- IP Status: patent application submitted
- Seeking: development partner, commercial partner.
Indoor air pollution causes an estimated 3.8 million deaths worldwide a year, according to a World Health Organisation report. Formaldehyde, for example, is the most common pollutant in indoor air, which can be emitted from walls, ﬂoors, cabinets, furniture, fabrics and cigarette smoke. Formaldehyde has been believed to cause various health problems, and has been classiﬁed as a Group 1 human carcinogen by WHO. Current technology for capturing formaldehyde is usually activated carbon adsorption, has low capture capacity and poor selectivity.
Researchers at the University of Liverpool have developed a molecular solution – a ‘cage prison’ to tackle this important challenge. Cage molecule solids have been designed and synthesised that eﬃciently capture low-concentration pollutants, by a combination of chemical and physical adsorption.
The researchers have obtained performance data to show the eﬀectiveness of the material from their own lab as well as through third-party testing facilities. The cage material has been proven to very eﬃciently capture formaldehyde at high and low concentration of formaldehyde even in the presence of high humidity.
In order to demonstrate its potential as air ﬁltration material, the researchers have made a prototype air puriﬁer ﬁtted with “cage loaded” air ﬁlters. They have also fabricated several “cage loaded” air ﬁlters which are ready to be sent for testing by their industrial partner and third-party testing facility.
Next steps are to look at the cost of goods and scale-up of manufacture. Synthesis of the material has been scaled up to an industrial level (kilograms) and the researchers are in discussions with several parties who have the facilities and ability to scale-up and potentially to supply the material in larger quantities.
In comparison to the activvated carbon material, which is widely used for domestic formaldehyde capture, these materials have the following advantages:
- Capacity - the overall formaldehyde capture capacity of the material is about 500 times more than that of activated carbon, the most common material used for formaldehyde removal indoors
- Selectivity - the formaldehyde adsorption capability of activated carbon decreases dramatically under humid conditions, due to poor formaldehyde/H2O selectivity, whereas this material will actually preferentially adsorb formaldehydes in humid conditions via reactions with functional groups
- Stability - physical adsorption can be reversible: activated carbon can release adsorbed pollutants at high temperatures and/or high humidity causing secondary pollution. In contrast, after the chemical absorption of formaldehyde molecules, the cage is robust, and will not generate the absorbed formaldehyde by decomposition until temperatures reach 300°C. This makes it ideal for use in hot, humid climates that are typical of many equatorial urban environments
- Compatibility - the cage material is solution processable and can be incorporated into pre-existing ﬁlter technologies to give a unique added beneﬁt.
The most common method to reduce indoor air pollution is through the use of air ﬁltration or puriﬁcation devices. The increasing awareness of their health beneﬁts coupled with tighter indoor air pollution regulations is fuelling growth in this area. It is estimated that the global indoor air ﬁltration market will reach $19 billion by 2020 and the global automotive air ﬁltration market will reach $6.1 billion by 2020.
In addition, the material has signiﬁcant potential in the paints/coatings market, which was valued at $141.58 billion in 2015 and is projected to reach $190.51 billion by 2021. By adding the cage material, the resulting paints/coatings can help abate the emission of formaldehyde from building materials and other sources of formaldehyde. Traditional adsorbents such as activated carbon or zeolites are generally insoluble in liquids and cannot readily be added as a formaldehyde scavenger into paints/coatings formulations. By contrast, the cage material can be easily incorporated into paints/coatings as a result of its solubility.
Based on this technology, it is possible to design and develop new materials for other speciﬁc pollutant scavenging – expanding its capability to capture other toxic VOC’s such as benzene. This represents a huge opportunity for a new material to make a real environmental, health and commercial impact.
The intellectual property associated with this technology is protected under a patent application (WO2016174468 A1), and the IP is owned by the University of Liverpool, with no encumbrances.