Em P Brian Heaton D. Phil. (Sussex) D. Sc. (Sussex)

Emeritus Professor Chemistry

+44 (0)151 794 3524
Work email Bth@liverpool.ac.uk

Publications

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2015

Comment on "The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]" by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D (Journal article)

Heaton, B. T., Grachova, E. V., Tunik, S. P., & Podkorytov, I. S. (2015). Comment on "The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]" by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D. DALTON TRANSACTIONS, 44(37), 16611-16613. doi:10.1039/c5dt01099c

DOI: 10.1039/c5dt01099c

2012

High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis (Journal article)

Torres, A., Perez, N. M., Overend, G., Hodge, N., Heaton, B. T., Iggo, J. A., . . . Gobby, D. (2012). High-Pressure In Situ NMR Methods for the Study of Reaction Kinetics in Homogeneous Catalysis. ACS CATALYSIS, 2(11), 2281-2289. doi:10.1021/cs300439n

DOI: 10.1021/cs300439n

2011

The inter-conversions of platinum carbonyl dianions [Pt3(CO)6]n2- (n = 2-5) in THF and acetonitrile. A combined in situ FTIR specstrocopic and BTEM study leading to the characterization of the new [H4-xPt15(CO)19]x- (x = 3, 4) cluster (Journal article)

Heaton, B. T., Gao, F., Li, C., Zachini, S., Zarra, S., Longoni, G., & Garland, M. (2011). The inter-conversions of platinum carbonyl dianions [Pt3(CO)6]n2- (n = 2-5) in THF and acetonitrile. A combined in situ FTIR specstrocopic and BTEM study leading to the characterization of the new [H4-xPt15(CO)19]x- (x = 3, 4) cluster. Dalton Transactions, (40), 5002-5008.

2010

The synthesis of, and characterization of the dynamic processes occurring in Pd(II) chelate complexes of 2-pyridyldiphenylphosphine (Journal article)

Liu, J., Jacob, C., Sheridan, K. J., Al-Mosule, F., Heaton, B. T., Iggo, J. A., . . . Steiner, A. (2010). The synthesis of, and characterization of the dynamic processes occurring in Pd(II) chelate complexes of 2-pyridyldiphenylphosphine. DALTON TRANSACTIONS, 39(34), 7921-7935. doi:10.1039/b918162h

DOI: 10.1039/b918162h

A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H2Rh2Pt2(CO)7(PPh3)3]2+ (Journal article)

Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Ponomarenko, V. I., Selivanov, S. I., & Tunik, S. P. (2010). A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H2Rh2Pt2(CO)7(PPh3)3]2+. INORGANICA CHIMICA ACTA, 363(3), 549-554. doi:10.1016/j.ica.2009.03.045

DOI: 10.1016/j.ica.2009.03.045

2009

The loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anionsThe loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anions (Journal article)

Heaton, B. T., Iggo, J. A., Femoni, C., Iapalucci, M. C., Longoni, G., Tiozzo, C., . . . Li, C. (2009). The loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anionsThe loss of CO from [Rh12(µ12-Sn)(CO)27]4-: Synthesis, Spectroscopic and Structural Characterization of the Electron-deficient, Icosahedral [Rh12(µ12-Sn)(CO)25]4- and [Rh12(µ12-Sn)(CO)26]4- Tetra-anions. Dalton Transactions, 2217-2223.

2008

Multinuclear NMR studies of the products resulting from the reaction of pyridine or 2,2′-bipyridine with [Rh4(CO)12] (Journal article)

Bradd, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., Sampanthar, J. T., & Zacchini, S. (2008). Multinuclear NMR studies of the products resulting from the reaction of pyridine or 2,2′-bipyridine with [Rh4(CO)12]. DALTON TRANSACTIONS, (5), 685-690. doi:10.1039/b715139j

DOI: 10.1039/b715139j

The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy (Journal article)

Overend, G., Iggo, J. A., Heaton, B. T., & Whyman, R. (2008). The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy. MAGNETIC RESONANCE IN CHEMISTRY, 46, S100-S106. doi:10.1002/mrc.2314

DOI: 10.1002/mrc.2314

2007

Sn-centred icosahedral Rh carbonyl clusters:: synthesis and structural characterization and 13C-{103Rh} HMQC NMR studies (Journal article)

Femoni, C., Iapalucci, M. C., Longoni, G., Tiozzo, C., Zacchini, S., Heaton, B. T., & Iggo, J. A. (2007). Sn-centred icosahedral Rh carbonyl clusters:: synthesis and structural characterization and 13C-{103Rh} HMQC NMR studies. DALTON TRANSACTIONS, (35), 3914-3923. doi:10.1039/b708469b

DOI: 10.1039/b708469b

A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters (Journal article)

Tomashevskaya, M. M., Tunik, S. P., Podkorytov, I. S., Heaton, B. T., Iggo, J. A., Haukka, M., . . . Pursiainen, J. (2007). A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692(14), 2911-2923. doi:10.1016/j.jorganchem.2007.03.008

DOI: 10.1016/j.jorganchem.2007.03.008

2006

CO fluxionality in Rh4(CO)12 and Rh6(CO)16 (Journal article)

Heaton, B. T., Jacob, C., Podkorytov, I. S., & Tunik, S. P. (2006). CO fluxionality in Rh4(CO)12 and Rh6(CO)16. Inorganica Chimica Acta, 359(11), 3557-3564. doi:10.1016/j.ica.2005.12.002

DOI: 10.1016/j.ica.2005.12.002

The mechanism of the hydroalkoxycarbonylation of ethene and alkene-CO copolymerization catalyzed by PdII-diphosphine cations (Journal article)

Liu, J., Heaton, B. T., Iggo, J. A., Whyman, R., Bickley, J. F., & Steiner, A. (2006). The mechanism of the hydroalkoxycarbonylation of ethene and alkene-CO copolymerization catalyzed by PdII-diphosphine cations. CHEMISTRY-A EUROPEAN JOURNAL, 12(16), 4417-4430. doi:10.1002/chem.200501398

DOI: 10.1002/chem.200501398

2005

'Comparison of theoretical studies and experimental results in the oxidative addition of alkyl or aryl halides to metal complexes' (Conference Paper)

Heaton, B. T., Iggo, J. A., Jacob, C., Skylaris, C. K., & Whyman, R. (2005). 'Comparison of theoretical studies and experimental results in the oxidative addition of alkyl or aryl halides to metal complexes'. In Â¿, 34th Inorganic Reaction Mechanisms Group Annual Meeting (pp. lecture). Liverpool: RSC.

Catalytic mechanisms from spectroscopic measurements (Book)

Heaton, B. T. (Ed.) (2005). Catalytic mechanisms from spectroscopic measurements. Weinheim, Germany: Wiley-VCH.

2004

The complete delineation of the initiation, propagation, and termination steps of the carbomethoxy cycle for the carboalkoxylation of ethene by Pd-diphosphane catalysts (Journal article)

Liu, J. K., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). The complete delineation of the initiation, propagation, and termination steps of the carbomethoxy cycle for the carboalkoxylation of ethene by Pd-diphosphane catalysts. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43(1), 90-94. doi:10.1002/anie.200352369

DOI: 10.1002/anie.200352369

Synthesis and structural characterization of two novel heterometallic clusters:: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2] (Journal article)

Koshevoy, I. O., Grachova, E. V., Tunik, S. P., Haukka, M., Pakkanen, T. A., Heaton, B. T., . . . Podkorytov, I. S. (2004). Synthesis and structural characterization of two novel heterometallic clusters:: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2]. DALTON TRANSACTIONS, (22), 3893-3899. doi:10.1039/b410216a

DOI: 10.1039/b410216a

Methanolysis of acyl-Pd(II) complexes relevant to CO/ethene coupling reactions (Journal article)

Liu, J. K., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). Methanolysis of acyl-Pd(II) complexes relevant to CO/ethene coupling reactions. CHEMICAL COMMUNICATIONS, (11), 1326-1327. doi:10.1039/b402275k

DOI: 10.1039/b402275k

“An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.” (Conference Paper)

Sheridan, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2004). “An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.”. In A-DCOCC (Ed.), 5th Anglo-Dutch Conference on Organometallic Chemistry and Catalysis (pp. Pzz). Cardiff: A-DCOCC.

"Methanolysis of Acylpalladium (II) complexes relevant to CO/Ethene coupling reaction" (Conference Paper)

Liu, J., Heaton, B. T., Iggo, J. A., & Whyman, R. (2004). "Methanolysis of Acylpalladium (II) complexes relevant to CO/Ethene coupling reaction". In A-DCOCC (Ed.), 5th Anglo-Dutch Conference on Organometallic Chemistry and Catalysis (pp. Pyy). Cardiff: A-DCOCC.

174."The Application of HMQC Spectroscopy to the Observation of the Metal resonance in polymetallic Compounds; the Effect of Multiple-Metal Spin Transitions" (Journal article)

Heaton, B. T., Iggo, J. A., Podkorytov, I., & Tunik, S. P. (2004). 174."The Application of HMQC Spectroscopy to the Observation of the Metal resonance in polymetallic Compounds; the Effect of Multiple-Metal Spin Transitions". Magnetic Resonance in Chemistry, 769-775.

2003

The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing bidentate phosphorus ligands (Journal article)

Farrar, D. H., Grachova, E. V., Haukka, M., Heaton, B. T., Iggo, J. A., Pakkanen, T. A., . . . Tunik, S. P. (2003). The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing bidentate phosphorus ligands. INORGANICA CHIMICA ACTA, 354, 11-20. doi:10.1016/S0020-1693(03)00315-3

DOI: 10.1016/S0020-1693(03)00315-3

Promotional effects of water and N-containing bases on Co-catalysed methoxycarbonylation of oct-1-ene (Journal article)

Jacob, C., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). Promotional effects of water and N-containing bases on Co-catalysed methoxycarbonylation of oct-1-ene. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 204, 149-155. doi:10.1016/S1381-1169(03)00294-2

DOI: 10.1016/S1381-1169(03)00294-2

Palladium(II)/β-diketonate complexes containing the enolates of N-acetyl-3-acyltetramic acids -: Crystal structure of the Lewis base adduct, [Pd(py)4](abta)2 (Journal article)

Gavrielatos, E., Athanasellis, G., Heaton, B. T., Steiner, A., Bickley, J. F., Igglessi-Markopoulou, O., & Markopoulos, J. (2003). Palladium(II)/β-diketonate complexes containing the enolates of N-acetyl-3-acyltetramic acids -: Crystal structure of the Lewis base adduct, [Pd(py)4](abta)2. INORGANICA CHIMICA ACTA, 351, 21-26. doi:10.1016/S0020-1693(03)00196-8

DOI: 10.1016/S0020-1693(03)00196-8

Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2NC(O)Me]–Dedicated to Dr Jean-Marie Basset on the occasion of his 60th birthday, with our congratulations and best wishes. (Journal article)

Braunstein, P., Heaton, B. T., Jacob, C., Manzi, L., & Morise, X. (2003). Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2NC(O)Me]–Dedicated to Dr Jean-Marie Basset on the occasion of his 60th birthday, with our congratulations and best wishes.. Dalton Transactions, (7), 1396-1401. doi:10.1039/b208735a

DOI: 10.1039/b208735a

“Spectroscopic studies on catalytic intermediates involved in the methoxycarbonylation of ethylene.” (Conference Paper)

Pepin, A., Eastham, G. R., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). “Spectroscopic studies on catalytic intermediates involved in the methoxycarbonylation of ethylene.”. In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.

"Elucidation of palladium carbomethoxy catalytic cycle in the Pd-catalysed CO/ ethylene reaction" (Conference Paper)

Liu, J., Heaton, B. T., Iggo, J. A., & Whyman, R. (2003). "Elucidation of palladium carbomethoxy catalytic cycle in the Pd-catalysed CO/ ethylene reaction". In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.

"NMR, X-ray Crystallographic Studies and DFT Calculations on Products resulting from the Oxidative Addition of Rhodium(I)/beta-diketonate Complexes with Methyl Iodide." (Conference Paper)

Bickley, J., Davis, J., Gray, J., Heaton, B. T., Iggo, J. A., Jacob, J., . . . Whyman, R. (2003). "NMR, X-ray Crystallographic Studies and DFT Calculations on Products resulting from the Oxidative Addition of Rhodium(I)/beta-diketonate Complexes with Methyl Iodide.". In A. L. Petrou (Ed.), Inorganic Mechanisms 2003 (pp. L 29). Athens, Greece: RSC/University oif Athens.

"The Structure and dynamic behaviour of disubstituted derivatives Rh6(CO)16 containing bidentate phosphorus ligands. Structure and dynamic behaviour" (Journal article)

Farrar, D. H., Grachova, E. V., Haukka, M., Heaton, B. T., Iggo, J. A., Nordlander, E., . . . Tunik, S. P. (2003). "The Structure and dynamic behaviour of disubstituted derivatives Rh6(CO)16 containing bidentate phosphorus ligands. Structure and dynamic behaviour". Inorganica Chimica Acta, 354, 11-20.

Elucidation of Catalytic Mechanisms from NMR measurements under ambient and high pressures of gas (Conference Paper)

Heaton, B. T. (2003). Elucidation of Catalytic Mechanisms from NMR measurements under ambient and high pressures of gas. In R. Society of Chemistry (Ed.), Royal Society of Chemistry, Dalton Division (pp. 1-4). Nottingham: Royal Society of Chemistry, Dalton Division.

Elucidation of Transition Metal Catalysed Reactions from in situ NMR measurements (Conference Paper)

Heaton, B. T. (2003). Elucidation of Transition Metal Catalysed Reactions from in situ NMR measurements. In F. of European Chemical Society (Ed.), XVth Conference on Organometallic Chemistry (pp. PL 06). Zurich: Federation of European Chemical Society.

The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing heterobidentate bridging phosphine ligands (Journal article)

Grachova, E. V., Haukka, M., Heaton, B. T., Nordlander, E., Pakkanen, T. A., Podkorytov, I. S., & Tunik, S. P. (2003). The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing heterobidentate bridging phosphine ligands. Dalton Transactions, (12), 2468. doi:10.1039/b211790h

DOI: 10.1039/b211790h

¿An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.¿ (Conference Paper)

Sheridan, K. J., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2003). ¿An Investigation of palladium-(2-pyridyldiphenylphosphine) complexes as possible precursors in alkyne carbonylation.¿. In RSC (Ed.), Dalton Discussion 6: Organometallic Chemistry and Catalysis (pp. Pxx). York: RSC.

2002

The effect of mechanistic pathway on activity in the Pd and Pt catalysed methoxycarbonylation of ethene (Journal article)

Wolowska, J., Eastham, G. R., Heaton, B. T., Iggo, J. A., Jacob, C., & Whyman, R. (2002). The effect of mechanistic pathway on activity in the Pd and Pt catalysed methoxycarbonylation of ethene. CHEMICAL COMMUNICATIONS, (23), 2784-2785. doi:10.1039/b208450c

DOI: 10.1039/b208450c

Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C4H9)4N]2[Pt2Br10]•(Br2)7 and [(C4H9)4N]2[PtBr4Cl2]•(Br2)6 (Journal article)

Berkei, M., Bickley, J. F., Heaton, B. T., & Steiner, A. (2002). Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C4H9)4N]2[Pt2Br10]•(Br2)7 and [(C4H9)4N]2[PtBr4Cl2]•(Br2)6. CHEMICAL COMMUNICATIONS, (18), 2180-2181. doi:10.1039/b205712n

DOI: 10.1039/b205712n

Synthesis and reactivity of palladium hydrido-solvento complexes, including a key intermediate in the catalytic methoxycarbonylation of ethene to methyl propanoate (Journal article)

Clegg, W., Eastham, G. R., Elsegood, M. R. J., Heaton, B. T., Iggo, J. A., Tooze, R. P., . . . Zacchini, S. (2002). Synthesis and reactivity of palladium hydrido-solvento complexes, including a key intermediate in the catalytic methoxycarbonylation of ethene to methyl propanoate. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (17), 3300-3308. doi:10.1039/b202372p

DOI: 10.1039/b202372p

Characterization and dynamics of [Pd(L-L)H(solv)]+, [Pd(L-L)(CH2CH3)]+, and [Pd(L-L)(C(O)Et)(THF)]+ (L-L=1,2-(CH2PBut2)2C6H4):: Key intermediates in the catalytic methoxycarbonylation of ethene to methylpropanoate (Journal article)

Clegg, W., Eastham, G. R., Elsegood, M. R. J., Heaton, B. T., Iggo, J. A., Tooze, R. P., . . . Zacchini, S. (2002). Characterization and dynamics of [Pd(L-L)H(solv)]+, [Pd(L-L)(CH2CH3)]+, and [Pd(L-L)(C(O)Et)(THF)]+ (L-L=1,2-(CH2PBut2)2C6H4):: Key intermediates in the catalytic methoxycarbonylation of ethene to methylpropanoate. ORGANOMETALLICS, 21(9), 1832-1840. doi:10.1021/om010938g

DOI: 10.1021/om010938g

Carbon monoxide activation in homogeneously catalysed reactions: the nature and roles of catalytic promoters (Journal article)

Whyman, R., Wright, A. P., Iggo, J. A., & Heaton, B. T. (2002). Carbon monoxide activation in homogeneously catalysed reactions: the nature and roles of catalytic promoters. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (5), 771-777. doi:10.1039/b107940a

DOI: 10.1039/b107940a

"Carbon Monoxide Activation in Homogeneously Catalysed Reactions: the Nature and the Roles of the Catalytic Promoters" (Journal article)

Whyman, R., Wright, A. P., Iggo, J. A., & Heaton, B. T. (2002). "Carbon Monoxide Activation in Homogeneously Catalysed Reactions: the Nature and the Roles of the Catalytic Promoters". Journal of the Chemical Society, Dalton Transactions, 771-777.

"Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]" (Journal article)

Berkei, M., Bickley, J. F., & Heaton, B. T. (2002). "Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]". Zeitschrift fur natuforschung, 57 b(6), 610-614.

"NMR Studies of Metal-Carbonyl/PhosphineComplexes/Clusters" (Chapter)

Heaton, B. T. (2002). "NMR Studies of Metal-Carbonyl/PhosphineComplexes/Clusters". In G. J. Leigh, & N. Winterton (Eds.), Modern Coordination Chemistry-the Legacy of Joseph Chatt (pp. 89-100). Cambridge: Royal Society of Chemistry.

Elucidation of Catalytic Mechanisms from NMR measurements under pressures of gas (Conference Paper)

Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2002). Elucidation of Catalytic Mechanisms from NMR measurements under pressures of gas. In I. Conference on Coordination Chemistry (Ed.), XXXV International Conference on Coordination Chemistry (pp. 78). Heidelberg: University of Heidelberg/GDCh.

¿Characterisation of new platinum complexes as possible intermediates in the methoxycarbonylation of ethane¿ (Conference Paper)

Eastham, G. R., Heaton, B. T., Iggo, J. A., Whyman, R., & Wolowska, J. (2002). ¿Characterisation of new platinum complexes as possible intermediates in the methoxycarbonylation of ethane¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P246). Tarragona: ISHC.

¿Elucidation of the mechanism of Pd catalyzed methoxycarbonylation¿ (Conference Paper)

Eastham, G. R., Heaton, B. T., Iggo, J. A., Liu, J., Tooze, R. P., Whyman, R., & Zacchini, S. (2002). ¿Elucidation of the mechanism of Pd catalyzed methoxycarbonylation¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P219). Tarragona: ISHC.

¿Toward integrating kinetic and structural NMR studies in homogeneous catalysis¿ (Conference Paper)

Heaton, B. T., Iggo, J. A., Molina Perez, N., Muir, M., & Whyman, R. (2002). ¿Toward integrating kinetic and structural NMR studies in homogeneous catalysis¿. In ISHC (Ed.), 13th International Symposium on Homogeneous Catalysis (pp. P215). Tarragona: ISHC.

2001

Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution (Journal article)

Grachova, E. V., Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (2001). Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (22), 3303-3311. doi:10.1039/b101962g

DOI: 10.1039/b101962g

Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues.: Crystal structure of [Cu(abta)2(py)2]•2H2O (Journal article)

Gavrielatos, E., Mitsos, C., Athanasellis, G., Heaton, B. T., Steiner, A., Bickley, J. F., . . . Markopoulos, J. (2001). Copper(II), cobalt(II), nickel(II) and zinc(II) complexes containing the enolate of N-acetyl-3-butanoyltetramic acid (Habta) and its phenylhydrazone derivative analogues.: Crystal structure of [Cu(abta)2(py)2]•2H2O. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (5), 639-644. doi:10.1039/b007252o

DOI: 10.1039/b007252o

1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2-1 (Journal article)

Sabounchei, J. S. Z., Heaton, B. T., Iggo, J. A., Jacob, C., & Podkorytov, I. S. (2001). 1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2-1. JOURNAL OF CLUSTER SCIENCE, 12(1), 339-348. doi:10.1023/A:1016651819071

DOI: 10.1023/A:1016651819071

Mechanistic studies of the hydroformylation of 1-alkenes using a monodentate phosphorus diamide ligand (Journal article)

van der Slot, S. C., Kamer, P. C. J., van Leeuwen, P. W. N. M., Iggo, J. A., & Heaton, B. T. (2001). Mechanistic studies of the hydroformylation of 1-alkenes using a monodentate phosphorus diamide ligand. ORGANOMETALLICS, 20(3), 430-441. doi:10.1021/om000785h

DOI: 10.1021/om000785h

"Rhodium Complexes Containing O-bonded NHxMe2-xCHO (x = 0, 1, 2); X-ray Structure of [Rh(PPh3)3(OCHNHMe)]ClO4" (Journal article)

Sabounchei, J. S., Heaton, B. T., Jacob, C., Jones, C., Olsson, A., Smith, A. K., & Kloo, L. (2001). "Rhodium Complexes Containing O-bonded NHxMe2-xCHO (x = 0, 1, 2); X-ray Structure of [Rh(PPh3)3(OCHNHMe)]ClO4". Helvetica Chimica Aca, 84(10), 3075-3084.

"Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution" (Journal article)

Grachova, E. V., Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (2001). "Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solution". Journal of the Chemical Society, Dalton Transactions, (22), 3303-3311.

1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2- (Journal article)

Sabounchei, J. S. Z., Heaton, B. T., Iggo, J. A., Jacob, C., & Podkorytov, I. S. (2001). 1-and 2-D NMR studies on [Rh6C(CO)14(PPh3)]2-. Journal of Cluster Science, 12(1), 339-348.

Acetic acid via methanol carbonylation: Ruthenium promotion of the iridium catalyzed CATIVA process (Journal article)

Heaton, B. T., Iggo, J. A., Whyman, R., & Wright, A. P. (2001). Acetic acid via methanol carbonylation: Ruthenium promotion of the iridium catalyzed CATIVA process. Abstracts of Papers of the American Chemical Society, 222, 44-CATL.

2000

Hexacarbonyldiplatinum(I). Synthesis, Spectroscopy, and Density Functional Calculation of the First Homoleptic, Dinuclear Platinum(I) Carbonyl Cation, [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid (Journal article)

Xu, Q., Heaton, B. T., Jacob, C., Mogi, K., Ichihashi, Y., Souma, Y., . . . Eguchi, T. (2000). Hexacarbonyldiplatinum(I). Synthesis, Spectroscopy, and Density Functional Calculation of the First Homoleptic, Dinuclear Platinum(I) Carbonyl Cation, [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid. Journal of the American Chemical Society, 122(29), 6862-6870. doi:10.1021/ja000716u

DOI: 10.1021/ja000716u

Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene (Journal article)

Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2000). Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene. CHEMICAL COMMUNICATIONS, (7), 609-610. doi:10.1039/b001110j

DOI: 10.1039/b001110j

"Spectroscopic Characterisation of the First Homoleptic, Dinuclear, Cationic Platinum(I) Carbonyl Complex [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid" (Journal article)

Xu, Q., Souma, Y., Heaton, B. T., Jacob, C., & Kanamori, K. (2000). "Spectroscopic Characterisation of the First Homoleptic, Dinuclear, Cationic Platinum(I) Carbonyl Complex [{Pt(CO)3}2]2+, Formed in Concentrated Sulfuric Acid". Angewandte Chemie, International Edition, 39(1), 208-209.

"Synthesis and Spectroscopic Characterisation of all the Intermediates in the Pd-catalysed Methoxyarbonylation of Ethene" (Journal article)

Eastham, G. R., Heaton, B. T., Iggo, J. A., Tooze, R. P., Whyman, R., & Zacchini, S. (2000). "Synthesis and Spectroscopic Characterisation of all the Intermediates in the Pd-catalysed Methoxyarbonylation of Ethene". Journal of the Chemical Society, Chemical Communications, (7), 609-610.

1999

Multinuclear NMR Studies on Homo‐and Heterometallic Rhodium Clusters Containing 6 or More Metal Atoms (Chapter)

Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., & Tunik, S. P. (1999). Multinuclear NMR Studies on Homo‐and Heterometallic Rhodium Clusters Containing 6 or More Metal Atoms. In Unknown Book (pp. 960-1000). Wiley. doi:10.1002/9783527618316.ch3c

DOI: 10.1002/9783527618316.ch3c

Observation of triple-quantum effects in the HMQC spectra of substituted derivatives of Rh6(CO)16 (Journal article)

Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1999). Observation of triple-quantum effects in the HMQC spectra of substituted derivatives of Rh6(CO)16. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (12), 1917-1919. doi:10.1039/a903513c

DOI: 10.1039/a903513c

Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh3)3];: crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] (Journal article)

Dolgushin, F. M., Grachova, E. V., Heaton, B. T., Iggo, J. A., Koshevoy, I. O., Podkorytov, I. S., . . . Yanovskii, A. I. (1999). Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh3)3];: crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh3)3]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (10), 1609-1614. doi:10.1039/a809118h

DOI: 10.1039/a809118h

Oxidative addition of chlorinated solvents (eg CH2Cl2 and CHCl3) with rhodium(I) complexes;: crystal structure of mer-[Rh(py)3(CH2Cl)Cl2] (Journal article)

Bradd, K. J., Heaton, B. T., Jacob, C., Sampanthar, J. T., & Steiner, A. (1999). Oxidative addition of chlorinated solvents (eg CH2Cl2 and CHCl3) with rhodium(I) complexes;: crystal structure of mer-[Rh(py)3(CH2Cl)Cl2]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (7), 1109-1112. doi:10.1039/a809652j

DOI: 10.1039/a809652j

Solid state studies (X-ray and 1H-, 13C-NMR) on (NMe4)4-x[HxNi12(CO)21]•S (x = 1, S = Me2CO; x = 2, S = 2THF) (Journal article)

Barkley, J. V., Eguchi, T., Harding, R. A., Heaton, B. T., Longoni, G., Manzi, L., . . . Steiner, A. (1999). Solid state studies (X-ray and 1H-, 13C-NMR) on (NMe4)4-x[HxNi12(CO)21]•S (x = 1, S = Me2CO; x = 2, S = 2THF). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 573(1-2), 254-260. doi:10.1016/S0022-328X(98)00766-9

DOI: 10.1016/S0022-328X(98)00766-9

"Observation of Triple Quantum Effects in HMQC Spectra in [Rh6(CO)15{P(o-FC6H4)3}]" (Journal article)

Heaton, B. T., Iggo, J. A., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1999). "Observation of Triple Quantum Effects in HMQC Spectra in [Rh6(CO)15{P(o-FC6H4)3}]". Journal of the Chemical Society, Dalton Transactions, (12), 1917-1919.

Comparative solid state and solution NMR structural and dynamic studies on tetra- and higher-nuclearity transition metal carbonyl clusters (Journal article)

Eguchi, T., & Heaton, B. T. (1999). Comparative solid state and solution NMR structural and dynamic studies on tetra- and higher-nuclearity transition metal carbonyl clusters. Journal of the Chemical Society, Dalton Transactions, (20), 3523-3530. doi:10.1039/a810025j

DOI: 10.1039/a810025j

Synthesis and structural characterisation of the mixed metal clusters Rh2Pt3(m-CO)5(CO)4(PPh3)3 and Rh2Pt2(m-CO)3(CO)4(PPh3)3 ; crystal structure of Rh2Pt3(m-CO)5(CO)4(PPh3)3 (Journal article)

Dolgushin, F. M., Grachova, E. V., Heaton, B. T., Iggo, J. A., Koshevoy, I. O., Podkorytov, I. S., . . . Yanovskii, A. I. (1999). Synthesis and structural characterisation of the mixed metal clusters Rh2Pt3(m-CO)5(CO)4(PPh3)3 and Rh2Pt2(m-CO)3(CO)4(PPh3)3 ; crystal structure of Rh2Pt3(m-CO)5(CO)4(PPh3)3. Journal of the Chemical Society-Dalton Transactions, (10), 1609-1614.

1998

'Structural elucidation of rhodium clusters using modern NMR technique' (Conference Paper)

Grachova, E. V., Heaton, B. T., Iggo, J., Podkorytov, I. S., Smawfield, D. J., Tunik, S. P., & Whyman, R. (1998). 'Structural elucidation of rhodium clusters using modern NMR technique'. In ICCC (Ed.), 33rd International Conference on Coordination Chemistry (pp. 1). Florence: ICCC.

Multinuclear NMR studies on substituted derivatives of Rh6(CO)16 in solution (Journal article)

Tunik, S. P., Podkorytov, I. S., Heaton, B. T., Iggo, J. A., & Sampanthar, J. (1998). Multinuclear NMR studies on substituted derivatives of Rh6(CO)16 in solution. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 550(1-2), 221-231. doi:10.1016/S0022-328X(97)00189-7

DOI: 10.1016/S0022-328X(97)00189-7

1995

SOLUTION AND SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE STUDIES ON INTERSTITIAL ATOMS WITHIN TRANSITION-METAL CARBONYL CLUSTERS (Journal article)

HEATON, B. T., IGGO, J. A., LONGONI, G., & MULLEY, S. (1995). SOLUTION AND SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE STUDIES ON INTERSTITIAL ATOMS WITHIN TRANSITION-METAL CARBONYL CLUSTERS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (12), 1985-1989. doi:10.1039/dt9950001985

DOI: 10.1039/dt9950001985

1994

ADDUCTS OF TRIGONAL-PRISMATIC AND OCTAHEDRAL METAL-CLUSTERS CONTAINING INTERSTITIAL ATOMS (NITROGEN OR CARBON) WITH [AU(PPH(3))](+) (Journal article)

BLUM, T., HEATON, B. T., IGGO, J. A., SABOUNCHEI, J., & SMITH, A. K. (1994). ADDUCTS OF TRIGONAL-PRISMATIC AND OCTAHEDRAL METAL-CLUSTERS CONTAINING INTERSTITIAL ATOMS (NITROGEN OR CARBON) WITH [AU(PPH(3))](+). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (3), 333-337. doi:10.1039/dt9940000333

DOI: 10.1039/dt9940000333

KINETICS OF LIGAND EXCHANGES IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4 (VOL 22, PG 1857, 1994) (Journal article)

BENGTSSON, L. A., HEATON, B. T., IGGO, J. A., JACOB, C., MONKS, G. L., RATNAM, J., & SMITH, A. K. (1994). KINETICS OF LIGAND EXCHANGES IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4 (VOL 22, PG 1857, 1994). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (22), 3335. doi:10.1039/dt9940003335

DOI: 10.1039/dt9940003335

KINETICS OF LIGAND-EXCHANGE IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4 (Journal article)

BENGTSSON, L. A., HEATON, B. T., IGGO, J. A., JACOB, C., MONKS, G. L., RATNAM, J., & SMITH, A. K. (1994). KINETICS OF LIGAND-EXCHANGE IN RHODIUM-(I) AND RHODIUM-(III) COMPLEXES FROM MAGNETIZATION-TRANSFER MEASUREMENTS - THE CRYSTAL-STRUCTURE OF [RH(NH3)(PPH3)3]CLO4. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (13), 1857-1865. doi:10.1039/dt9940001857

DOI: 10.1039/dt9940001857

PHOSPHINE-SUBSTITUTED TRIGONAL-PRISMATIC AND OCTAHEDRAL CLUSTERS (Journal article)

BLUM, T., BROWN, M. P., HEATON, B. T., HOR, A. S., IGGO, J. A., SABOUNCHEI, J. S. Z., & SMITH, A. K. (1994). PHOSPHINE-SUBSTITUTED TRIGONAL-PRISMATIC AND OCTAHEDRAL CLUSTERS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (4), 513-520. doi:10.1039/dt9940000513

DOI: 10.1039/dt9940000513

REACTIONS OF WILKINSON CATALYST WITH PYRIDINE - OBSERVATION OF RHODIUM COMPLEXES CONTAINING BOTH PYRIDINE AND PHOSPHINE-LIGANDS (Journal article)

HEATON, B. T., IGGO, J. A., JACOB, C., NADARAJAH, J., FONTAINE, M. A., MESSERE, R., & NOELS, A. F. (1994). REACTIONS OF WILKINSON CATALYST WITH PYRIDINE - OBSERVATION OF RHODIUM COMPLEXES CONTAINING BOTH PYRIDINE AND PHOSPHINE-LIGANDS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (19), 2875-2880. doi:10.1039/dt9940002875

DOI: 10.1039/dt9940002875

1993

CHARACTERIZATION OF HYDRIDOPALLADIUM COMPLEXES (Journal article)

HEATON, B. T., HEBERT, S. P. A., IGGO, J. A., METZ, F., & WHYMAN, R. (1993). CHARACTERIZATION OF HYDRIDOPALLADIUM COMPLEXES. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (20), 3081-3084. doi:10.1039/dt9930003081

DOI: 10.1039/dt9930003081

1991

HIGH-PRESSURE SPECTROSCOPIC STUDIES OF REACTIONS OF THE CLUSTERS [RH4(CO)12-X(P(OPH)3)X] (X=1-4) WITH CARBON-MONOXIDE OR SYNGAS (Journal article)

BROWN, D. T., EGUCHI, T., HEATON, B. T., IGGO, J. A., & WHYMAN, R. (1991). HIGH-PRESSURE SPECTROSCOPIC STUDIES OF REACTIONS OF THE CLUSTERS [RH4(CO)12-X(P(OPH)3)X] (X=1-4) WITH CARBON-MONOXIDE OR SYNGAS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 677-683. doi:10.1039/dt9910000677

DOI: 10.1039/dt9910000677