, C., Wang, X., Chong, S. Y., . . . Cooper, A. I. (2020). Covalent Organic Framework Nanosheets Embedding Single Cobalt Sites for Photocatalytic Reduction of Carbon Dioxide. CHEMISTRY OF MATERIALS, 32(21), 9107-9114. doi:10.1021/acs.chemmater.0c01642DOI: 10.1021/acs.chemmater.0c01642
Li, M., Aveyard, J., Fleming, G., Curran, J. M., McBride, F., Raval, R., & D'Sa, R. A. (2020). Nitric Oxide Releasing Titanium Surfaces for Antimicrobial Bone-Integrating Orthopedic Implants. ACS APPLIED MATERIALS & INTERFACES, 12(20), 22433-22443. doi:10.1021/acsami.0c00871DOI: 10.1021/acsami.0c00871
Smith, J. A., Mulhall, R., Goodman, S., Fleming, G., Allison, H., Raval, R., & Hasell, T. (2020). Investigating the Antibacterial Properties of Inverse Vulcanized Sulfur Polymers. ACS Omega. doi:10.1021/acsomega.9b04267DOI: 10.1021/acsomega.9b04267
Gibson, Q. D., Manning, T. D., Zanella, M., Zhao, T., Murgatroyd, P. J., Robertson, C. M., . . . Rosseinsky, M. J. (2020). Modular design via multiple anion chemistry of the high mobility van der Waals semiconductor Bi4O4SeCl2. Journal of the American Chemical Society, 142(02), 847-856. doi:10.1021/jacs.9b09411DOI: 10.1021/jacs.9b09411
2019
Fleming, G., Aveyard, J., Fothergill, J. L., McBride, F., Raval, R., & D'Sa, R. A. (2019). Effect of Polymer Demixed Nanotopographies on Bacterial Adhesion and Biofilm Formation. POLYMERS, 11(12). doi:10.3390/polym11121921DOI: 10.3390/polym11121921
Sorzabal Bellido, I., Diaz Fernandez, Y. A., Skelton, A. A., Susarrey Arce, A., McBride, F., Prior, I. A., . . . Raval, R. (2019). Exploiting Covalent, H-Bonding, and π–π Interactions to Design Antibacterial PDMS Interfaces That Load and Release Salicylic Acid. ACS Appl. Bio Mater.. doi:10.1021/acsabm.9b00562DOI: 10.1021/acsabm.9b00562
Seufert, K., McBride, F., Jaekel, S., Wit, B., Haq, S., Steiner, A., . . . Grill, L. (2019). Porphine Homocoupling on Au(111). JOURNAL OF PHYSICAL CHEMISTRY C, 123(27), 16690-16698. doi:10.1021/acs.jpcc.9b02770DOI: 10.1021/acs.jpcc.9b02770
Abbasi-Perez, D., Sang, H., Perez-Garcia, L., Floris, A., Amabilino, D. B., Raval, R., . . . Kantorovich, L. (2019). Controlling the preferential motion of chiral molecular walkers on a surface (vol 10, pg 5864, 2019). CHEMICAL SCIENCE, 10(24), 6220. doi:10.1039/c9sc90124hDOI: 10.1039/c9sc90124h
Abbasi-Perez, D., Sang, H., Perez-Garcia, L., Floris, A., Amabilino, D. B., Raval, R., . . . Kantorovich, L. (2019). Controlling the preferential motion of chiral molecular walkers on a surface. CHEMICAL SCIENCE, 10(23), 5864-5874. doi:10.1039/c9sc01135hDOI: 10.1039/c9sc01135h
Omiya, T., Kim, Y., Raval, R., & Arnolds, H. (2019). Ultrafast Vibrational Dynamics of CO Ligands on RuTPP/Cu(110) under Photodesorption Conditions. SURFACES, 2(1), 117-130. doi:10.3390/surfaces2010010DOI: 10.3390/surfaces2010010
2018
Susarrey Arce, A., Hernández-Sánchez, J. F., Marcello, M., Diaz Fernandez, Y. A., Oknianska, A., Sorzabal Bellido, I., . . . Raval, R. (2018). Bacterial Footprints in Elastic Pillared Microstructures. ACS Appl. Bio Mater.. doi:10.1021/acsabm.8b00176DOI: 10.1021/acsabm.8b00176
C H Bond Breaking: A Simple Route to Synthesizing Complex Porphyrin Oligomers at a Surface (Chapter)
McBride, F., & Raval, R. (2018). C H Bond Breaking: A Simple Route to Synthesizing Complex Porphyrin Oligomers at a Surface. In Encyclopedia of Interfacial Chemistry (pp. 1-10). Elsevier. doi:10.1016/b978-0-12-409547-2.13079-3DOI: 10.1016/b978-0-12-409547-2.13079-3
CH bond breaking: A simple route to synthesizing complex porphyrin oligomers at a surface (Chapter)
McBride, F., & Raval, R. (2018). CH bond breaking: A simple route to synthesizing complex porphyrin oligomers at a surface. In Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry (pp. 1-10). doi:10.1016/B978-0-12-409547-2.13079-3DOI: 10.1016/B978-0-12-409547-2.13079-3
2017
Fleming, G., Aveyard, J., Fothergill, J. L., McBride, F., Raval, R., & D'Sa, R. A. (2017). Nitric oxide releasing polymeric coatings for the prevention of biofilm formation. Polymers, 9(11). doi:10.3390/polym9110601DOI: 10.3390/polym9110601
Michailidis, M., Sorzabal-Bellido, I., Adamidou, E., Diaz-Fernandez, Y. A., Aveyard, J. L., Wengier, R., . . . Shchukin, D. G. (2017). Modified Mesoporous Silica Nanoparticles with a Dual Synergetic Antibacterial Effect. ACS applied materials & interfaces, 9(44), 38364-38372. doi:10.1021/acsami.7b14642DOI: 10.1021/acsami.7b14642
Supramolecular effects in self-assembled monolayers: general discussion (2017). FARADAY DISCUSSIONS, 204, 123-158. doi:10.1039/C7FD90073BDOI: 10.1039/C7FD90073B
Raval, R. (2017). Molecular assembly at surfaces: progress and challenges. FARADAY DISCUSSIONS, 204, 9-33. doi:10.1039/c7fd90072dDOI: 10.1039/c7fd90072d
Amabilino, D., Baldea, I., Barykina, O., Batteas, J., Besenius, P., Beton, P., . . . Zuilhof, H. (2017). Preparing macromolecular systems on surfaces: general discussion. FARADAY DISCUSSIONS, 204, 395-418. doi:10.1039/C7FD90076GDOI: 10.1039/C7FD90076G
Amabilino, D., Baldea, I., Batteas, J., Beton, P., Bilbao, N., Costantini, G., . . . Diaz Fernandez, Y. (2017). Probing properties of molecule-based interface systems: general discussion and Discussion of the Concluding Remarks. FARADAY DISCUSSIONS, 204, 503-530. doi:10.1039/C7FD90077EDOI: 10.1039/C7FD90077E
Amabilino, D., Baldea, I., Besenius, P., Beton, P., Blunt, M., Buck, M., . . . Zuilhof, H. (2017). Supramolecular systems at liquid-solid interfaces: general discussion. FARADAY DISCUSSIONS, 204, 271-295. doi:10.1039/c7fd90074kDOI: 10.1039/c7fd90074k
Jiang, S., Song, Q., Massey, A., Chong, S. Y., Chen, L., Sun, S., . . . Cooper, A. I. (2017). Oriented Two-Dimensional Porous Organic Cage Crystals. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 56(32), 9391-9395. doi:10.1002/anie.201704579DOI: 10.1002/anie.201704579
Pallavicini, P., Bassi, B., Chirico, G., Collini, M., Dacarro, G., Fratini, E., . . . Diaz Fernandez, Y. A. (2017). Modular approach for bimodal antibacterial surfaces combining photo-switchable activity and sustained biocidal release. Scientific Reports, 7. doi:10.1038/s41598-017-05693-3DOI: 10.1038/s41598-017-05693-3
Omiya, T., Poli, P., Arnolds, H., Raval, R., Persson, M., & Kim, Y. (2017). Desorption of CO from individual ruthenium porphyrin molecules on a copper surface via an inelastic tunnelling process.. Chemical communications (Cambridge, England), 53(45), 6148-6151. doi:10.1039/c7cc01310hDOI: 10.1039/c7cc01310h
Aveyard, J., Bradley, J. W., McKay, K., McBride, F., Donaghy, D., Raval, R., & D'Sa, R. A. (2017). Linker-free covalent immobilization of nisin using atmospheric pressure plasma induced grafting. Journal of Materials Chemistry B, 5(13), 2500-2510. doi:10.1039/C7TB00113DDOI: 10.1039/C7TB00113D
Chiral segregation driven by a dynamical response of the adsorption footprint to the local adsorption environment: Bitartrate on Cu(110) (Journal article)
darling., forster, M., Lin, C., liu, N., raval, R., & Hodgson, A. (2017). Chiral segregation driven by a dynamical response of the adsorption footprint to the local adsorption environment: Bitartrate on Cu(110). Physical Chemistry Chemical Physics, 19(11), 7617-7623. doi:10.1039/C7CP00622EDOI: 10.1039/C7CP00622E
Zheng, Z., Chang, Z., Xu, G. -K., McBride, F., Ho, A., Zhuola, Z., . . . Shchukin, D. (2017). Microencapsulated Phase Change Materials in Solar-Thermal Conversion Systems: Understanding Geometry-Dependent Heating Efficiency and System Reliability. ACS Nano, 11(1), 721-729. doi:10.1021/acsnano.6b07126DOI: 10.1021/acsnano.6b07126
2016
Forster, M., & Raval, R. (2016). Simple rules and the emergence of complexity in surface chirality. CHEMICAL COMMUNICATIONS, 52(98), 14075-14084. doi:10.1039/c6cc06523fDOI: 10.1039/c6cc06523f
Nanoscale Aspects of Chiral Nucleation and Propagation (Chapter)
Latter, E. G., & Raval, R. (2016). Nanoscale Aspects of Chiral Nucleation and Propagation. In Unknown Book (pp. 285-306). Wiley. doi:10.1002/9781118867334.ch10DOI: 10.1002/9781118867334.ch10
Susarrey-Arce, A., Marin, A., Massey, A., Oknianska, A., Diaz-Fernandez, Y., Hernandez-Sanchez, J. F., . . . Rayal, R. (2016). Pattern Formation by <i>Staphylococcus epidermidis</i> via Droplet Evaporation on Micropillars Arrays at a Surface. LANGMUIR, 32(28), 7159-7169. doi:10.1021/acs.langmuir.6b01658DOI: 10.1021/acs.langmuir.6b01658
Susarrey-Arce, A., Sorzabal-Bellido, I., Oknianska, A., McBride, F., Beckett, A. J., Gardeniers, J. G. E., . . . Fernandez, Y. A. D. (2016). Bacterial viability on chemically modified silicon nanowire arrays. JOURNAL OF MATERIALS CHEMISTRY B, 4(18), 3104-3112. doi:10.1039/c6tb00460aDOI: 10.1039/c6tb00460a
Floris, A., Haq S., In’t Veld, M., Amabilino, D. B., Raval, R., & Kantorovich, L. (2016). Driving Forces for Covalent Assembly of Porphyrins by Selective C–H Bond Activation and Intermolecular Coupling on a Copper Surface. Journal of the American Chemical Society, 138(18), 5837-5847. doi:10.1021/jacs.5b11594DOI: 10.1021/jacs.5b11594
2015
A small molecule that walks along a surface between porphyrin fences assembled in situ (Journal article)
Haq, S., Wit, B., Sang, H., Floris, A., Wang, Y., Wang, J., . . . Raval, R. (2015). A small molecule that walks along a surface between porphyrin fences assembled in situ. Angewandte Chemie, 54(24), 7101-7105. doi:10.1002/anie.201502153DOI: 10.1002/anie.201502153
1D self-assembly of chemisorbed thymine on Cu(110) driven by dispersion forces (Journal article)
Temprano, I., Thomas, G., Haq, S., Dyer, M. S., Latter, E. G., Darling, G. R., . . . Raval, R. (2015). 1D self-assembly of chemisorbed thymine on Cu(110) driven by dispersion forces. JOURNAL OF CHEMICAL PHYSICS, 142(10). doi:10.1063/1.4907721DOI: 10.1063/1.4907721
2014
Haq, S., Hanke, F., Sharp, J., Persson, M., Amabilino, D. B., & Raval, R. (2014). Versatile Bottom-up Construction of Diverse Macromolecules on a Surfaces Observed by Scanning Tunnelling Microscopy. ACS Nano, 8(9), 8856-8870. doi:10.1021/nn502388uDOI: 10.1021/nn502388u
Chirality, shape, and orientation influencing the self-assembly of organic molecules at interfaces (Conference Paper)
Amabilino, D., Xu, H., Saletra, W. J., Raval, R., De Feyter, S., & Haq, S. (2014). Chirality, shape, and orientation influencing the self-assembly of organic molecules at interfaces. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 247. Retrieved from https://www.webofscience.com/
2012
Photon-Based Techniques (Chapter)
Barrett, S. D., Lucas, C., & Raval, R. (2012). Photon-Based Techniques. In K. Wandelt, & K. Wandelt (Eds.), Surface and Interface Science: Concepts and Methods Volume 1 (pp. 1-59). Weinheim: Wiley-VCH Verlag GmbH & Co.
Separation of chiral molecule using a bare metal surface (Patent)
Raval, R. (2012). Separation of chiral molecule using a bare metal surface.
Water-hydroxyl phases on an open metal surface: breaking the ice rules (Journal article)
Forster, M., Raval, R., Carrasco, J., Michaelides, A., & Hodgson, A. (2012). Water-hydroxyl phases on an open metal surface: breaking the ice rules. CHEMICAL SCIENCE, 3(1), 93-102. doi:10.1039/c1sc00355kDOI: 10.1039/c1sc00355k
2011
Heat-to-Connect: Surface Commensurability Directs Organometallic One-Dimensional Self-Assembly (Journal article)
Hanke, F., Haq, S., Raval, R., & Persson, M. (2011). Heat-to-Connect: Surface Commensurability Directs Organometallic One-Dimensional Self-Assembly. ACS NANO, 5(11), 9093-9103. doi:10.1021/nn203337vDOI: 10.1021/nn203337v
Dynamic chiral flipping within strongly chemisorbed molecular monolayers at surfaces (Journal article)
Liu, N., Darling, G. R., & Raval, R. (2011). Dynamic chiral flipping within strongly chemisorbed molecular monolayers at surfaces. CHEMICAL COMMUNICATIONS, 47(40), 11324-11326. doi:10.1039/c1cc13317aDOI: 10.1039/c1cc13317a
Tailoring Homochirality at Surfaces: Going Beyond Molecular Handedness (Journal article)
Forster, M., Dyer, M. S., Persson, M., & Raval, R. (2011). Tailoring Homochirality at Surfaces: Going Beyond Molecular Handedness. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(40), 15992-16000. doi:10.1021/ja202986sDOI: 10.1021/ja202986s
Clean Coupling of Unfunctionalized Porphyrins at Surfaces To Give Highly Oriented Organometallic Oligomers (Journal article)
Haq, S., Hanke, F., Dyer, M. S., Persson, M., Iavicoli, P., Amabilino, D. B., & Raval, R. (2011). Clean Coupling of Unfunctionalized Porphyrins at Surfaces To Give Highly Oriented Organometallic Oligomers. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(31), 12031-12039. doi:10.1021/ja201389uDOI: 10.1021/ja201389u
Understanding the Interaction of the Porphyrin Macrocycle to Reactive Metal Substrates: Structure, Bonding, and Adatom Capture (Journal article)
Dyer, M. S., Robin, A., Haq, S., Raval, R., Persson, M., & Klimes, J. (2011). Understanding the Interaction of the Porphyrin Macrocycle to Reactive Metal Substrates: Structure, Bonding, and Adatom Capture. ACS NANO, 5(3), 1831-1838. doi:10.1021/nn102610kDOI: 10.1021/nn102610k
Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110) (Journal article)
Forster, M., Dyer, M. S., Persson, M., & Raval, R. (2011). Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110). TOPICS IN CATALYSIS, 54(1-4), 13-19. doi:10.1007/s11244-011-9634-9DOI: 10.1007/s11244-011-9634-9
Mapping Complex Chiral Adlayers: A Truly Random 2-D Solid Solution of (<i>RS</i>)-3-Pyrroline-2-Carboxylic Acid on Cu(110) (Journal article)
Forster, M., Dyer, M. S., Barrett, S. D., Persson, M., & Raval, R. (2011). Mapping Complex Chiral Adlayers: A Truly Random 2-D Solid Solution of (<i>RS</i>)-3-Pyrroline-2-Carboxylic Acid on Cu(110). JOURNAL OF PHYSICAL CHEMISTRY C, 115(4), 1180-1185. doi:10.1021/jp1065314DOI: 10.1021/jp1065314
<i>c</i>(2 x 2) Water-Hydroxyl Layer on Cu(110): A Wetting Layer Stabilized by Bjerrum Defects (Journal article)
Forster, M., Raval, R., Hodgson, A., Carrasco, J., & Michaelides, A. (2011). <i>c</i>(2 x 2) Water-Hydroxyl Layer on Cu(110): A Wetting Layer Stabilized by Bjerrum Defects. PHYSICAL REVIEW LETTERS, 106(4). doi:10.1103/PhysRevLett.106.046103DOI: 10.1103/PhysRevLett.106.046103
<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>c</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:mn>2</mml:mn><mml:mo>×</mml:mo><mml:mn>2</mml:mn><mml:mo stretchy="false">)</mml:mo></mml:math>Water-Hydroxyl Layer on Cu(110): A Wetting Layer Stabilized by Bjerrum Defects (Journal article)
Forster, M., Raval, R., Hodgson, A., Carrasco, J., & Michaelides, A. (n.d.). <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>c</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:mn>2</mml:mn><mml:mo>×</mml:mo><mml:mn>2</mml:mn><mml:mo stretchy="false">)</mml:mo></mml:math>Water-Hydroxyl Layer on Cu(110): A Wetting Layer Stabilized by Bjerrum Defects. Physical Review Letters, 106(4). doi:10.1103/physrevlett.106.046103DOI: 10.1103/physrevlett.106.046103
Direction Visualisations on Chirality in Two Dimensions. (Journal article)
Marks, A. G., Forster, M., & Raval, R. (2011). Direction Visualisations on Chirality in Two Dimensions.. Tetrahedron Asymmetry, 21, 1125-1134.
Recognition and Ordering at Surfaces: The Importance of Handedness and Footedness (Journal article)
Mark, A. G., Forster, M., & Raval, R. (2011). Recognition and Ordering at Surfaces: The Importance of Handedness and Footedness. ChemPhysChem, 12, 1474-1480.
2010
Unexpected Deformations Induced by Surface Interaction and Chiral Self-Assembly of Co<SUP>II</SUP>-Tetraphenylporphyrin (Co-TPP) Adsorbed on Cu(110): A Combined STM and Periodic DFT Study (Journal article)
Donovan, P., Robin, A., Dyer, M. S., Persson, M., & Raval, R. (2010). Unexpected Deformations Induced by Surface Interaction and Chiral Self-Assembly of Co<SUP>II</SUP>-Tetraphenylporphyrin (Co-TPP) Adsorbed on Cu(110): A Combined STM and Periodic DFT Study. CHEMISTRY-A EUROPEAN JOURNAL, 16(38), 11641-11652. doi:10.1002/chem.201001776DOI: 10.1002/chem.201001776
A Racemic Conglomerate Nipped in the Bud: A Molecular View of Enantiomer Cross-Inhibition of Conglomerate Nucleation at a Surface (Journal article)
Robin, A., Iavicoli, P., Wurst, K., Dyer, M. S., Haq, S., Amabilino, D. B., & Raval, R. (2010). A Racemic Conglomerate Nipped in the Bud: A Molecular View of Enantiomer Cross-Inhibition of Conglomerate Nucleation at a Surface. CRYSTAL GROWTH & DESIGN, 10(10), 4516-4525. doi:10.1021/cg100806wDOI: 10.1021/cg100806w
2D random organization of racemic amino acid monolayers driven by nanoscale adsorption footprints: Proline on Cu(110) (Journal article)
Forster, M., Dyer, M. S., Persson, M., & Raval, R. (2010). 2D random organization of racemic amino acid monolayers driven by nanoscale adsorption footprints: Proline on Cu(110). Angewandte Chemie - International Edition, 49(13), 2344-2348. doi:10.1002/anie.200904979DOI: 10.1002/anie.200904979
Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110). (Journal article)
Forster, M., Dyer, M., Persson, M., & Raval, R. (2010). Assembly of Chiral Amino-Acids at Surfaces from a Single Molecule Perspective: Proline on Cu(110).. Topics in Catalysis, 54, 13-19.
2009
Drastic symmetry breaking in supramolecular organization of enantiomerically unbalanced monolayers at surfaces (Journal article)
Haq, S., Liu, N., Humblot, V., Jansen, A. P. J., & Raval, R. (2009). Drastic symmetry breaking in supramolecular organization of enantiomerically unbalanced monolayers at surfaces. Nature Chemistry, 1(5), 409-414. doi:10.1038/nchem.295DOI: 10.1038/nchem.295
Adsorption and Organization of the Organic Radical 3-Carboxyproxyl on a Cu(110) Surface: A Combined STM, RAIRS, and DFT Study (Journal article)
Robin, A., Marnell, L., Bjork, J., Dyer, M. S., Bermudez, P. S., Haq, S., . . . Raval, R. (2009). Adsorption and Organization of the Organic Radical 3-Carboxyproxyl on a Cu(110) Surface: A Combined STM, RAIRS, and DFT Study. JOURNAL OF PHYSICAL CHEMISTRY C, 113(30), 13223-13230. doi:10.1021/jp9017579DOI: 10.1021/jp9017579
Probing Conformers and Adsorption Footprints at the Single-Molecule Level in a Highly Organized Amino Acid Assembly of (S)-Proline on Cu(110) (Journal article)
Forster, M., Dyer, M. S., Persson, M., & Raval, R. (2009). Probing Conformers and Adsorption Footprints at the Single-Molecule Level in a Highly Organized Amino Acid Assembly of (S)-Proline on Cu(110). JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(29), 10173-10181. doi:10.1021/ja9020364DOI: 10.1021/ja9020364
1,2-Dichloroethene on Cu(110): Adsorption, dechlorination and trimerisation reactions (Journal article)
Haq, S., Laroze, S. C., Mitchell, C., Winterton, N., & Raval, R. (2009). 1,2-Dichloroethene on Cu(110): Adsorption, dechlorination and trimerisation reactions. Journal of Molecular Catalysis A: Chemical, 305(1-2), 117-120. doi:10.1016/j.molcata.2008.12.018DOI: 10.1016/j.molcata.2008.12.018
A one-dimensional ice structure built from pentagons (Journal article)
Carrasco, J., Michaelides, A., Forster, M., Haq, S., Raval, R., & Hodgson, A. (2009). A one-dimensional ice structure built from pentagons. NATURE MATERIALS, 8(5), 427-431. doi:10.1038/NMAT2403DOI: 10.1038/NMAT2403
2008
Unique intermolecular reaction of simple porphyrins at a metal surface gives covalent nanostructures. (Journal article)
In't Veld, M., Iavicoli, P., Haq, S., Amabilino, D. B., & Raval, R. (2008). Unique intermolecular reaction of simple porphyrins at a metal surface gives covalent nanostructures.. Chemical communications (Cambridge, England), (13), 1536-1538. doi:10.1039/b718865jDOI: 10.1039/b718865j
2007
Hydrogen and Coordination Bonding Supramolecular Structures of Trimesic Acid on Cu(110) (Journal article)
Classen, T., Lingenfelder, M., Wang, Y., Chopra, R., Virojanadara, C., Starke, U., . . . Kern, K. (2007). Hydrogen and Coordination Bonding Supramolecular Structures of Trimesic Acid on Cu(110). The Journal of Physical Chemistry A, 111(49), 12589-12603. doi:10.1021/jp076037oDOI: 10.1021/jp076037o
Direct visualization of enantiospecific substitution of chiral guest molecules into heterochiral molecular assemblies at surfaces (Journal article)
Liu, N., Haq, S., Darling, G. R., & Raval, R. (2007). Direct visualization of enantiospecific substitution of chiral guest molecules into heterochiral molecular assemblies at surfaces. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 46(40), 7613-7616. doi:10.1002/anie.200701675DOI: 10.1002/anie.200701675
Racemic versus Enantiopure Alanine on Cu(110): An Experimental Study (Journal article)
Haq, S., Massey, A., Moslemzadeh, N., Robin, A., Barlow, S. M., & Raval, R. (2007). Racemic versus Enantiopure Alanine on Cu(110): An Experimental Study. Langmuir, 23(21), 10694-10700. doi:10.1021/la700965dDOI: 10.1021/la700965d
Amino acid and peptides on Cu(110) surfaces: Chemical and structural analyses of l-lysine (Journal article)
Humblot, V., Méthivier, C., Raval, R., & Pradier, C. -M. (2007). Amino acid and peptides on Cu(110) surfaces: Chemical and structural analyses of l-lysine. Surface Science, 601(18), 4189-4194. doi:10.1016/j.susc.2007.04.170DOI: 10.1016/j.susc.2007.04.170
NO and dichloroethene reactivity on single crystal and supported Cu nanoparticles: just how big is the materials gap? (Journal article)
Haq, S., & Raval, R. (2007). NO and dichloroethene reactivity on single crystal and supported Cu nanoparticles: just how big is the materials gap?. Physical Chemistry Chemical Physics, 9(27), 3641. doi:10.1039/b702595pDOI: 10.1039/b702595p
Nanoscale insights in the creation and transfer of chirality in amino acid monolayers at defined metal surfaces (Journal article)
Barlow, S. M., & Raval, R. (2007). Nanoscale insights in the creation and transfer of chirality in amino acid monolayers at defined metal surfaces. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 13, 65-73.
2006
Reflection absorption infrared study of the adsorption of dimethylamine on copper (110) and nickel (111) surfaces (Journal article)
Chalker, S., Haq, S., Birtill, J. J., Nunney, T. S., & Raval, R. (2006). Reflection absorption infrared study of the adsorption of dimethylamine on copper (110) and nickel (111) surfaces. Surface Science, 600(11), 2364-2371. doi:10.1016/j.susc.2006.03.038DOI: 10.1016/j.susc.2006.03.038
The local adsorption geometry and electronic structure of alanine on Cu{110} (Journal article)
Jones, G., Jones, L. B., Thibault-Starzyk, F., Seddon, E. A., Raval, R., Jenkins, S. J., & Held, G. (2006). The local adsorption geometry and electronic structure of alanine on Cu{110}. Surface Science, 600(9), 1924-1935. doi:10.1016/j.susc.2006.02.033DOI: 10.1016/j.susc.2006.02.033
The interaction of γ-glycidoxypropyltrimethoxy silane and model analogues with the Al(111) surface (Journal article)
Woods, G. A., Haq, S., Shaw, S. J., & Raval, R. (2006). The interaction of γ-glycidoxypropyltrimethoxy silane and model analogues with the Al(111) surface. International Journal of Adhesion and Adhesives, 26(1-2), 94-102. doi:10.1016/j.ijadhadh.2003.06.002DOI: 10.1016/j.ijadhadh.2003.06.002
Molecular Sociology (Journal article)
Raval, R. (2006). Molecular Sociology. Nature, 442, 605.
2005
Polymorphism in supramolecular chiral structures of R- and S-alanine on Cu(110) (Journal article)
Barlow, S. M., Louafi, S., Le Roux, D., Williams, J., Muryn, C., Haq, S., & Raval, R. (2005). Polymorphism in supramolecular chiral structures of R- and S-alanine on Cu(110). Surface Science, 590(2-3), 243-263. doi:10.1016/j.susc.2005.06.015DOI: 10.1016/j.susc.2005.06.015
IRAS investigation of a catenane adsorption on Au(111) (Journal article)
Fustin, C. A., Haq, S., Wingen, A., Grégoire, C., Raval, R., Dumas, P., . . . Rudolf, P. (2005). IRAS investigation of a catenane adsorption on Au(111). Surface Science, 580(1-3), 57-62. doi:10.1016/j.susc.2005.02.021DOI: 10.1016/j.susc.2005.02.021
Chiral metal surfaces from the adsorption of chiral and achiral molecules (Journal article)
Humblot, V., & Raval, R. (2005). Chiral metal surfaces from the adsorption of chiral and achiral molecules. Applied Surface Science, 241(1-2), 150-156. doi:10.1016/j.apsusc.2004.09.058DOI: 10.1016/j.apsusc.2004.09.058
CHx hydrogenation on Co(0001): A density functional theory study (Journal article)
Gong, X. Q., Raval, R., & Hu, P. (2005). CHx hydrogenation on Co(0001): A density functional theory study. J. Chemical Physics, 122.
Chemical Transformation, Volume Expansion and Kinetics Barriers to Creating the Chiral Phase of R,R-Tartaric acid on Cu(110). (Journal article)
Ortega-Lorenzo, M., Humblot, V., Murray, P., Baddeley, C. J., Haq, S., & Raval, R. (2005). Chemical Transformation, Volume Expansion and Kinetics Barriers to Creating the Chiral Phase of R,R-Tartaric acid on Cu(110).. Journal of Catalysis, 205, 123-134.
2004
(,)-Tartaric acid on Ni(110): the dynamic nature of chiral adsorption motifs (Journal article)
HUMBLOT, V., HAQ, S., MURYN, C., & RAVAL, R. (2004). (,)-Tartaric acid on Ni(110): the dynamic nature of chiral adsorption motifs. Journal of Catalysis, 228(1), 130-140. doi:10.1016/j.jcat.2004.08.023DOI: 10.1016/j.jcat.2004.08.023
trans-1,2-Dichloroethene on Cu50Pd50(110) alloy surface: dynamical changes in the adsorption, reaction, and surface segregation (Journal article)
BLOXHAM, L., HAQ, S., YUGNET, Y., BERTOLINI, J., & RAVAL, R. (2004). trans-1,2-Dichloroethene on Cu50Pd50(110) alloy surface: dynamical changes in the adsorption, reaction, and surface segregation. Journal of Catalysis, 227(1), 33-43. doi:10.1016/j.jcat.2004.06.015DOI: 10.1016/j.jcat.2004.06.015
Supramolecular assembly of strongly chemisorbed size- and shape-defined chiral clusters: S- and R-alanine on Cu(110). (Journal article)
Barlow, S. M., Louafi, S., Le Roux, D., Williams, J., Muryn, C., Haq, S., & Raval, R. (2004). Supramolecular assembly of strongly chemisorbed size- and shape-defined chiral clusters: S- and R-alanine on Cu(110).. Langmuir : the ACS journal of surfaces and colloids, 20(17), 7171-7176. doi:10.1021/la049391bDOI: 10.1021/la049391b
Adsorption and reaction of trans-1,2-dichloroethene on copper nanoclusters supported on thin Al2O3 films (Journal article)
HAQ, S. (2004). Adsorption and reaction of trans-1,2-dichloroethene on copper nanoclusters supported on thin Al2O3 films. Journal of Catalysis, 226(1), 1-8. doi:10.1016/j.jcat.2004.04.036DOI: 10.1016/j.jcat.2004.04.036
Local and Global Chirality at Surfaces: Succinic Acid versus Tartaric Acid on Cu(110) (Journal article)
Humblot, V., Lorenzo, M. O., Baddeley, C. J., Haq, S., & Raval, R. (2004). Local and Global Chirality at Surfaces: Succinic Acid versus Tartaric Acid on Cu(110). Journal of the American Chemical Society, 126(20), 6460-6469. doi:10.1021/ja0382056DOI: 10.1021/ja0382056
Conveying chirality onto the electronic structure of achiral metals: (R,R)-tartaric acid on nickel (Journal article)
Hofer, W. A., Humblot, V., & Raval, R. (2004). Conveying chirality onto the electronic structure of achiral metals: (R,R)-tartaric acid on nickel. Surface Science, 554(2-3), 141-149. doi:10.1016/j.susc.2003.12.060DOI: 10.1016/j.susc.2003.12.060
Nitric oxide reduction by Cu nanoclusters supported on thin Al2O3 films (Journal article)
Haq, S. (2004). Nitric oxide reduction by Cu nanoclusters supported on thin Al2O3 films. Journal of Catalysis, 221(1), 204-212. doi:10.1016/s0021-9517(03)00311-7DOI: 10.1016/s0021-9517(03)00311-7
2003
Methods and devices utilising adsorption of chiral molecules at a surface or interface (Patent)
Raval, R. (2003). Methods and devices utilising adsorption of chiral molecules at a surface or interface.
Complex organic molecules at metal surfaces: bonding, organisation and chirality (Journal article)
Barlow, S. M., & Raval, R. (2003). Complex organic molecules at metal surfaces: bonding, organisation and chirality. Surface Science Reports, 50(6-8), 201-341. doi:10.1016/s0167-5729(03)00015-3DOI: 10.1016/s0167-5729(03)00015-3
Chlorinated ethenes at Cu(110): adsorption, dissociation and reactions of trans-1,2-dichloroethene (Journal article)
Haq, S., Laroze, S. C., Mitchell, C., Winterton, N., & Raval, R. (2003). Chlorinated ethenes at Cu(110): adsorption, dissociation and reactions of trans-1,2-dichloroethene. Surface Science, 531(2), 145-158. doi:10.1016/s0039-6028(03)00441-2DOI: 10.1016/s0039-6028(03)00441-2
RAIRS investigations on the orientation and intermolecular interactions of adenine on Cu(110) (Journal article)
McNutt, A., Haq, S., & Raval, R. (2003). RAIRS investigations on the orientation and intermolecular interactions of adenine on Cu(110). Surface Science, 531(2), 131-144. doi:10.1016/s0039-6028(03)00444-8DOI: 10.1016/s0039-6028(03)00444-8
Carbon Monoxide on γ-Alumina Single Crystal Surfaces with Gold Nanoparticles (Journal article)
Winkler, C., Carew, A. J., Haq, S., & Raval, R. (2003). Carbon Monoxide on γ-Alumina Single Crystal Surfaces with Gold Nanoparticles. Langmuir, 19(3), 717-721. doi:10.1021/la026054zDOI: 10.1021/la026054z
2002
Vibrational dynamics of fullerene molecules adsorbed on metal surfaces studied with synchrotron infrared radiation (Journal article)
Rudolf, P., Raval, R., Dumas, P., & Williams, G. P. (2002). Vibrational dynamics of fullerene molecules adsorbed on metal surfaces studied with synchrotron infrared radiation. Applied Physics A: Materials Science & Processing, 75(1), 147-153. doi:10.1007/s003390101063DOI: 10.1007/s003390101063
High temperature phase of the DNA base thymine on Cu(110): a resonance delocalised bonding system (Conference Paper)
McNutt, A., Haq, S., & Raval, R. (2002). High temperature phase of the DNA base thymine on Cu(110): a resonance delocalised bonding system. In Surface Science Vol. 502-503 (pp. 185-192). Elsevier BV. doi:10.1016/s0039-6028(01)01931-8DOI: 10.1016/s0039-6028(01)01931-8
Bonding and assembly of the chiral amino acid S-proline on Cu(): the influence of structural rigidity (Journal article)
Mateo Marti, E., Barlow, S. M., Haq, S., & Raval, R. (2002). Bonding and assembly of the chiral amino acid S-proline on Cu(): the influence of structural rigidity. Surface Science, 501(3), 191-202. doi:10.1016/s0039-6028(01)02026-xDOI: 10.1016/s0039-6028(01)02026-x
From local adsorption stresses to chiral surfaces: (R,R)-tartaric acid on Ni(110). (Journal article)
Humblot, V., Haq, S., Muryn, C., Hofer, W. A., & Raval, R. (2002). From local adsorption stresses to chiral surfaces: (R,R)-tartaric acid on Ni(110).. Journal of the American Chemical Society, 124(3), 503-510. doi:10.1021/ja012021eDOI: 10.1021/ja012021e
Chemical Transformations, Molecular Transport, and Kinetic Barriers in Creating the Chiral Phase of (R, R)-Tartaric Acid on Cu(110) (Journal article)
Lorenzo, M. O., Humblot, V., Murray, P., Baddeley, C. J., Haq, S., & Raval, R. (2002). Chemical Transformations, Molecular Transport, and Kinetic Barriers in Creating the Chiral Phase of (R, R)-Tartaric Acid on Cu(110). Journal of Catalysis, 205(1), 123-134. doi:10.1006/jcat.2001.3422DOI: 10.1006/jcat.2001.3422
2001
Scaling parameters for gold and copper cluster growth on an alumina single crystal surface (Journal article)
Winkler, C., Carew, A., Raval, R., Ledieu, J., & McGrath, R. (2001). Scaling parameters for gold and copper cluster growth on an alumina single crystal surface. SURFACE REVIEW AND LETTERS, 8(6), 693-697. doi:10.1016/S0218-625X(01)00163-4DOI: 10.1016/S0218-625X(01)00163-4
Dynamical catalytic responses in the reaction of trans-1,2-dichloroethene on Pd(110) (Journal article)
Bloxham, L. H., Haq, S., Mitchell, C., & Raval, R. (2001). Dynamical catalytic responses in the reaction of trans-1,2-dichloroethene on Pd(110). Surface Science, 489(1-3), 1-19. doi:10.1016/s0039-6028(01)01179-7DOI: 10.1016/s0039-6028(01)01179-7
Bonding, Organization, and Dynamical Growth Behavior of Tripeptides on a Defined Metal Surface: Tri-<scp>l</scp>-alanine and Tri-<scp>l</scp>-leucine on Cu{110} (Journal article)
Barlow, S. M., Haq, S., & Raval, R. (2001). Bonding, Organization, and Dynamical Growth Behavior of Tripeptides on a Defined Metal Surface: Tri-<scp>l</scp>-alanine and Tri-<scp>l</scp>-leucine on Cu{110}. Langmuir, 17(11), 3292-3300. doi:10.1021/la001441zDOI: 10.1021/la001441z
Propan-2-ol on Ni(111): identification of surface intermediates and reaction products (Journal article)
Shorthouse, L. J., Roberts, A. J., & Raval, R. (2001). Propan-2-ol on Ni(111): identification of surface intermediates and reaction products. Surface Science, 480(1-2), 37-46. doi:10.1016/s0039-6028(01)00991-8DOI: 10.1016/s0039-6028(01)00991-8
Quantitative Analysis of Adsorbate Induced Segregation at Bimetallic Surfaces: Improving the Accuracy of Medium Energy Ion Scattering Results (Journal article)
Baddeley, C. J., Bloxham, L. H., Laroze, S. C., Raval, R., Noakes, T. C. Q., & Bailey, P. (2001). Quantitative Analysis of Adsorbate Induced Segregation at Bimetallic Surfaces: Improving the Accuracy of Medium Energy Ion Scattering Results. The Journal of Physical Chemistry B, 105(14), 2766-2772. doi:10.1021/jp003227pDOI: 10.1021/jp003227p
Degradation of Methanol and Methylamines to Carbon over Heated Alloy Surfaces (Journal article)
Birtill, J. J., Ridley, P., Liddle, S., Nunney, T. S., & Raval, R. (2001). Degradation of Methanol and Methylamines to Carbon over Heated Alloy Surfaces. Industrial & Engineering Chemistry Research, 40(2), 553-557. doi:10.1021/ie0005856DOI: 10.1021/ie0005856
2000
Extended surface chirality from supramolecular assemblies of adsorbed chiral molecules (Journal article)
Ortega Lorenzo, M., Baddeley, C. J., Muryn, C., & Raval, R. (2000). Extended surface chirality from supramolecular assemblies of adsorbed chiral molecules. Nature, 404(6776), 376-379. doi:10.1038/35006031DOI: 10.1038/35006031
1999
Creating Chiral Surfaces for Enantioselective Heterogeneous Catalysis: <i>R</i>,<i>R</i>-Tartaric Acid on Cu(110) (Journal article)
Lorenzo, M. O., Haq, S., Bertrams, T., Murray, P., Raval, R., & Baddeley, C. J. (1999). Creating Chiral Surfaces for Enantioselective Heterogeneous Catalysis: <i>R</i>,<i>R</i>-Tartaric Acid on Cu(110). The Journal of Physical Chemistry B, 103(48), 10661-10669. doi:10.1021/jp992188iDOI: 10.1021/jp992188i
Identification of reaction intermediates and products in the dehalogenation of trichloroethene on Cu(110) (Journal article)
Laroze, S. C., Haq, S., Raval, R., Jugnet, Y., & Bertolini, J. C. (1999). Identification of reaction intermediates and products in the dehalogenation of trichloroethene on Cu(110). Surface Science, 433-435, 193-198. doi:10.1016/s0039-6028(99)00049-7DOI: 10.1016/s0039-6028(99)00049-7
Modelling the interaction of hybrid inorganic–organic molecules on oxide surfaces: glycidyl isopropyl ether and epoxyhexane on a γ-Al2O3(111) mimic (Journal article)
Woods, G. A., Haq, S., Richardson, N. V., Shaw, S., Digby, R., & Raval, R. (1999). Modelling the interaction of hybrid inorganic–organic molecules on oxide surfaces: glycidyl isopropyl ether and epoxyhexane on a γ-Al2O3(111) mimic. Surface Science, 433-435, 199-204. doi:10.1016/s0039-6028(99)00467-7DOI: 10.1016/s0039-6028(99)00467-7
Complexities and dynamics of the enantioselective active site in heterogeneous catalysis (Journal article)
Raval, R., Baddeley, C. J., Haq, S., Louafi, S., Murray, P., Muryn, C., . . . Williams, J. (1999). Complexities and dynamics of the enantioselective active site in heterogeneous catalysis. Unknown Journal, 11-22. doi:10.1016/s0167-2991(99)80129-3DOI: 10.1016/s0167-2991(99)80129-3
1996
Hydrocarbons with orthogonal π-systems: molecular adsorption versus structural isomerisation at surfaces (Journal article)
Shorthouse, L. J., Haq, S., & Raval, R. (1996). Hydrocarbons with orthogonal π-systems: molecular adsorption versus structural isomerisation at surfaces. Surface Science, 368(1-3), 296-302. doi:10.1016/s0039-6028(96)01066-7DOI: 10.1016/s0039-6028(96)01066-7
The bonding and orientation of the amino acid l-alanine on Cu{110} determined by RAIRS (Journal article)
Williams, J., Haq, S., & Raval, R. (1996). The bonding and orientation of the amino acid l-alanine on Cu{110} determined by RAIRS. Surface Science, 368(1-3), 303-309. doi:10.1016/s0039-6028(96)01067-9DOI: 10.1016/s0039-6028(96)01067-9
Propyne chemistry on Ni(111) and Cu(110); analogies with ethyne adsorption (Journal article)
Roberts, A. J., Haq, S., & Raval, R. (1996). Propyne chemistry on Ni(111) and Cu(110); analogies with ethyne adsorption. Journal of the Chemical Society - Faraday Transactions, (23), 4823-4827.
Electromodulated Fourier transform infrared reflectance spectroscopy at the gold-aqueous tetramethylthiourea interface (Journal article)
Port, S. N., HOrswell, S. L., Raval, R., & Schiffrin, D. J. (1996). Electromodulated Fourier transform infrared reflectance spectroscopy at the gold-aqueous tetramethylthiourea interface. LANGMUIR, 12(24), 5934-5941. doi:10.1021/la960346gDOI: 10.1021/la960346g
1993
Adsorption of NO on Pd{110} (Journal article)
Raval, R., Harrison, M. A., Haq, S., & King, D. A. (1993). Adsorption of NO on Pd{110}. Surface Science, 294(1-2), 10-20. doi:10.1016/0039-6028(93)90154-cDOI: 10.1016/0039-6028(93)90154-c
1990
Molecular adsorbate-induced surface reconstruction: CO/Pd{110} (Journal article)
Raval, R., Haq, S., Harrison, M. A., Blyholder, G., & King, D. A. (1990). Molecular adsorbate-induced surface reconstruction: CO/Pd{110}. Chemical Physics Letters, 167(5), 391-398. doi:10.1016/0009-2614(90)85019-9DOI: 10.1016/0009-2614(90)85019-9
CO induced reconstruction of Pd110 characterised by RAIRS (Journal article)
Raval, R., Haq, S., Blyholder, G., & King, D. A. (1990). CO induced reconstruction of Pd110 characterised by RAIRS. Journal of Electron Spectroscopy and Related Phenomena, 54-55, 629-638. doi:10.1016/0368-2048(90)80255-9DOI: 10.1016/0368-2048(90)80255-9
1989
CO site transfer induced by NO co-adsorption on Pd(110): high-resolution infrared spectroscopy (Journal article)
Raval, R., Blyholder, G., Haq, S., & King, D. A. (1989). CO site transfer induced by NO co-adsorption on Pd(110): high-resolution infrared spectroscopy. Journal of Physics: Condensed Matter, 1(SB), SB165-SB169. doi:10.1088/0953-8984/1/sb/028DOI: 10.1088/0953-8984/1/sb/028
