2024
Nuclear Magnetic Resonance Chemical Shift as a Probe for Single-Molecule Charge Transport. (Journal article)
Qiao, X., Sil, A., Sangtarash, S., Smith, S. M., Wu, C., Robertson, C. M., . . . Vezzoli, A. (2024). Nuclear Magnetic Resonance Chemical Shift as a Probe for Single-Molecule Charge Transport.. Angewandte Chemie (International ed. in English), e202402413. doi:10.1002/anie.202402413DOI: 10.1002/anie.202402413
Gibson, Q. D., Wen, D., Lin, H., Zanella, M., Daniels, L. M., Robertson, C. M., . . . Rosseinsky, M. J. (2024). Control of Polarity in Kagome-NiAs Bismuthides.. Angewandte Chemie (International ed. in English), e202403670. doi:10.1002/anie.202403670DOI: 10.1002/anie.202403670
Gibson, Q. D., Wen, D., Lin, H., Zanella, M., Daniels, L. M., Robertson, C. M., . . . Rosseinsky, M. J. (n.d.). Control of Polarity in Kagome‐NiAs Bismuthides. Angewandte Chemie. doi:10.1002/ange.202403670DOI: 10.1002/ange.202403670
Han, G., Vasylenko, A., Daniels, L. M., Collins, C. M., Corti, L., Chen, R., . . . Rosseinsky, M. J. (2024). Superionic lithium transport via multiple coordination environments defined by two-anion packing. Science, 383(6684), 739-745. doi:10.1126/science.adh5115DOI: 10.1126/science.adh5115
Sil, A., Alsaqer, M., Spano, C. E., Larbi, A., Higgins, S. J., Robertson, C. M., . . . Vezzoli, A. (2024). Mechanical Manipulation of Quantum Interference in Single-Molecule Junctions.. Small (Weinheim an der Bergstrasse, Germany), e2308865. doi:10.1002/smll.202308865DOI: 10.1002/smll.202308865
2023
Smith, M. J. S., Tu, W., Robertson, C. M., & Bower, J. F. (2023). Stereospecific Aminative Cyclizations Triggered by Intermolecular Aza-Prilezhaev Alkene Aziridination.. Angewandte Chemie (International ed. in English), 62(48), e202312797. doi:10.1002/anie.202312797DOI: 10.1002/anie.202312797
Stereospecific Aminative Cyclizations Triggered by Intermolecular Aza‐Prilezhaev Alkene Aziridination (Journal article)
Smith, M. J. S., Tu, W., Robertson, C. M., & Bower, J. F. (2023). Stereospecific Aminative Cyclizations Triggered by Intermolecular Aza‐Prilezhaev Alkene Aziridination. Angewandte Chemie, 135(48). doi:10.1002/ange.202312797DOI: 10.1002/ange.202312797
2022
Investigation of C-FmiddotmiddotmiddotF-C Interactions Using Experimental and Theoretical Charge Density Analyses (Journal article)
Singla, L., Kumar, A., Robertson, C. M., Munshi, P., & Choudhury, A. R. (2022). Investigation of C-FmiddotmiddotmiddotF-C Interactions Using Experimental and Theoretical Charge Density Analyses. CRYSTAL GROWTH & DESIGN. doi:10.1021/acs.cgd.2c01097DOI: 10.1021/acs.cgd.2c01097
Vidal, L., Chen, P. -P., Nicolas, E., Hackett, A., Robertson, C. M., Houk, K. N., & Aissa, C. (2022). Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides. ORGANIC LETTERS, 24(46), 8503-8508. doi:10.1021/acs.orglett.2c03396DOI: 10.1021/acs.orglett.2c03396
Gibson, Q. D., Robertson, C. M., Dyer, M. S., Zanella, M., Surta, T. W., Daniels, L. M., . . . Rosseinsky, M. J. (n.d.). Single crystal growth and properties of the polar ferromagnet Mn1.05Bi with Kagome layers, huge magnetic anisotropy and slow spin dynamics. Physical Review Materials, 6(11). doi:10.1103/physrevmaterials.6.114405DOI: 10.1103/physrevmaterials.6.114405
Livesley, S., Trueman, B., Robertson, C. M., Goundry, W. R. F., Morris, J. A., & Aissa, C. (2022). Synthesis of Sulfur-Substituted Bicyclo[1.1.1]pentanes by Iodo-Sulfenylation of [1.1.1]Propellane. ORGANIC LETTERS, 24(38), 7015-7020. doi:10.1021/acs.orglett.2c02875DOI: 10.1021/acs.orglett.2c02875
Gibson, Q. D., Newnham, J. A., Dyer, M. S., Robertson, C. M., Zanella, M., Surta, T. W., . . . Rosseinsky, M. J. (2022). Expanding multiple anion superlattice chemistry: Synthesis, structure and properties of Bi<sub>4</sub>O<sub>4</sub>SeBr<sub>2</sub> and Bi<sub>6</sub>O<sub>6</sub>Se<sub>2</sub>Cl<sub>2</sub>. JOURNAL OF SOLID STATE CHEMISTRY, 312. doi:10.1016/j.jssc.2022.123246DOI: 10.1016/j.jssc.2022.123246
Zhou, J., Jia, M., Song, M., Huang, Z., Steiner, A., An, Q., . . . Li, C. (2022). Chemoselective Oxyfunctionalization of Functionalized Benzylic Compounds with a Manganese Catalyst. Angewandte Chemie, 134(30). doi:10.1002/ange.202205983DOI: 10.1002/ange.202205983
Zhou, J., Jia, M., Song, M., Huang, Z., Steiner, A., An, Q., . . . Li, C. (2022). Chemoselective Oxyfunctionalization of Functionalized Benzylic Compounds with a Manganese Catalyst. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 61(30). doi:10.1002/anie.202205983DOI: 10.1002/anie.202205983
Livesley, S., Sterling, A. J., Robertson, C. M., Goundry, W. R. F., Morris, J. A., Duarte, F., & Aissa, C. (2022). Electrophilic Activation of [1.1.1]Propellane for the Synthesis of Nitrogen-Substituted Bicyclo[1.1.1]pentanes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 61(2). doi:10.1002/ange.202111291DOI: 10.1002/ange.202111291
Livesley, S., Sterling, A. J., Robertson, C. M., Goundry, W. R. F., Morris, J. A., Duarte, F., & Aïssa, C. (2022). Electrophilic Activation of [1.1.1]Propellane for the Synthesis of Nitrogen‐Substituted Bicyclo[1.1.1]pentanes. Angewandte Chemie, 134(2). doi:10.1002/ange.202111291DOI: 10.1002/ange.202111291
2021
Han, G., Vasylenko, A., Neale, A. R., Duff, B. B., Chen, R., Dyer, M. S., . . . Rosseinsky, M. J. (2021). Extended Condensed Ultraphosphate Frameworks with Monovalent Ions Combine Lithium Mobility with High Computed Electrochemical Stability. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(43), 18216-18232. doi:10.1021/jacs.1c07874DOI: 10.1021/jacs.1c07874
Low temperature insights into the crystal and magnetic structure of a neutral radical ferromagnet (Journal article)
Robertson, C. M., Winter, S. M., Howard, J. A. K., Probert, M. R., & Oakley, R. T. (2021). Low temperature insights into the crystal and magnetic structure of a neutral radical ferromagnet. CHEMICAL COMMUNICATIONS, 57(79), 10238-10241. doi:10.1039/d1cc03842gDOI: 10.1039/d1cc03842g
Stachulski, A. V., Rossignol, J. -F., Pate, S., Taujanskas, J., Robertson, C. M., Aerts, R., . . . O'Neill, P. M. (2021). Synthesis, antiviral activity, preliminary pharmacokinetics and structural parameters of thiazolide amine salts. FUTURE MEDICINAL CHEMISTRY, 13(20). doi:10.4155/fmc-2021-0055DOI: 10.4155/fmc-2021-0055
Huang, Z., Guan, R., Shanmugam, M., Bennett, E. L., Robertson, C. M., Brookfield, A., . . . Xiao, J. (2021). Oxidative Cleavage of Alkenes by O<sub>2</sub> with a Non-Heme Manganese Catalyst. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143(26), 10005-10013. doi:10.1021/jacs.1c05757DOI: 10.1021/jacs.1c05757
Fortune, K. M., Castel, C., Robertson, C. M., Horton, P. N., Light, M. E., Coles, S. J., . . . Butler, I. R. (2021). Ferrocenylmethylphosphanes and the Alpha Process for Methoxycarbonylation: The Original Story. INORGANICS, 9(7). doi:10.3390/inorganics9070057DOI: 10.3390/inorganics9070057
Morscher, A., Dyer, M. S., Duff, B. B., Han, G., Gamon, J., Daniels, L. M., . . . Rosseinsky, M. J. (2021). Li<sub>6</sub>SiO<sub>4</sub>Cl<sub>2</sub>: A Hexagonal Argyrodite Based on Antiperovskite Layer Stacking. CHEMISTRY OF MATERIALS, 33(6), 2206-2217. doi:10.1021/acs.chemmater.1c00157DOI: 10.1021/acs.chemmater.1c00157
Butler, I. R., Beaumont, M., Bruce, M. I., Zaitseva, N. N., Iggo, J. A., Robertson, C., . . . Coles, S. J. (n.d.). Synthesis and Structures of 1,1′,2-Tribromoferrocene, 1,1′,2,2′-Tetrabromoferrocene, 1,1′,2,2′-Tetrabromoruthenocene: Expanding the Range of Precursors for the Metallocene Chemist. Australian Journal of Chemistry. doi:10.1071/ch19184DOI: 10.1071/ch19184
2020
Pugh, C. J., Robertson, C. M., & Steiner, A. (n.d.). The Helical Structure of Diallylamine in the Solid State. Journal of Chemical Crystallography. doi:10.1007/s10870-019-00816-2DOI: 10.1007/s10870-019-00816-2
Wu, C., Bates, D., Sangtarash, S., Ferri, N., Thomas, A., Higgins, S. J., . . . Vezzoli, A. (2020). Folding a Single-Molecule Junction. NANO LETTERS, 20(11), 7980-7986. doi:10.1021/acs.nanolett.0c02815DOI: 10.1021/acs.nanolett.0c02815
Wu, C., Qiao, X., Robertson, C. M., Higgins, S. J., Cai, C., Nichols, R. J., & Vezzoli, A. (2020). A Chemically Soldered Polyoxometalate Single-Molecule Transistor. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 59(29), 12029-12034. doi:10.1002/anie.202002174DOI: 10.1002/anie.202002174
GeSe: Optical Spectroscopy and Theoretical Study of a van der Waals Solar Absorber (Journal article)
Murgatroyd, P. A. E., Smiles, M. J., Savory, C. N., Shalvey, T. P., Swallow, J. E. N., Fleck, N., . . . Veal, T. D. (2020). GeSe: Optical Spectroscopy and Theoretical Study of a van der Waals Solar Absorber. CHEMISTRY OF MATERIALS, 32(7), 3245-3253. doi:10.1021/acs.chemmater.0c00453DOI: 10.1021/acs.chemmater.0c00453
Wu, C., Alqahtani, A., Sangtarash, S., Vezzoli, A., Sadeghi, H., Robertson, C. M., . . . Nichols, R. J. (2020). In situ formation of H-bonding imidazole chains in break-junction experiments. Nanoscale, 2020(14), 7914-7920. doi:10.1039/d0nr00630kDOI: 10.1039/d0nr00630k
A Chemically Soldered Polyoxometalate Single-Molecule Transistor (Other)
Wu, C., Qiao, X., Robertson, C., Higgins, S., Cai, C., Nichols, R., & Vezzoli, A. (2020). A Chemically Soldered Polyoxometalate Single-Molecule Transistor. doi:10.26434/chemrxiv.11763426.v2DOI: 10.26434/chemrxiv.11763426.v2
A Chemically Soldered Polyoxometalate Single-Molecule Transistor (Other)
Wu, C., Qiao, X., Robertson, C., Higgins, S., Cai, C., Nichols, R., & Vezzoli, A. (2020). A Chemically Soldered Polyoxometalate Single-Molecule Transistor. doi:10.26434/chemrxiv.11763426.v1DOI: 10.26434/chemrxiv.11763426.v1
Gibson, Q. D., Manning, T. D., Zanella, M., Zhao, T., Murgatroyd, P. J., Robertson, C. M., . . . Rosseinsky, M. J. (2020). Modular design via multiple anion chemistry of the high mobility van der Waals semiconductor Bi4O4SeCl2. Journal of the American Chemical Society, 142(02), 847-856. doi:10.1021/jacs.9b09411DOI: 10.1021/jacs.9b09411
2019
In-Situ Formation of H-Bonding Imidazole Chains in Break-Junction Experiments (Other)
Wu, C., Alqahtani, A., Sangtarash, S., Vezzoli, A., Sadeghi, H., Robertson, C., . . . Nichols, R. (2019). In-Situ Formation of H-Bonding Imidazole Chains in Break-Junction Experiments. doi:10.26434/chemrxiv.9976913.v1DOI: 10.26434/chemrxiv.9976913.v1
The Importance of Electronic Dimensionality in Multiorbital Radical Conductors (Journal article)
Mailman, A., Robertson, C. M., Winter, S. M., Dube, P. A., & Oakley, R. T. (2019). The Importance of Electronic Dimensionality in Multiorbital Radical Conductors. INORGANIC CHEMISTRY, 58(9), 6495-6506. doi:10.1021/acs.inorgchem.9b00691DOI: 10.1021/acs.inorgchem.9b00691
Gonzalez-de-Castro, A., Robertson, C. M., & Xiao, J. (2019). Boosting Molecular Complexity with O<sub>2</sub>: Iron-Catalysed Oxygenation of 1-Arylisochromans through Dehydrogenation, Csp<SUP>3</SUP>-O Bond Cleavage and Hydrogenolysis. CHEMISTRY-A EUROPEAN JOURNAL, 25(17), 4345-4357. doi:10.1002/chem.201806117DOI: 10.1002/chem.201806117
Frontispiece: Boosting Molecular Complexity with O<sub>2</sub>: Iron‐Catalysed Oxygenation of 1‐Arylisochromans through Dehydrogenation, Csp<sup>3</sup>−O Bond Cleavage and Hydrogenolysis (Journal article)
Gonzalez‐de‐Castro, A., Robertson, C. M., & Xiao, J. (2019). Frontispiece: Boosting Molecular Complexity with O<sub>2</sub>: Iron‐Catalysed Oxygenation of 1‐Arylisochromans through Dehydrogenation, Csp<sup>3</sup>−O Bond Cleavage and Hydrogenolysis. Chemistry – A European Journal, 25(17). doi:10.1002/chem.201981765DOI: 10.1002/chem.201981765
Richards, P. I., Lawson, G. T., Bickley, J. F., Robertson, C. M., Iggo, J. A., & Steiner, A. (2019). Polyanionic Ligand Platforms for Methyl- and Dimethylaluminum Arrays. INORGANIC CHEMISTRY, 58(5), 3355-3363. doi:10.1021/acs.inorgchem.8b03448DOI: 10.1021/acs.inorgchem.8b03448
Three-Dimensional Magnetic Exchange Networks in Trigonal Bisdithiazolyl Radicals (Journal article)
Yutronkie, N. J., Bates, D., Dube, P. A., Winter, S. M., Robertson, C. M., Brusso, J. L., & Oakley, R. T. (2019). Three-Dimensional Magnetic Exchange Networks in Trigonal Bisdithiazolyl Radicals. INORGANIC CHEMISTRY, 58(1), 419-427. doi:10.1021/acs.inorgchem.8b02608DOI: 10.1021/acs.inorgchem.8b02608
Elwrfalli, F., Esvan, Y. J., Robertson, C. M., & Aissa, C. (2019). Regioselective cycloaddition of potassium alkynyltrifluoroborates with 3-azetidinones and 3-oxetanone by nickel-catalysed C-C bond activation. CHEMICAL COMMUNICATIONS, 55(4), 497-500. doi:10.1039/c8cc09241aDOI: 10.1039/c8cc09241a
Trigonal bisdithiazolyl radicals as building blocks towards three-dimensional magnetic exchange networks (Conference Paper)
Yutronkie, N., Bates, D., Dube, P., Winter, S., Robertson, C., Oakley, R., & Brusso, J. (2019). Trigonal bisdithiazolyl radicals as building blocks towards three-dimensional magnetic exchange networks. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 258. Retrieved from https://www.webofscience.com/
2018
Non-Innocent Base Properties of 3-and 4-Pyridyl-dithia- and Diselenadiazolyl Radicals: The Effect of <i>N</i>-Methylation (Journal article)
Taponen, A. I., Wong, J. W. L., Lekin, K., Assoud, A., Robertson, C. M., Lahtinen, M., . . . Oakley, R. T. (2018). Non-Innocent Base Properties of 3-and 4-Pyridyl-dithia- and Diselenadiazolyl Radicals: The Effect of <i>N</i>-Methylation. INORGANIC CHEMISTRY, 57(21), 13901-13911. doi:10.1021/acs.inorgchem.8b02416DOI: 10.1021/acs.inorgchem.8b02416
Delacotte, C., Whitehead, G. F. S., Pitcher, M. J., Robertson, C. M., Sharp, P. M., Dyer, M. S., . . . Rosseinsky, M. J. (2018). Structure determination and crystal chemistry of large repeat mixed-layer hexaferrites. IUCRJ, 5, 681-698. doi:10.1107/S2052252518011351DOI: 10.1107/S2052252518011351
Aboo, A. H., Bennett, E. L., Deeprose, M., Robertson, C. M., Iggo, J. A., & Xiao, J. (2018). Methanol as hydrogen source: transfer hydrogenation of aromatic aldehydes with a rhodacycle. Chemical Communications, (83), 11805-11808. doi:10.1039/c8cc06612dDOI: 10.1039/c8cc06612d
Gibson, Q. D., Dyer, M. S., Robertson, C., Delacotte, C., Manning, T. D., Pitcher, M. J., . . . Rosseinsky, M. J. (2018). Bi<sub>2+2<i>n</i></sub>O<sub>2+2<i>n</i></sub>Cu<sub>2-δ</sub>Se<sub>2+<i>n</i>-δ</sub>X<sub>δ</sub> (X = CI, Br): A Three-Anion Homologous Series. INORGANIC CHEMISTRY, 57(20), 12489-12500. doi:10.1021/acs.inorgchem.8b01126DOI: 10.1021/acs.inorgchem.8b01126
N,O- vs N,C-Chelation in Half-Sandwich Iridium Complexes: A Dramatic Effect on Enantioselectivity in Asymmetric Transfer Hydrogenation of Ketones (Journal article)
Zhou, G., Aboo, A. H., Robertson, C. M., Liu, R., Li, Z., Luzyanin, K., . . . Xiao, J. (2018). N,O- vs N,C-Chelation in Half-Sandwich Iridium Complexes: A Dramatic Effect on Enantioselectivity in Asymmetric Transfer Hydrogenation of Ketones. ACS CATALYSIS, 8(9), 8020-8026. doi:10.1021/acscatal.8b02068DOI: 10.1021/acscatal.8b02068
Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts (Journal article)
Gee, J. C., Fuller, B. A., Lockett, H. -M., Sedghi, G., Robertson, C. M., & Luzyanin, K. V. (2018). Visible light accelerated hydrosilylation of alkynes using platinum-[acyclic diaminocarbene] photocatalysts. CHEMICAL COMMUNICATIONS, 54(68), 9450-9453. doi:10.1039/c8cc04287jDOI: 10.1039/c8cc04287j
Hanke, F., Pugh, C. J., Kay, E., Taylor, J. B., Todd, M. T., Robertson, C. M., . . . Steiner, A. (2018). The simplest supramolecular helix. Chemical Communications, 54(47), 6012-6015. doi:10.1039/C8CC03295EDOI: 10.1039/C8CC03295E
Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N-N σ-Bonded Dimer (Journal article)
Bates, D., Robertson, C. M., Leitch, A. A., Dube, P. A., & Oakley, R. T. (2018). Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N-N σ-Bonded Dimer. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 140(11), 3846-3849. doi:10.1021/jacs.7b13699DOI: 10.1021/jacs.7b13699
2017
Mailman, A., Wong, J. W. L., Winter, S. M., Claridge, R. C. M., Robertson, C. M., Assoud, A., . . . Oakley, R. T. (2017). Fine Tuning the Performance of Multiorbital Radical Conductors by Substituent Effects. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 139(4), 1625-1635. doi:10.1021/jacs.6b11779DOI: 10.1021/jacs.6b11779
2016
Neri, G., Forster, M., Walsh, J. J., Robertson, C. M., Whittles, T. J., Farras, P., & Cowan, A. J. (2016). Photochemical CO<sub>2</sub> reduction in water using a co-immobilised nickel catalyst and a visible light sensitiser. CHEMICAL COMMUNICATIONS, 52(99), 14200-14203. doi:10.1039/c6cc08590cDOI: 10.1039/c6cc08590c
Spin Frustration in an Organic Radical Ion Salt Based on a Kagome-Coupled Chain Structure (Journal article)
Postulka, L., Winter, S. M., Mihailov, A. G., Mailman, A., Assoud, A., Robertson, C. M., . . . Oakley, R. T. (2016). Spin Frustration in an Organic Radical Ion Salt Based on a Kagome-Coupled Chain Structure. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(34), 10738-10741. doi:10.1021/jacs.6b05079DOI: 10.1021/jacs.6b05079
Alkylaminophosphazenes as Efficient and Tuneable Phase-Transfer Agents for Polyoxometalate-Catalysed Biphasic Oxidation with Hydrogen Peroxide (Journal article)
Craven, M., Yahya, R., Kozhevnikova, E. F., Robertson, C. M., Steiner, A., & Kozhevnikov, I. V. (2016). Alkylaminophosphazenes as Efficient and Tuneable Phase-Transfer Agents for Polyoxometalate-Catalysed Biphasic Oxidation with Hydrogen Peroxide. CHEMCATCHEM, 8(1), 200-208. doi:10.1002/cctc.201500922DOI: 10.1002/cctc.201500922
Cu(I)Cu(II)BTC, a microporous mixed-valence MOF <i>via</i> reduction of HKUST-1 (Journal article)
Ahmed, A., Robertson, C. M., Steiner, A., Whittles, T., Ho, A., Dhanak, V., & Zhang, H. (2016). Cu(I)Cu(II)BTC, a microporous mixed-valence MOF <i>via</i> reduction of HKUST-1. RSC ADVANCES, 6(11), 8902-8905. doi:10.1039/c5ra23754hDOI: 10.1039/c5ra23754h
2015
A New Phenoxide Chelated Ir<SUP>III</SUP> N-Heterocyclic Carbene Complex and Its Application in Reductive Amination Reactions (Journal article)
Gulcemal, D., Gulcemal, S., Robertson, C. M., & Xiao, J. (2015). A New Phenoxide Chelated Ir<SUP>III</SUP> N-Heterocyclic Carbene Complex and Its Application in Reductive Amination Reactions. ORGANOMETALLICS, 34(17), 4394-4400. doi:10.1021/acs.organomet.5b00625DOI: 10.1021/acs.organomet.5b00625
Multiple Orbital Effects and Magnetic Ordering in a Neutral Radical (Journal article)
Mailman, A., Winter, S. M., Wong, J. W. L., Robertson, C. M., Assoud, A., Dube, P. A., & Oakley, R. T. (2015). Multiple Orbital Effects and Magnetic Ordering in a Neutral Radical. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(3), 1044-1047. doi:10.1021/ja512235hDOI: 10.1021/ja512235h
ChemInform Abstract: Dehydrogenative α‐Oxygenation of Ethers with an Iron Catalyst. (Journal article)
Gonzalez‐de‐Castro, A., Robertson, C. M., & Xiao, J. (2015). ChemInform Abstract: Dehydrogenative α‐Oxygenation of Ethers with an Iron Catalyst.. ChemInform, 46(2). doi:10.1002/chin.201502085DOI: 10.1002/chin.201502085
Walsh, J. J., Smith, C. L., Neri, G., Whitehead, G. F. S., Robertson, C. M., & Cowan, A. J. (2015). Improving the efficiency of electrochemical CO<sub>2</sub> reduction using immobilized manganese complexes. FARADAY DISCUSSIONS, 183, 147-160. doi:10.1039/c5fd00071hDOI: 10.1039/c5fd00071h
Magnetic ordering and conductivity in heavy atom and multiband radicals (Conference Paper)
Mailman, A., Winter, S., Wong, J., Tian, D., Robertson, C., Dube, P., . . . Oakley, R. (2015). Magnetic ordering and conductivity in heavy atom and multiband radicals. In ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Vol. 249. Retrieved from https://www.webofscience.com/
2014
ChemInform Abstract: The Synthesis and Structure of Chiral Enamine N‐Oxides. (Journal article)
O'Neil, I. A., McConville, M., Zhou, K., Brooke, C., Robertson, C. M., & Berry, N. G. (2014). ChemInform Abstract: The Synthesis and Structure of Chiral Enamine N‐Oxides.. ChemInform, 45(48). doi:10.1002/chin.201448115DOI: 10.1002/chin.201448115
The synthesis and structure of chiral enamine N-oxides (Journal article)
O'Neil, I. A., McConville, M., Zhou, K., Brooke, C., Robertson, C. M., & Berry, N. G. (2014). The synthesis and structure of chiral enamine N-oxides. Chemical Communications, 50(55), 7336-7339. doi:10.1039/c3cc47928eDOI: 10.1039/c3cc47928e
Macroporous metal-organic framework microparticles with improved liquid phase separation (Journal article)
Ahmed, A., Hodgson, N., Barrow, M., Clowes, R., Robertson, C. M., Steiner, A., . . . Zhang, H. (2014). Macroporous metal-organic framework microparticles with improved liquid phase separation. Journal of Materials Chemistry A, 2(24), 9085-9090. doi:10.1039/c4ta00138aDOI: 10.1039/c4ta00138a
Dehydrogenative alpha-Oxygenation of Ethers with an Iron Catalyst (Journal article)
Gonzalez-de-Castro, A., Robertson, C. M., & Xiao, J. (2014). Dehydrogenative alpha-Oxygenation of Ethers with an Iron Catalyst. Journal of the American Chemical Society, 136(23), 8350-8360. doi:10.1021/ja502167hDOI: 10.1021/ja502167h
ChemInform Abstract: Primary Amines by Transfer Hydrogenative Reductive Amination of Ketones by Using Cyclometalated Ir<sup>III</sup> Catalysts. (Journal article)
Talwar, D., Salguero, N. P., Robertson, C. M., & Xiao, J. (2014). ChemInform Abstract: Primary Amines by Transfer Hydrogenative Reductive Amination of Ketones by Using Cyclometalated Ir<sup>III</sup> Catalysts.. ChemInform, 45(23). doi:10.1002/chin.201423081DOI: 10.1002/chin.201423081
Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor (Journal article)
Wong, J. W. L., Mailman, A., Winter, S. M., Robertson, C. M., Holmberg, R. J., Murugesu, M., . . . Oakley, R. T. (2014). Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor. CHEMICAL COMMUNICATIONS, 50(7), 785-787. doi:10.1039/c3cc46686hDOI: 10.1039/c3cc46686h
Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical (Journal article)
Edkins, R. M., Probert, M. R., Robertson, C. M., Howard, J. A. K., & Beeby, A. (2014). Photocrystallisation of the 2C-2′C dimer of a triphenylimidazolyl radical. RSC ADVANCES, 4(11), 5351-5356. doi:10.1039/c3ra43892aDOI: 10.1039/c3ra43892a
Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control (Journal article)
Katsoulidis, A. P., Park, K. S., Antypov, D., Marti-Gastaldo, C., Miller, G. P., Warren, J. E., . . . Rosseinsky, M. J. (2014). Guest Adaptable and Water Stable Peptide Based Porous Materials by Imidazolate Sidechain Control. Angew. Chem. Int. Ed., 53, 193-198.
Katsoulidis, A., Park, K. S., Antypov, D., Martí-Gastaldo, C., Miller, G., Warren, J., . . . Rosseinsky, M. (2014). Guest-Adaptable and Water-Stable Peptide-Based Porous Materials by Imidazolate Side Chain Control. Angewandte Chemie International Edition, 53(1), 193-198. doi:10.1002/anie.201307074DOI: 10.1002/anie.201307074
Guest‐Adaptable and Water‐Stable Peptide‐Based Porous Materials by Imidazolate Side Chain Control (Journal article)
Katsoulidis, A. P., Park, K. S., Antypov, D., Martí‐Gastaldo, C., Miller, G. J., Warren, J. E., . . . Rosseinsky, M. J. (2014). Guest‐Adaptable and Water‐Stable Peptide‐Based Porous Materials by Imidazolate Side Chain Control. Angewandte Chemie, 126(1), 197-202. doi:10.1002/ange.201307074DOI: 10.1002/ange.201307074
Primary Amines by Transfer Hydrogenative Reductive Amination of Ketones by Using Cyclometalated Ir<SUP>III</SUP> Catalysts (Journal article)
Talwar, D., Salguero, N. P., Robertson, C. M., & Xiao, J. (2014). Primary Amines by Transfer Hydrogenative Reductive Amination of Ketones by Using Cyclometalated Ir<SUP>III</SUP> Catalysts. CHEMISTRY-A EUROPEAN JOURNAL, 20(1), 245-252. doi:10.1002/chem.201303541DOI: 10.1002/chem.201303541
The synthesis and structure of chiral enamine N-oxides (Journal article)
O'Neil, I. A., McConville, M., Zhou, K., Brooke, C., Robertson, C. M., & Berry, N. G. (2014). The synthesis and structure of chiral enamine N-oxides. Chemical Communications, 50(55), 7336-7339.
2013
ChemInform Abstract: Robust Cyclometallated Ir(III) Catalysts for the Homogeneous Hydrogenation of N‐Heterocycles under Mild Conditions. (Journal article)
Wu, J., Barnard, J. H., Zhang, Y., Talwar, D., Robertson, C. M., & Xiao, J. (2013). ChemInform Abstract: Robust Cyclometallated Ir(III) Catalysts for the Homogeneous Hydrogenation of N‐Heterocycles under Mild Conditions.. ChemInform, 44(48). doi:10.1002/chin.201348169DOI: 10.1002/chin.201348169
Robust cyclometallated Ir(III) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions (Journal article)
Wu, J., Barnard, J. H., Zhang, Y., Talwar, D., Robertson, C. M., & Xiao, J. (2013). Robust cyclometallated Ir(III) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions. CHEMICAL COMMUNICATIONS, 49(63), 7052-7054. doi:10.1039/c3cc44567dDOI: 10.1039/c3cc44567d
The formation of peroxide degradation products of photochromic triphenylimidazolyl radical-dimers (Journal article)
Edkins, R. M., Probert, M. R., Fucke, K., Robertson, C. M., Howard, J. A. K., & Beeby, A. (2013). The formation of peroxide degradation products of photochromic triphenylimidazolyl radical-dimers. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15(20), 7848-7853. doi:10.1039/c3cp50757bDOI: 10.1039/c3cp50757b
Novel polyoxometalate-phosphazene aggregates and their use as catalysts for biphasic oxidations with hydrogen peroxide (Journal article)
Craven, M., Yahya, R., Kozhevnikova, E., Boomishankar, R., Robertson, C. M., Steiner, A., & Kozhevnikov, I. (2013). Novel polyoxometalate-phosphazene aggregates and their use as catalysts for biphasic oxidations with hydrogen peroxide. CHEMICAL COMMUNICATIONS, 49(4), 349-351. doi:10.1039/c2cc36793aDOI: 10.1039/c2cc36793a
2012
Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor (Journal article)
Mailman, A., Winter, S. M., Yu, X., Robertson, C. M., Yong, W., Tse, J. S., . . . Oakley, R. T. (2012). Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(24), 9886-9889. doi:10.1021/ja303169yDOI: 10.1021/ja303169y
Metal Complexes of Bridging Neutral Radical Ligands: pymDTDA and pymDSDA (Journal article)
Wu, J., MacDonald, D. J., Clerac, R., Jeon, I. -R., Jennings, M., Lough, A. J., . . . Preuss, K. E. (2012). Metal Complexes of Bridging Neutral Radical Ligands: pymDTDA and pymDSDA. INORGANIC CHEMISTRY, 51(6), 3827-3839. doi:10.1021/ic3000284DOI: 10.1021/ic3000284
Semiquinone-Bridged Bisdithiazolyl Radicals as Neutral Radical Conductors (Journal article)
Yu, X., Mailman, A., Lekin, K., Assoud, A., Robertson, C. M., Noll, B. C., . . . Oakley, R. T. (2012). Semiquinone-Bridged Bisdithiazolyl Radicals as Neutral Radical Conductors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(4), 2264-2275. doi:10.1021/ja209841zDOI: 10.1021/ja209841z
2011
The XIPHOS diffraction facility for extreme sample environments (Conference Paper)
Goeta, A. E., Probert, M. R., Coome, J. A., Robertson, C. M., & Howard, J. A. K. (2011). The XIPHOS diffraction facility for extreme sample environments. In ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES Vol. 67 (pp. C528-C529). doi:10.1107/S0108767311086612DOI: 10.1107/S0108767311086612
2010
The XIPHOS diffraction facility for extreme sample conditions (Journal article)
Probert, M. R., Robertson, C. M., Coome, J. A., Howard, J. A. K., Michell, B. C., & Goeta, A. E. (2010). The XIPHOS diffraction facility for extreme sample conditions. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 43, 1415-1418. doi:10.1107/S0021889810041282DOI: 10.1107/S0021889810041282
Using the nitro group to induce π-stacking in terthiophenes (Journal article)
Sears, W. A., MacKinnon, C. D., Mawhinney, R. C., Sinnemaki, L. C., Johnson, M. J., Winter, A. J., & Robertson, C. M. (2010). Using the nitro group to induce π-stacking in terthiophenes. CANADIAN JOURNAL OF CHEMISTRY, 88(4), 309-317. doi:10.1139/V09-165DOI: 10.1139/V09-165
2009
Metamagnetism in a π-stacked bis-dithiazolyl radical (Journal article)
Winter, S. M., Cvrkalj, K., Dube, P. A., Robertson, C. M., Probert, M. R., Howard, J. A. K., & Oakley, R. T. (2009). Metamagnetism in a π-stacked bis-dithiazolyl radical. CHEMICAL COMMUNICATIONS, (47), 7306-7308. doi:10.1039/b917213kDOI: 10.1039/b917213k
Heavy Atom Ferromagnets under Pressure: Structural Changes and the Magnetic Response (Journal article)
Mito, M., Komorida, Y., Tsuruda, H., Tse, J. S., Desgreniers, S., Ohishi, Y., . . . Oakley, R. T. (2009). Heavy Atom Ferromagnets under Pressure: Structural Changes and the Magnetic Response. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(44), 16012-+. doi:10.1021/ja908238wDOI: 10.1021/ja908238w
Isostructural Bis-1,2,3-Thiaselenazolyl Dimers (Journal article)
Leitch, A. A., Yu, X., Robertson, C. M., Secco, R. A., Tse, J. S., & Oakley, R. T. (2009). Isostructural Bis-1,2,3-Thiaselenazolyl Dimers. INORGANIC CHEMISTRY, 48(20), 9874-9882. doi:10.1021/ic901563nDOI: 10.1021/ic901563n
Cationic Thorium Alkyl Complexes of Rigid NON- and NNN-Donor Ligands: π-Arene Coordination as a Persistent Structural Motif (Journal article)
Cruz, C. A., Emslie, D. J. H., Robertson, C. M., Harrington, L. E., Jenkins, H. A., & Britten, J. F. (2009). Cationic Thorium Alkyl Complexes of Rigid NON- and NNN-Donor Ligands: π-Arene Coordination as a Persistent Structural Motif. ORGANOMETALLICS, 28(6), 1891-1899. doi:10.1021/om800624tDOI: 10.1021/om800624t
5,5′-Dicyano-2,2′-bithiophene and 3,3′-dicyanobiphenyl: off-axis rod-like ligands for silver(I) (Journal article)
MacKinnon, C. D., Parent, S. L. M., Mawhinney, R. C., Assoud, A., & Robertson, C. M. (2009). 5,5′-Dicyano-2,2′-bithiophene and 3,3′-dicyanobiphenyl: off-axis rod-like ligands for silver(I). CRYSTENGCOMM, 11(1), 160-167. doi:10.1039/b810479dDOI: 10.1039/b810479d
2008
Ferromagnetic Ordering in Bisthiaselenazolyl Radicals: Variations on a Tetragonal Theme (Journal article)
Robertson, C. M., Leitch, A. A., Cvrkalj, K., Myles, D. J. T., Reed, R. W., Dube, P. A., & Oakley, R. T. (2008). Ferromagnetic Ordering in Bisthiaselenazolyl Radicals: Variations on a Tetragonal Theme. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(44), 14791-14801. doi:10.1021/ja8054436DOI: 10.1021/ja8054436
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-ligand: Investigations into η<SUP>3</SUP>(<i>BCC</i>)-Triarylborane Coordination (Journal article)
Emslie, D. J. H., Harrington, L. E., Jenkins, H. A., Robertson, C. M., & Britten, J. F. (2008). Group 10 Transition-Metal Complexes of an Ambiphilic PSB-ligand: Investigations into η<SUP>3</SUP>(<i>BCC</i>)-Triarylborane Coordination. ORGANOMETALLICS, 27(20), 5317-5325. doi:10.1021/om800670eDOI: 10.1021/om800670e
Self-association of the N-methyl benzotellurodiazolylium cation: implications for the generation of super-heavy atom radicals (Journal article)
Risto, M., Reed, R. W., Robertson, C. M., Oilunkaniemi, R., Laitinen, R. S., & Oakley, R. T. (2008). Self-association of the N-methyl benzotellurodiazolylium cation: implications for the generation of super-heavy atom radicals. CHEMICAL COMMUNICATIONS, (28), 3278-3280. doi:10.1039/b803159bDOI: 10.1039/b803159b
Tetrathiophenalenyl radical and its disulfide-bridged dimer (Journal article)
Beer, L., Reed, R. W., Robertson, C. M., Oakley, R. T., Tham, F. S., & Haddon, R. C. (2008). Tetrathiophenalenyl radical and its disulfide-bridged dimer. ORGANIC LETTERS, 10(14), 3121-3123. doi:10.1021/ol801159zDOI: 10.1021/ol801159z
Enhanced conductivity and magnetic ordering in isostructural heavy atom radicals (Journal article)
Robertson, C. M., Leitch, A. A., Cvrkalj, K., Reed, R. W., Myles, D. J. T., Dube, P. A., & Oakley, R. T. (2008). Enhanced conductivity and magnetic ordering in isostructural heavy atom radicals. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(26), 8414-8425. doi:10.1021/ja801070dDOI: 10.1021/ja801070d
Two-dimensional structural motif in thienoacene semiconductors: Synthesis, structure, and properties of tetrathienoanthracene isomers (Journal article)
Brusso, J. L., Hirst, O. D., Dadvand, A., Ganesan, S., Cicoira, F., Robertson, C. M., . . . Perepichkat, D. F. (2008). Two-dimensional structural motif in thienoacene semiconductors: Synthesis, structure, and properties of tetrathienoanthracene isomers. CHEMISTRY OF MATERIALS, 20(7), 2484-2494. doi:10.1021/cm7030653DOI: 10.1021/cm7030653
Polymorphism in a π-stacked 1,3,2-dithiazolyl radical:: Pyridyl-1,3,2-dithiazolyl (Journal article)
Alberola, A., Clements, O. P., Collis, R. J., Cubbitt, L., Grant, C. M., Less, R. J., . . . Robertson, C. M. (2008). Polymorphism in a π-stacked 1,3,2-dithiazolyl radical:: Pyridyl-1,3,2-dithiazolyl. CRYSTAL GROWTH & DESIGN, 8(1), 155-161. doi:10.1021/cg7010056DOI: 10.1021/cg7010056
2007
Ferromagnetism in a heavy atom Heterocyclic radical conductor (Journal article)
Robertson, C. M., Myles, D. J. T., Leitch, A. A., Reed, R. W., Dooley, B. M., Frank, N. L., . . . Oakley, R. T. (2007). Ferromagnetism in a heavy atom Heterocyclic radical conductor. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(42), 12688-+. doi:10.1021/ja076841oDOI: 10.1021/ja076841o
Spin-canting in heavy atom heterocyclic radicals (Journal article)
Leitch, A. A., Brusso, J. L., Cvrkalj, K., Reed, R. W., Robertson, C. M., Dube, P. A., & Oakley, R. T. (2007). Spin-canting in heavy atom heterocyclic radicals. CHEMICAL COMMUNICATIONS, (32), 3368-3370. doi:10.1039/b708756jDOI: 10.1039/b708756j
An alternating π-stacked bisdithiazolyl radical conductor (Journal article)
Leitch, A. A., Reed, R. W., Robertson, C. M., Britten, J. F., Yu, X., Secco, R. A., & Oakley, R. T. (2007). An alternating π-stacked bisdithiazolyl radical conductor. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(25), 7903-7914. doi:10.1021/ja071218pDOI: 10.1021/ja071218p
Extremely stable thorium(IV) dialkyl complexes supported by rigid tridentate 4,5-bis(anilido)xanthene and 2,6-bis(anilidomethyl)pyridine ligands (Journal article)
Cruz, C. A., Emslie, D. J. H., Harrington, L. E., Britten, J. F., & Robertson, C. M. (2007). Extremely stable thorium(IV) dialkyl complexes supported by rigid tridentate 4,5-bis(anilido)xanthene and 2,6-bis(anilidomethyl)pyridine ligands. ORGANOMETALLICS, 26(3), 692-701. doi:10.1021/om060914fDOI: 10.1021/om060914f
2006
Isostructural bisdithiazolyl and bisthiaselenazolyl radicals: Trends in bandwidth and conductivity (Journal article)
Brusso, J. L., Derakhshan, S., Itkis, M. E., Kleinke, H., Haddon, R. C., Oakley, R. T., . . . Thompson, L. K. (2006). Isostructural bisdithiazolyl and bisthiaselenazolyl radicals: Trends in bandwidth and conductivity. INORGANIC CHEMISTRY, 45(26), 10958-10966. doi:10.1021/ic061687cDOI: 10.1021/ic061687c
Synthesis of a heterobimetallic rhodium-iron complex containing an η<SUP>3</SUP>-interaction between rhodium and the B-C<i><sub>ipso</sub></i>-C<i><sub>ortho</sub></i> unit of a triarylborane (Journal article)
Oakley, S. R., Parker, K. D., Emslie, D. J. H., Vargas-Baca, I., Robertson, C. M., Harrington, L. E., & Britten, J. F. (2006). Synthesis of a heterobimetallic rhodium-iron complex containing an η<SUP>3</SUP>-interaction between rhodium and the B-C<i><sub>ipso</sub></i>-C<i><sub>ortho</sub></i> unit of a triarylborane. ORGANOMETALLICS, 25(25), 5835-5838. doi:10.1021/om060903mDOI: 10.1021/om060903m
Resonance stabilized bisdiselenazolyls as neutral radical conductors (Journal article)
Brusso, J. L., Cvrkalj, K., Leitch, A. A., Oakley, R. T., Reed, R. W., & Robertson, C. M. (2006). Resonance stabilized bisdiselenazolyls as neutral radical conductors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(47), 15080-15081. doi:10.1021/ja0666856DOI: 10.1021/ja0666856
2005
Naphthalene-1,2,3-dithiazolyl and its selenium-containing variants (Journal article)
Oakley, R. T., Reed, R. W., Robertson, C. M., & Richardson, J. F. (2005). Naphthalene-1,2,3-dithiazolyl and its selenium-containing variants. INORGANIC CHEMISTRY, 44(6), 1837-1845. doi:10.1021/ic048534eDOI: 10.1021/ic048534e
2003
Prototypal dithiazolodithiazolyl radicals: Synthesis, structures, and transport properties (Journal article)
Beer, L., Britten, J. F., Brusso, J. L., Cordes, A. W., Haddon, R. C., Itkis, M. E., . . . Robertson, C. M. (2003). Prototypal dithiazolodithiazolyl radicals: Synthesis, structures, and transport properties. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(47), 14394-14403. doi:10.1021/ja0371350DOI: 10.1021/ja0371350
2002
A π‐Stacked 1,2,3‐Dithiazolyl Radical. Preparation and Solid State Characterization of (Cl<sub>2</sub>C<sub>3</sub>NS)(ClC<sub>2</sub>NS<sub>2</sub>). (Journal article)
Beer, L., Cordes, A. W., Haddon, R. C., Itkis, M. E., Oakley, R. T., Reed, R. W., & Robertson, C. M. (2002). A π‐Stacked 1,2,3‐Dithiazolyl Radical. Preparation and Solid State Characterization of (Cl<sub>2</sub>C<sub>3</sub>NS)(ClC<sub>2</sub>NS<sub>2</sub>).. ChemInform, 33(51), 142. doi:10.1002/chin.200251142DOI: 10.1002/chin.200251142
A 1,2,3,5-dithiadiazolyl dimeric radical cation.: Preparation and solid state characterization of 1,3-[(S<sub>2</sub>N<sub>2</sub>C)C<sub>6</sub>H<sub>4</sub>(CN<sub>2</sub>S<sub>2</sub>)]<sub>2</sub>[Cl]<sub>3</sub> (Journal article)
Britten, J. F., Cordes, A. W., Haddon, R. C., Itkis, M. E., Oakley, R. T., Reed, R. W., & Robertson, C. M. (2002). A 1,2,3,5-dithiadiazolyl dimeric radical cation.: Preparation and solid state characterization of 1,3-[(S<sub>2</sub>N<sub>2</sub>C)C<sub>6</sub>H<sub>4</sub>(CN<sub>2</sub>S<sub>2</sub>)]<sub>2</sub>[Cl]<sub>3</sub>. CRYSTENGCOMM, 4, 205-207. doi:10.1039/b204999fDOI: 10.1039/b204999f
A π-stacked 1,2,3-dithiazolyl radical.: Preparation and solid state characterization of (Cl<sub>2</sub>C<sub>3</sub>NS)( ClC<sub>2</sub>NS<sub>2</sub>) (Journal article)
Beer, L., Cordes, A. W., Haddon, R. C., Itkis, M. E., Oakley, R. T., Reed, R. W., & Robertson, C. M. (2002). A π-stacked 1,2,3-dithiazolyl radical.: Preparation and solid state characterization of (Cl<sub>2</sub>C<sub>3</sub>NS)( ClC<sub>2</sub>NS<sub>2</sub>). CHEMICAL COMMUNICATIONS, (17), 1872-1873. doi:10.1039/b204855hDOI: 10.1039/b204855h