Module Details

The information contained in this module specification was correct at the time of publication but may be subject to change, either during the session because of unforeseen circumstances, or following review of the module at the end of the session. Queries about the module should be directed to the member of staff with responsibility for the module.
Title Solid State Chemistry and Energy Storage Materials
Code CHEM442
Coordinator Dr JB Claridge
Chemistry
J.B.Claridge@liverpool.ac.uk
Year CATS Level Semester CATS Value
Session 2021-22 Level 7 FHEQ Second Semester 7.5

Pre-requisites before taking this module (or general academic requirements):

CHEM313 CHEM313 - Inorganic Materials Chemistry 

Aims

• To provide an introduction to diffraction methods for the characterisation of solid state materials.
• To introduce the students to the concepts and applications of symmetry in the solid state.
• To provide an introduction to the structures of solid state materials and their description and phase transitions.
• To provide a perspective on the ranges of properties displayed by solids, particularly cooperative magnetism, ferroelectricity, and multiferroicity and their relationships to structure and symmetry.
• To introduce the rich chemistry of insertion materials and highlight their relevance in energy applications.
• To demonstrate the importance of defect chemistry with particular relevance to energy materials.
• To provide a basic understanding of superconductivity and the chemistry of superconducting materials.
This will provide the student with a deep and high level understanding of the properties of solids, and currently active areas of research, to enable the student to pursue their interests to a deeper level independently (for example to PhD level).


Learning Outcomes

(LO1) Students will be able to demonstrate an understanding of the application of diffraction methods to the characterisation of key material types in the solid state.

(LO2) Students will become familiar with a range of properties displayed by solids, particularly cooperative magnetism, ferroelectricity and multiferroicity, and how these relate to structure and symmetry.

(LO3) Student will be able to demonstrate a grasp of the importance of intercalation/insertion chemistry in energy storage applications (batteries).

(LO4) Students will develop the ability to relate fundamental concepts of diffraction, characterisation etc. in solid state chemistry to practical applications in energy storage and related materials.

(S1) Critical thinking (e.g. compare and contrast different energy storage devices and their advantageous and disadvantageous properties, scientific challenges etc.)

(S2) Self-study via reading and understanding suggested review articles


Teaching and Learning Strategies

15 online lecture equivalents, supported by 2 3-hour workshops, 1 1-hour tutorial, and a 1 hour-Peerwise exercise.


Syllabus

 

Battery and Electrode Materials (LJH, 7 lectures + 1 Tutorial)
• Introduction to insertion chemistry – chemical and electrochemical methods of synthesis
• Intercalation/Insertion chemistry in batteries (Li-ion, Na-ion, ternary intercalation compounds)
• The proton as the guest species – NiMH hydride batteries, H2 storage
• Alloy chemistry in battery electrochemistry and phase diagrams (applied thermodynamics)
• Ternary electrodes under equilibrium or near-equilibrium conditions
• Superconductivity
• Defect chemistry – ion conduction (solid state electrolytes)

Solid State Chemistry (JBC, 8 Lectures + 2 Workshops)
Part I: Fundamentals of solids, symmetry and reciprocal space.
• Point Symmetry Operations, Crystal Systems and Bravis Lattices
• Crystallographic Point Groups and Development of Space Groups
• Space Group Applications (and N ow Atoms)
• Reciprocal Space and the fundamentals of diffraction
• Practical diffraction (How does one find out what one has made?)
Part II: Understanding cooperative properties and phase transitions: the application of symmetry.
• Ferroelectrics and phase transitions
• Cooperative magnetism and multiferroicics (a symmetry based approach)
Workshops:
• Introduction and walkthrough of some crytallographically useful software and web resources
• My first structure solution


Recommended Texts

Reading lists are managed at readinglists.liverpool.ac.uk. Click here to access the reading lists for this module.

Teaching Schedule

  Lectures Seminars Tutorials Lab Practicals Fieldwork Placement Other TOTAL
Study Hours 15

  1

    1

6

23
Timetable (if known)              
Private Study 103
TOTAL HOURS 126

Assessment

EXAM Duration Timing
(Semester)
% of
final
mark
Resit/resubmission
opportunity
Penalty for late
submission
Notes
online time-controlled written exam  2 hours + 1 hour for    60       
CONTINUOUS Duration Timing
(Semester)
% of
final
mark
Resit/resubmission
opportunity
Penalty for late
submission
Notes
Online Tutorial workshops in diffraction methods/characterisation techniques Standard UoL penalties apply for late submission. There is no re-submission opportunity. These assignments are not marke  2 x 3 hour    20       
Online tutorial exercise on energy storage materials (Dr. Hardwick) Standard UoL penalty applies for late submission. This is not an anonymous assessment. Assessment Schedule (When) :Early-mid se  1 h    10       
Peerwise exercise on entire module topics (Dr. Hardwick) Standard UoL penalty applies for late submission. This is not an anonymous assessment. Assessment Schedule (When) :Mid-semester (week 6)  1 h    10