Photo of Dr Alexey Sergeev

Dr Alexey Sergeev Ph.D. in Chemistry

Lecturer in Chemistry Chemistry

Publications

2020

Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids (Journal article)

Neumann, H., Sergeev, A., Spannenberg, A., & Beller, M. (2020). Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids. Molecules, 25(15). doi:10.3390/molecules25153421

DOI: 10.3390/molecules25153421

Metal-mediated cleavage of unsaturated C-C bonds (Journal article)

Chan, A. P. Y., & Sergeev, A. G. (2020). Metal-mediated cleavage of unsaturated C-C bonds. COORDINATION CHEMISTRY REVIEWS, 413. doi:10.1016/j.ccr.2020.213213

DOI: 10.1016/j.ccr.2020.213213

2019

Transition-Metal-Mediated Cleavage of C-C Bonds in Aromatic Rings (Journal article)

Jakoobi, M., & Sergeev, A. G. (2019). Transition-Metal-Mediated Cleavage of C-C Bonds in Aromatic Rings. CHEMISTRY-AN ASIAN JOURNAL, 14(13), 2181-2192. doi:10.1002/asia.201900443

DOI: 10.1002/asia.201900443

Reversible insertion of Ir into arene ring C-C bonds with improved regioselectivity at a higher reaction temperature (Journal article)

Jakoobi, M., Tian, Y., Boulatov, R., & Sergeev, A. (2019). Reversible insertion of Ir into arene ring C-C bonds with improved regioselectivity at a higher reaction temperature. Journal of the American Chemical Society, 141(14), 6048-6053. doi:10.1021/jacs.9b01562

DOI: 10.1021/jacs.9b01562

2017

Selective arene cleavage by direct insertion of iridium into the aromatic ring (Journal article)

Jakoobi, M., Halcovitch, N., Whitehead, G., & Sergeev, A. (2017). Selective arene cleavage by direct insertion of iridium into the aromatic ring. Angewandte Chemie (International Edition), 56(12), 3266-3269. doi:10.1002/anie.201611409

DOI: 10.1002/anie.201611409

2014

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes (Journal article)

Bair, J. S., Schramm, Y., Sergeev, A., Clot, E., Eisenstein, O., & Hartwig, J. F. (2014). Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes. Journal of the American Chemical Society, 136(38), 13098-13101. doi:10.1021/ja505579f

DOI: 10.1021/ja505579f

2012

A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation (Journal article)

Sergeev, A. G., Webb, J. D., & Hartwig, J. F. (2012). A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(50), 20226-20229. doi:10.1021/ja3085912

DOI: 10.1021/ja3085912

2011

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers (Journal article)

Sergeev, A. G., & Hartwig, J. F. (2011). Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers. SCIENCE, 332(6028), 439-443. doi:10.1126/science.1200437

DOI: 10.1126/science.1200437

2010

A General and Efficient Catalyst for Palladium-Catalyzed C-O Coupling Reactions of Aryl Halides with Primary Alcohols (Journal article)

Gowrisankar, S., Sergeev, A. G., Anbarasan, P., Spannenberg, A., Neumann, H., & Beller, M. (2010). A General and Efficient Catalyst for Palladium-Catalyzed C-O Coupling Reactions of Aryl Halides with Primary Alcohols. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(33), 11592-11598. doi:10.1021/ja103248d

DOI: 10.1021/ja103248d

Synthesis and Catalytic Applications of Stable Palladium Dioxygen Complexes (Journal article)

Sergeev, A. G., Neumann, H., Spannenberg, A., & Beller, M. (2010). Synthesis and Catalytic Applications of Stable Palladium Dioxygen Complexes. ORGANOMETALLICS, 29(15), 3368-3373. doi:10.1021/om1003418

DOI: 10.1021/om1003418

2009

Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions (Journal article)

Sergeev, A. G., Schulz, T., Torborg, C., Spannenberg, A., Neumann, H., & Beller, M. (2009). Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 48(41), 7595-7599. doi:10.1002/anie.200902148

DOI: 10.1002/anie.200902148

2008

Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction (Journal article)

Sergeev, A. G., Spannenberg, A., & Beller, M. (2008). Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(46), 15549-15563. doi:10.1021/ja804997z

DOI: 10.1021/ja804997z

Palladium catalysts for the formylation of vinyl triflates to form alpha,beta-unsaturated aldehydes (Journal article)

Neumann, H., Sergeev, A., & Beller, M. (2008). Palladium catalysts for the formylation of vinyl triflates to form alpha,beta-unsaturated aldehydes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47(26), 4887-4891. doi:10.1002/anie.200800994

DOI: 10.1002/anie.200800994

Synthesis- and crystal structure of palladium(0) and arylpalladium(II) bromide complexes of CataCXium A (Journal article)

Sergeev, A. G., Zapf, A., Spannenberg, A., & Beller, M. (2008). Synthesis- and crystal structure of palladium(0) and arylpalladium(II) bromide complexes of CataCXium A. ORGANOMETALLICS, 27(2), 297-300. doi:10.1021/om700889b

DOI: 10.1021/om700889b

2007

Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination (Journal article)

Sergeev, A. G., Artamkina, G. A., Khrustalev, V. N., Antipin, M. Y., & Beletskaya, I. P. (2007). Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination. MENDELEEV COMMUNICATIONS, 17(3), 142-144. doi:10.1016/j.mencom.2007.05.003

DOI: 10.1016/j.mencom.2007.05.003

2006

Urea as ammonia equivalent in aryl halides amination catalyzed by palladium complexes (Journal article)

Artamkina, G. A., Sergeev, A. G., Shtern, M. M., & Beletskaya, I. P. (2006). Urea as ammonia equivalent in aryl halides amination catalyzed by palladium complexes. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 42(11), 1683-1689. doi:10.1134/S1070428006110133

DOI: 10.1134/S1070428006110133

One-Pot synthesis of symmetrical Di- and triarylamines using urea as the source of the amino group (Journal article)

Artamkina, G. A., Sergeev, A. G., Stern, M. M., & Beletskaya, I. P. (2006). One-Pot synthesis of symmetrical Di- and triarylamines using urea as the source of the amino group. SYNLETT, (2), 235-238. doi:10.1055/s-2005-923596

DOI: 10.1055/s-2005-923596

2005

Palladium-catalyzed amination and amidation of benzo-fused bromine-containing heterocycles (Journal article)

Sergeev, A. G., Artamkina, G. A., Velezheva, V. S., Fedorova, I. N., & Beletskaya, I. P. (2005). Palladium-catalyzed amination and amidation of benzo-fused bromine-containing heterocycles. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 41(6), 860-874. doi:10.1007/s11178-005-0257-0

DOI: 10.1007/s11178-005-0257-0

2003

Variation of xantphos-based ligands in the palladium-catalyzed reaction of aryl halides with ureas (Journal article)

Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of xantphos-based ligands in the palladium-catalyzed reaction of aryl halides with ureas. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 39(12), 1741-1752. doi:10.1023/B:RUJO.0000019738.50339.e8

DOI: 10.1023/B:RUJO.0000019738.50339.e8

Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas (Journal article)

Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas. TETRAHEDRON LETTERS, 44(25), 4719-4723. doi:10.1016/S0040-4039(03)01051-7

DOI: 10.1016/S0040-4039(03)01051-7

Variation of Xanthphos-Based Bidentate Ligands in the Palladium-Catalyzed Reaction Aryl Halides with Ureas (Engl. Transl.) (Journal article)

Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2003). Variation of Xanthphos-Based Bidentate Ligands in the Palladium-Catalyzed Reaction Aryl Halides with Ureas (Engl. Transl.). Russ. J. Org. Chem., 39, 860-874.

2002

Palladium-catalyzed arylation of ureas (Journal article)

Artamkina, G. A., Sergeev, A. G., & Beletskaya, I. P. (2002). Palladium-catalyzed arylation of ureas. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 38(4), 538-545. doi:10.1023/A:1016503307552

DOI: 10.1023/A:1016503307552

Palladium-Catalyzed Arylation of Ureas (Engl. Transl.) (Journal article)

Sergeev, A. G., Artamkina, G. A., & Beletskaya, I. P. (2002). Palladium-Catalyzed Arylation of Ureas (Engl. Transl.). Russ. J. Org. Chem., 38, 538-545.

2001

Palladium-catalyzed reaction of aryl halides with ureas (Journal article)

Artamkina, G. A., Sergeev, A. G., & Beletskaya, I. P. (2001). Palladium-catalyzed reaction of aryl halides with ureas. TETRAHEDRON LETTERS, 42(26), 4381-4384. doi:10.1016/S0040-4039(01)00716-X

DOI: 10.1016/S0040-4039(01)00716-X