Programme Grant

Chemical Synthesis of Transformative Extended Materials

Reference Number: EP/H000925/1

Start date: 1/10/2009

End date: 31/3/2015

The Programme Grant (PG) is a collaboration between the University of Liverpool (UoL) and University College London (UCL) that is developing new capability in the chemical synthesis of functional materials. The project involves organic, inorganic, and hybrid nanomaterials synthesis, coupled with characterisation and the computational understanding of the resulting structures and properties.

Department of Chemistry University of Liverpool:

A. I. Cooper

M. J. Rosseinsky

Department of Chemistry, University College London:

F. Cora

B. Slater

Research highlights

Porous Materials

Barrer identified molecular porous solids as a distinct family of porous materials in the 1970s (Barrer J. Chem. Soc., Chem. Commun. 1976, 9, 333). However, crystalline solids such as Dianin’s compound and calixarenes have been associated with marginal surface areas (0–350 m2/g) and unpredictable molecular packing, which has limited their utility. We developed a family of porous organic cagemolecules with much larger surface areas (>600 m2/g; Nature Mater. 2009, 8, 973; >1,300 m2/g, Nature 2011, 474, 367).

PG1

Because the porosity is a property of the molecule itself, we can use solution processability to create hybrid materials and composites that cannot readily be formed with more traditional insoluble framework materials. (ACIE 2013, 52, 1253).

PG2

The 6:1 sorption selectivity for p-xylene over m-xylene in a metal-organic framework (Angew. Chem. Int. Ed. 2014, 10.1002/anie.201307656; UK patent appl. 1215693) is part of a broader study of molecular separations that includes dynamical restructuring around guests (J. Am. Chem. Soc. 2012, 134, 20466) and separation of mesitylene from its isomers (Nat. Chem. 2013, 5, 276). Our work on flexible metal-organic frameworks in molecular separations was the subject of a Nature News and Views article.

PG3

PG4

We have also produced the first solution processable conjugated microporous polymers (UK patent appl. No. 1219783.6; ACIE 2012, 51, 12727). This opens up new technological possibilities for this growing class of porous material.

PG5

Solid State Conductors

We have produced new approaches to mixed ionic and electronic conductors for use as solid oxide fuel cell cathodes. The modular structure of complex oxides can enhance oxide anion mobility by structural and chemical bonding mismatch at the interface between the blocks. This destabilisation of the equilibrium geometry of the solid facilitates bond-breaking processes associated with ionic migration. This internal activation strain thus lowers the barrier to anion motion. (Chem. Mater., 2013, 25, 3441–3457).

PG6

Magnetoelectric Properties

Multiferroic and magnetoelectric materials that can combine electrical writing and magnetic reading in four-state and low-power memories are important for next-generation information storage. We have combined polarity and ferromagnetism above room temperature in ScFeO3. (Journal of the American Chemical Society 2012, 134, 3737-3747)

PG7

The local-structure of the lead-free polar material Bi(Ti3/8Mg3/8Fe¼)O3 has been revealed by pair distribution function analysis, which shows that the local structure is monoclinic rather than rhombohedral. (Journal of the American Chemical Society 2012, 134, 5836-5849)

PG8

Photocatalysis

The porphyrin group is responsible for solar absorption in photosynthesis. We have made a hybrid open framework material where porphyrins are separated by metal hydroxide chains. This material generates hydrogen from water sacrificially under visible-light illumination. (Angew. Chem., Int. Ed., 2012, 7440-7444)

PG9

Publications

  • A metal-organic framework with a covalently prefabricated porous organic linker, Swamy, Shashikala I., Bacsa, John, Jones, James T. A., Stylianou, Kyriakos C., Steiner, Alexander, Ritchie, Lyndsey K., Hasell, Tom, Gould, Jamie A., Laybourn, Andrea, Khimyak, Yaroslav Z., Adams, Dave J., Rosseinsky, Matthew J., and Cooper, Andrew I., J. Am. Chem. Soc. 132 (37), 12773, 2010
  • Ultrahigh surface areas in porous solids, J. R. Holst and A. I. Cooper, Adv. Mater., 2010, 22, 5212.
  • Porous organic molecules J. R. Holst, A. Trewin and A. I. Cooper, Nature Chem., 2010, 2, 915.
  • Triply interlocked covalent organic cages. T. Hasell, X. Wu, J.T.A. Jones, J. Bacsa, A. Steiner, T. Mitra, A. Trewin, D.J. Adams and A.I. Cooper, Nature Chem., 2010, 2, 750. (Paper highlighted in C & E News, also in a News and Views article: J. E. Beves and D. A. Leigh, Nature Chem., 2010, 2, 708-710)
  • A-Site Order Control in Mixed Conductor NdBaCo2O5+delta Films through Manipulation of Growth Kinetics, Grygiel, C., McMitchell, S. R. C., Xu, Z., Yan, L., Niu, H. J., Giap, D., Bacsa, J., Chalker, P. R., and Rosseinsky, M. J., Chem. Mater. 2010, 22, 1955.
  • Palladium nanoparticle incorporation in conjugated microporous polymers by supercritical fluid processing, T. Hasell, C. D. Wood, R. Clowes, J. T. A. Jones, Y. Z. Khimyak, D. J. Adams and A. I. Cooper, Chem. Mater., 2010, 22, 557.
  • Room Temperature Oxidation of Methyl Orange and Methanol over Pt-HCa2Nb3O10 and Pt-WO3 Catalysts Without Light, Emiliana Dvininov, Upendra A. Joshi, James R. Darwent, John B. Claridge, Zhongling Xu and Matthew Rosseinsky Chem. Commun. 2011, 47, 881
  • Visible light Photo-oxidation of Model Pollutants Using CaCu3Ti4O12, Joanna H. Clark, Matthew S. Dyer, Robert G. Palgrave, Christopher P. Ireland, James R. Darwent, John B. Claridge, Matthew J. Rosseinsky, J. Am. Chem. Soc. 2011, 133, 1016-1032.
  • Fe³O4 nanoparticles with multi-functionality for targeted bi-modular imaging of pancreatic cancer, Cristina I. Olariu, Humphrey H. P. Yiu, Laurent Bouffier, Eithne Costello, Christopher M. Halloran, Matthew J. Rosseinsky J. Mater. Chem. 2011, 21, 12650-12659.
  • Multi-responsive polymer-stabilized magnetic engineered emulsions as liquid-based switchable magneto-responsive actuators, Robert T. Woodward, Cristina I. Olariu, Erol A. Hasan, Humphrey H. P. Yiu, Matthew J. Rosseinsky and Jonathan V. M. Weaver, Soft Matter, 2011, 7, 4335.
  • Modular and predictable assembly of porous organicmolecular crystals, J. T. A. Jones, T. Hasell, X. Wu, J. Bacsa, K.E. Jelfs, M. Schmidtmann, S.Y. Chong, D. J. Adams, A. Trewin, F. Schiffman, F. Cora, B. Slater, A. Steiner, G.M. Day and A. I. Cooper, Nature, 2011, 474, 367.
  • CO2 selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water, Kyriakos C. Stylianou, John E. Warren, Samantha Y. Chong, John Bacsa, Darren Bradshaw and Matthew J. Rosseinsky Chem. Commun., 2011, 47, 3389–3391
  • Metal-organic conjugated microporous polymers. J.-X. Jiang, C.Wang, A. Laybourn, T. Hasell, R. Clowes, Y. Z. Khimyak, J. Xiao, S. J. Higgins, D. J. Adams and A. I. Cooper, Angew. Chem., Int. Ed., 2011, 50, 1072.
  • On–Off Porosity Switching in a Molecular Organic Solid, J. T. A. Jones, D. Holden, T. Mitra, T. Hasell, D. J. Adams, K. E. Jelfs, A. Trewin, D. J. Willock, G. M. Day, J. Bacsa, A. Steiner and A. I. Cooper, Angew. Chem., Int. Ed., 2011, 50, 749.
  • Porous organic molecular solids by dynamic covalent scrambling, S. Jiang, J. T. A. Jones, T. Hasell, C. E. Blythe, D. J. Adams, A. Trewin and A. I. Cooper, Nature Commun., 2011, 2, 207.
  • A scalable synthesis for porous organic cages, D. Lydon, D. J. Adams and A. I. Cooper, Synth. Commun., 2011, 41, 2146.
  • Nanoporous organics enter the cage age, A. I. Cooper, Angew. Chem., Int. Ed., 2011, 50, 996.
  • Selective gas sorption in a [2+3] ‘propeller’ cage crystal, S. Jiang, J. Bacsa, X. Wu, J.T.A. Jones, R. Dawson, A. Trewin, D. J. Adams and A. I. Cooper, Chem., Commun., 2011, 8919.
  • Band gap engineering in fluorescent conjugated microporous polymers, J-X. Jiang, A. Trewin, D.J. Adams and A.I. Cooper, Chem. Sci., 2011, 2, 1777.
  • A soft porous organic cage crystal with complex gas sorption behavior, T. Mitra, X. Wu, R. Clowes, J.T.A. Jones, K. Jelfs, D.J. Adams, A. Trewin, J. Bacsa, A. Steiner and A.I. Cooper, Chem. Eur. J., 2011, 17, 10235
  • Molecular doping of porous organic cages, T. Hasell, M. Schmidtmann and A.I. Cooper, J. Am. Chem. Soc., 2011, 133, 14920
  • Supramolecular engineering of intrinsic and extrinsic porosity in covalent organic cages, M.J. Bojdys, M.E. Briggs, J.T.A. Jones, D.J. Adams, S.Y. Chong, M. Schmidtmann and A.I. Cooper, J. Am. Chem. Soc., 2011, 113, 16566–16571
  • Large self-assembled chiral organic cages: synthesis, structure and shape persistence, K.E. Jelfs, X. Wu, M. Schmidtmann, J.T.A. Jones, J.E. Warren, D.J. Adams and A.I. Cooper, Angew. Chem., Int. Ed., 2011, 50, 10653–10656.
  • Conformer interconversion in a switchable porous organic cage, K. E. Jelfs, F. Schiffmann, J. T. A. Jones, B. Slater, F. Cora and A. I. Cooper, PCCP, 2011, 13, 20081–20085.
  • Cation ordering within the perovskite block of a six-layer Ruddlesden-Popper oxide from layer-by-layer growth – artificial interfaces in complex unit cells, L.Yan, H. J. Niu, Giap. V. Duong, M.R. Suchomel, J. Bacsa, P.R. Chalker, J. Hadermann, G. van Tendeloo, M. J. Rosseinsky Chem. Sci. 2011, 2, 261-272.
  • Stabilization of a complex perovskite superstructure under ambient conditions: influence of cation composition and ordering, and evaluation as an SOFC cathode, A. Demont, M. Dyer, R. Sayers, M.F. Thomas, M. Tsiamtsouri, H. Niu, G.R. Darling, A. Daoud-Aladine, J.B. Claridge, M.J. Rosseinsky Chem. Mater. 2011, 22, 6598-6615.
  • SrHf0.67Ti0.33O3 high-k films deposited on Si by pulsed laser deposition, L. Yan, Z.L. Xu, C. Grygiel, S.R.C. McMitchell, M.R. Suchomel, J. Bacsa, J.H. Clark, H.J. Niu, S. Romani, R.G. Palgrave, P.R. Chalker, M.J. Rosseinsky Appl. Phys. A, 2011, 104, 447-451.
  • Cation vacancy order in the K0.8+xFe1.6-ySe2 system: Five-fold cell expansion accommodates 20% tetrahedral vacancies, J. Bacsa A. Y. Ganin Y. Takabayashi K. E. Christensen K. Prassides M. J. Rosseinsky and J. B. Claridge Chem. Sci., 2011, 2, 1054.
  • Soluble conjugated microporous polymers, G. Cheng, T. Hasell, A. Trewin, D. J. Adams, and A. I. Cooper, Angew. Chem., Int. Ed., 2012, 51, 12727–12731.
  • Porous, fluorescent, covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis, S. Ren, M. J. Bojdys, R. Dawson, A. Laybourn, Y. Z. Khimyak, D. J. Adams and A. I. Cooper, Adv. Mater., 2012, 24, 2357-2361.
  • Molecular organic crystals: From barely porous to really porous, A. I. Cooper, Angew. Chem., Int. Ed., 2012, 51, 7892–7894
  • Porous organic alloys, T. Hasell, S. Y. Chong, M. Schmidtmann, D. J. Adams and A. I. Cooper, Angew. Chem., Int. Ed., 2012, 51, 7154.
  • Alkylated organic cages: from porous crystals to neat liquids, N. Giri, C. E. Davidson, G. Melaugh, M. G. Del Popolo, J. T. A. Jones, T. Hasell, A. I. Cooper, P. N. Horton, M. B. Hursthouse and S. L. James, Chem. Sci., 2012, 3, 2153-2157
  • Reversible water uptake by a stable imine-based porous organic cage, T. Hasell, M Schmidtmann, C.A. Stone, M.W. Smith and A.I. Cooper, Chem. Commun., 2012, 4689-4691
  • Porous organic cage nanocrystals by solution mixing, T. Hasell, S. Y. Chong, K. E. Jelfs, D. J. Adams and A. I. Cooper, J. Am. Chem. Soc., 2012, 134, 588-598
  • A porous layered metal-organic framework from pi-pi-stacking of layers based on a Co-6 building unit, C.G. Perkins, J.E. Warren, A. Fateeva, K.C. Stylianou, A. McLennan, K.E. Jelfs, D. Bradshaw, M.J. Rosseinsky Microporous Mesoporous Mater., 2012, 157, 24-32.
  • Enhanced stability in rigid Peptide-based porous materials, C. Marti-Gastaldo, J.E. Warren, K.C. Stylianou, N.L.O. Flack, M.J. Rosseinsky Angew. Chem. Int. Ed. Engl. 2012, 51, 11044.
  • Dimensionality Transformation through Paddlewheel Reconfiguration in a Flexible and Porous Zn-based MOF, K. C. Stylianou, J. Rabone, S.Y. Chong, R. Heck, J. Armstrong, P. V. Wiper, K. E. Jelfs, S. Zlatogorsky, J. Bacsa, A. G. McLennan, C. P. Ireland, Y. Z. Khimyak, K. M. Thomas, D. Bradshaw, M. J. Rosseinsky, J. Am. Chem. Soc. 2012, 134, 20466,
  • A water-stable porphyrin-based metal-organic framework active for visible light photocatalysis, Fateeva, A., Chater, P., Ireland, C., Tahir, A. A., Khimyak, Y., Wiper, P., Darwent, J. R. & Rosseinsky, M. J., Angew. Chem., Int. Ed., 2012, 7440-7444,.
  • Molecular organic crystals: From barely porous to really porous, A. I. Cooper, Angew. Chem., Int. Ed., 2012, 51, 7892–7894
  • Chemical control of octahedral tilting and off-axis A cation displacement allows ferroelectric switching in a bismuth-based perovskite, Dolgos, M., Adem, U., Wan, X., Xu, Z., Bell, A. J., Comyn, T. P., Stevenson, T., Bennett, J., Claridge, J. B. & Rosseinsky, M. J. Chem. Sci. 2012, 3, 1426-1435.
  • A Polar Corundum Oxide Displaying Weak Ferromagnetism at Room Temperature, Li, M.-R., Adem, U., McMitchell, S. R. C., Xu, Z., Thomas, C. I., Warren, J. E., Giap, D. V., Niu, H., Wan, X., Palgrave, R. G., Schiffmann, F., Cora, F., Slater, B., Burnett, T. L., Cain, M. G., Abakumov, A. M., van Tendeloo, G., Thomas, M. F., Rosseinsky, M. J. & Claridge, J. B., J. Am. Chem. Soc. 2012, 134, 3737-3747.
  • Local Structure of a Pure Bi A Site Polar Perovskite Revealed by Pair Distribution Function Analysis and Reverse Monte Carlo Modeling: Correlated Off-Axis Displacements in a Rhombohedral Material, Chong, S. Y., Szczecinski, R. J., Bridges, C. A., Tucker, M. G., Claridge, J. B. & Rosseinsky, M. J., J. Am. Chem. Soc. 2012, 134, 5836-5849.
  • Perovskite B site compositional control of [110]p polar displacement coupling in an ambient pressure stable Bi-based ferroelectric, Dolgos, M, Adem, U, Comyn, T, Bell, A.J., Stephenson, T, Bennett, J., Tran, T.T., Halsayamani, P.S., Claridge, J.B., Rosseinsky, M.J. Angew. Chem. Int. Ed. 2012, 51, 10770-5.
  • Molecular shape sorting using molecular organic cages, T. Mitra, K. E. Jelfs, M. Schmidtmann, A. Ahmed, S. Y. Chong, D. J. Adams, A. I. Cooper, Nature Chem., 2013, 5, 276–281.
  • Molecular simulations to understand and to design porous organic molecules, K. E. Jelfs and A. I. Cooper, Curr. Opin. Sol. State Mater. Sci., 2013, 17, 19–30
  • In silico design of supramolecules from their precursors: odd–even effects in cage-forming reactions, K. E. Jelfs, E. G. B. Eden, J. L. Culshaw, S. Shakespeare, E. O. Pyzer-Knapp, H. P. G. Thompson, J. Bacsa, G. M. Day, D. J. Adams and A. I. Cooper, J. Am. Chem. Soc., 2013, 135, 9307–9310
  • Dodecaamide cages: organic 12-arm building blocks for supramolecular chemistry, J. L. Culshaw, G. Cheng, M. Schmidtmann, T. Hasell, M. Liu, D. J. Adams and A. I. Cooper, J. Am. Chem. Soc., 2013, 135, 10007–10010
  • High-pressure carbon dioxide uptake for porous organic cages: comparison of spectroscopic and manometric measurement techniques, T. Hasell, J. A. Armstrong, K. E. Jelfs, F. H. Tay, K. M. Thomas, S. G. Kazarian and A. I. Cooper, Chem. Commun., 2013, 49, 9410–9412
  • Dynamic nuclear polarization NMR spectroscopy allows high throughput characterization of microporous organic polymers, F. Blanc, S. Y. Chong, T. O McDonald, D. J. Adams, S. Pawsey, M. A. Caporini and A. I. Cooper, J. Am. Chem. Soc., 2013, 135, 15290-15293
  • Low band-gap benzothiadiazole conjugated microporous polymers, S. Ren, R. Dawson, D. J. Adams and A. I. Cooper, Polym. Chem., 2013, 4, 5585-5590.
  • Shedding light on structure–property relationships for conjugated microporous polymers: the importance of rings and strain, M. A. Zwijnenburg, G. Cheng, T. O. McDonald, K. E. Jelfs, J.-X. Jiang, S. Ren, T. Hasell, F. Blanc, A. I. Cooper and D. J. Adams, Macromolecules, 2013, 46, 7696-7704.
  • Shape prediction for supramolecular organic nanostructures: [4+4] macrocyclic tetrapods, M. E. Briggs, K. E. Jelfs, S. Y. Chong, C. Lester, M. Schmidtmann, D. J. Adams and A. I. Cooper, Cryst. Growth Des., 2013, 13, 4993-5000.
  • Molecular dynamics simulations of gas selectivity in amorphous porous molecular solids, S. Jiang, K. E. Jelfs, D. Holden, T. Hasell, S. Y. Chong, M. Haranczyk, A. Trewin and A. I. Cooper, J. Am. Chem. Soc., 2013, 10.1021/ja407374k.
  • Growth of M-type hexaferrite thin films with conical magnetic structure, P. Borisov, J.A. Alaria, S.R.C. McMitchell, T. Yang, M.J. Rosseinsky Applied Physics Letters 2013, 102, 032902.
  • 1:1:1 triple cation B-site ordered and oxygen-deficient perovskite Ca4GaNbO8 – a member of a family of anion-vacancy based cation ordered complex perovskites, T. Yang, J.B. Claridge, M.J. Rosseinsky, Inorg. Chem. 2013, 52, 3795.
  • A new family of layered ferrites: BaFe9LiO15, T. Yang, A. Daoud-Aladine, M.F. Thomas, J. B. Claridge, M.J. Rosseinsky Inorg. Chem. 2013, 52, 4866.
  • Internal activation strain and oxygen mobility in a thermally stable layered Fe3+ oxide, R. Sayers, F. Schiffmann, S. Fearn, J.A. Kilner, B. Slater, S. Romani, D. J. Tatham, J.B. Claridge, F. Cora, M.J. Rosseinsky, Chem. Mater., 2013, 25, 3441–3457
  • Epitaxial growth and enhanced conductivity of an IT-SOFC cathode based on a complex perovskite superstructure with six distinct cation sites, R. Sayers, N.L.O. Flack, J. Alaria, S. Romani, S.R.C. McMitchell, R. Palgrave, T.J. Pennycook, Q. Ramasse, M.J. Rosseinsky Chem. Sci. 2013, 4, 2403.
  • Single sublattice endotaxial phase separation driven by charge frustration in a complex oxide, A. Demont, R. Sayers, M. Tsiamtsouri, Z. Xu, P. Chater, S. Romani, H, Niu, Y. Breard, Z.Q. Deng, J.B. Claridge, M.J. Rosseinsky J. Amer. Chem. Soc. 2013, 135, 10114.
  • Nanoporous organic polymer/cage composite membranes, A. F. Bushell, P. M. Budd, M. P. Attfield, J. T. A. Jones, T. Hasell, A. I. Cooper, P. Bernardo, F. Bazzarelli, G. Clarizia and J. C. Jansen, Angew. Chem., Int. Ed., 2013, 52, 1253–1256
  • Exfoliation of crystalline 2D carbon nitride: thin sheets, scrolls and bundles via mechanical and chemical routes, M. J. Bojdys, N. Severin, J. P. Rabe, A. I. Cooper, A. Thomas and M. Antonietti, Macromol. Rapid Commun., 2013, 34, 850–854
  • Tuning of gallery heights in a crystalline 2D carbon nitride network, S. Y. Chong, J. T. A. Jones, Y. Z. Khimyak, A. I. Cooper, A. Thomas, M. Antonietti and M. J. Bojdys, J. Mater. Chem. A, 2013, 1, 1102–1107
  • Conjugated microporous polymers with Rose Bengal dye for highly efficient heterogeneous organo-photocatalysis, J.-X. Jiang, Y.-Y. Li, X. Wu, J.-L. Xiao, D. J. Adams and A. I. Cooper, Macromolecules, 2013, 46, 8779-8783.
  • Controlling the crystallization of porous organic cages: molecular analogs of isoreticular frameworks using shape-specific directing solvents, T. Hasell, J. L. Culshaw, S. Y. Chong, M. Schmidtmann, M. A. Little, K. E. Jelfs, E. O. Pyzer-Knapp,H. Shepherd, D. J. Adams, G. M. Day and A. I. Cooper, under revision. J. Am. Chem. Soc., 2014, 136, 1438-1448.
  • Rare gas separation by a dynamic molecular filter, P. S. Reiss, L. Chen, D. Holden, K. E. Jelfs, S. Y. Chong, T. Hasell, K. Mark Thomas, J. Bell, J. Busto, R. Noel, J. Liu, D. M. Strachan, P. K. Thallapally and A. I. Cooper, Nature Mater., 2014, under review.
  • Linear conjugated polymers ofintrinsic microporosity, Ge Cheng, B. Bonillo, R. S. Sprick, T. Hasell, D. J. Adams, and A. I. Cooper, in preparation (submitted for publication to Adv. Funct. Mater.). 2014.
  • Predicting the crystal energy landscapes of porous molecular cages, Edward O. Pyzer-Knapp, Hugh P. G. Thompson, Florian Schiffman, Kim E. Jelfs, Andrew I. Cooperand Graeme M. Day, Chem. Sci. 2014, DOI: 10.1039/C4SC00095A
  • Sidechain control of porosity closure in multiple peptide-based porous materials by cooperative folding, C. Martí-Gastaldo, D. Antypov, J. E. Warren, M. E. Briggs, P. A. Chater, P. V. Wiper, G. Miller, Y. Z. Khimyak, G. R. Darling, N. G. Berry, M. J. Rosseinsky Nature Chem. 2014, 6, 343-351.
  • Shape Selectivity by Guest-driven Restructuring of a Porous Material, J. E. Warren, C. G. Perkins, K. E. Jelfs, P. Boldrin, P. A. Chater, M. E. Briggs, K. C. Stylianou, J. B. Claridge, M. J. Rosseinsky Angew. Chem. Int. Ed. 2014, 15, 4592-4596
  • Triazine-based, graphitic carbon nitride: a two-dimensional semiconductor, G. Algara-Siller, N. Severin, S. Y. Chong, T. Björkman, R. G. Palgrave, A. Laybourn, M. Antonietti, Y. Z. Khimyak, A. V. Krasheninnikov, J. P. Rabe, U. Kaiser, A. I. Cooper, A. Thomas, M. J. Bojdys, Angew. Chem., Int. Ed., 2014, under review.
  • Shining a light on s-tiazine-based polymers, C. Butchosa, T. O. McDonald, A. I. Cooper, D. J. Adams, M. A. Zwijnenburg, J. Phys. Chem. C 2014, 118, 4314-4324